Results 61 to 70 of about 131,639 (350)

Advancing Research on Biomaterials and Biological Materials with Scanning Electron Microscopy under Environmental and Low Vacuum Conditions

open access: yesAdvanced Engineering Materials, EarlyView.
Herein, environmental scanning electron microscopy (ESEM) is discussed as a powerful extension of conventional SEM for life sciences. By combining high‐resolution imaging with variable pressure and humidity, ESEM allows the analysis of untreated biological materials, supports in situ monitoring of hydration‐driven changes, and advances the functional ...
Jendrian Riedel   +6 more
wiley   +1 more source

Hidroformilação do oleato de metila catalisada por complexos de ródio

open access: yesQuímica Nova, 2012
In this work, we describe the hydroformylation of methyl oleate catalyzed by several rhodium complexes. Parameters including total pressure, phosphorous/rhodium and CO/H2 ratio, temperature and phosphorous ligands were scanned.
Ana Nery Furlan Mendes   +2 more
doaj   +1 more source

Pseudotetrahedral Rhodium(I) Complexes [PDF]

open access: yesChemistry – A European Journal, 2014
AbstractA combination of four‐electron donors, such as alkynes, with strongly donating and strong‐field scorpionate ligands is appropriate to create pseudotetrahedral rhodium(I) environments, as found in [Rh(PhBP3)(HCCPh)], which promotes HC bond activation and CC coupling reactions under very smooth conditions.
Geer, Ana M.   +4 more
openaire   +3 more sources

Superconductivity in zirconium-rhodium alloys [PDF]

open access: yes, 1969
Metallographic studies and transition temperature measurements were made with isothermally annealed and water-quenched zirconium-rhodium alloys. The results clarify both the solid-state phase relations at the Zr-rich end of the Zr-Rh alloy system and the
Zegler, S. T.
core   +1 more source

Thermoelectric Modules Incorporating MgAgSb and Mg3(Sb,Bi)2 Synthesized Using a Melting Method

open access: yesAdvanced Engineering Materials, EarlyView.
A scalable synthesis method for a thermoelectric material of MgAgSb is established. A thermoelectric power module of MgAgSb/Mg3(Sb,Bi)2 is fabricated, showing the conversion efficiency of 7.4% at ΔT = 315 K. The performance is comparable to conventional Bi2Te3 modules when they are operated with an air‐cooled heat exchanger.
Kazuo Nagase   +8 more
wiley   +1 more source

Terminal Imido Rhodium Complexes [PDF]

open access: yesAngewandte Chemie, 2014
AbstractCompounds of the late transition metals with MX multiple bonds (X=CR2, NR, O) represent a synthetic challenge, partly overcome by preparative chemists, but with noticeable gaps in the second‐ and third‐row elements. For example, there are no isolated examples of terminal imido rhodium complexes known to date. Described herein is the isolation,
Geer, Ana M.   +3 more
openaire   +3 more sources

In Situ Constructed Magnetic Core‐Shell Hydrogen‐Bonded Organic Framework‐on‐Metal–Organic Framework Structure: an Efficient Catalyst for Peroxymonosulfate Activation

open access: yesAdvanced Functional Materials, EarlyView.
In this work, a magnetic core‐shell catalyst (HOF‐on‐Fe3O4/ZIF‐67) is successfully synthesized, consisting of a metal–organic framework (ZIF‐67) with magnetic Fe3O4 as the core and a porous hydrogen‐bonded organic framework (HOF) as the shell. The catalyst efficiently activated peroxymonosulfate, resulting in rapid and effective removal of water ...
Yingying Du   +4 more
wiley   +1 more source

Self-Organization at the Nanoscale Scale in Far-From-Equilibrium Surface Reactions and Copolymerizations

open access: yes, 2012
An overview is given of theoretical progress on self-organization at the nanoscale in reactive systems of heterogeneous catalysis observed by field emission microscopy techniques and at the molecular scale in copolymerization processes.
Gaspard, Pierre
core   +1 more source

Ferrocene Derivatives Enable Ultrasensitive Perovskite Photodetectors with Enhanced Reverse Bias Stability

open access: yesAdvanced Functional Materials, EarlyView.
Novel ferrocene derivatives (e.g., FcPhc2) are used as an ultrathin layer hole‐blocking layer, reducing hole injection from the Ag contact. This results in an ultralow noise spectral density of 1.2 × 10−14 A Hz−1/2, and a high specific detectivity of 8.1 × 1012 Jones at −0.5 V.
Eunyoung Hong   +16 more
wiley   +1 more source

Understanding and Optimizing Li Substitution in P2‐Type Sodium Layered Oxides for Sodium‐Ion Batteries

open access: yesAdvanced Functional Materials, EarlyView.
This work explores Li‐substituted P2 layered oxides for Na‐ion batteries by crystallographic and electrochemical studies. The effect of lithium on superstructure orderings, on phase transitions during synthesis and electrochemical cycling and on the interplay of O‐ versus TM‐redox is revealed via various advanced techniques, including semi‐simultaneous 
Mingfeng Xu   +5 more
wiley   +1 more source

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