Results 61 to 70 of about 93,160 (359)
Electromeric Rhodium Radical Complexes [PDF]
Angewandte Chemie, 2009 Radical changes: One single P-Rh-P angle determines whether the odd electron in the paramagnetic complex [Rh(trop2PPh)(PPh3)] is delocalized over the whole molecule (see picture, blue) or is localized on the P—Rh unit (red). The two energetically almost degenerate electromers exist in a fast equilibrium, and the "red" complex has the highest spin ...
Puschmann, Florian Frank +5 more
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Advanced Functional Materials, EarlyView.Novel ferrocene derivatives (e.g., FcPhc2) are used as an ultrathin layer hole‐blocking layer, reducing hole injection from the Ag contact. This results in an ultralow noise spectral density of 1.2 × 10−14 A Hz−1/2, and a high specific detectivity of 8.1 × 1012 Jones at −0.5 V.
Eunyoung Hong +16 more
wiley +1 more source
Reactivity of Rhodium(II) amido/Rhodium(I) aminyl complexes [PDF]
Inorganica Chimica Acta, 2018 Reaction of the Rh(II) dimer [LRh]2(μ-Br)2 (L = ([2,6-Me2C6H3NCMe]2CH) with the bulky amide LiNH(2,6-iPr2C6H3) leads to a monomeric Rh(II) amide with a T-shape N3Rh arrangement and a pronounced agostic interaction. Reaction with the less bulky LiNH(2,6-Me2C6H3) results in benzylic C-H activation to a binuclear complex with a unique aza-xylylene ...
Nicolaas P. van Leest +6 more
openaire +5 more sources
Advanced Functional Materials, EarlyView.This work explores Li‐substituted P2 layered oxides for Na‐ion batteries by crystallographic and electrochemical studies. The effect of lithium on superstructure orderings, on phase transitions during synthesis and electrochemical cycling and on the interplay of O‐ versus TM‐redox is revealed via various advanced techniques, including semi‐simultaneous
Mingfeng Xu +5 more
wiley +1 more source
Comparison Of The MWCNTs-Rh And MWCNTs-Re Carbon-Metal Nanocomposites Obtained In High-Temperature
Archives of Metallurgy and Materials, 2015 Carbon-metal nanocomposites consisting of multiwalled carbon nanotubes coated with rhodium or rhenium nanoparticles by the high-temperature method were fabricated during the research undertaken.
Dobrzańska-Danikiewicz A.D. +3 more
doaj +1 more source
From Low Symmetry to High Dissymmetry: Chiral Plasmonic Films of Binary and Nanobipyramid Assemblies
Advanced Functional Materials, EarlyView.This work develops highly dissymmetric chiral plasmonic thin films by helically assembling gold nano bipyramids within a liquid‐crystal template. Engineering of the chiroptical response is achieved by varying particle size and geometry, as well as preparing binary assemblies.
Martyna Wasiluk +10 more
wiley +1 more source
Calculation of the X-Ray Spectrum of a Mammography System with Various Voltages and Different Anode-Filter Combinations Using MCNP Code [PDF]
Iranian Journal of Medical Physics, 2016 Introduction One of the best methods in the diagnosis and control of breast cancer is mammography. The importance of mammography is directly related to its value in the detection of breast cancer in the early stages, which leads to a more effective ...
Lida Gholamkar +3 more
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Fractional Skyrmion Tubes in Chiral‐Interfaced 3D Magnetic Nanowires
Advanced Functional Materials, EarlyView.In chiral 3D helical magnetic nanowires, the coupling between the geometric and magnetic chirality provides a way to create topological spin states like vortex tubes. Here, it is demonstrated how the breaking of this coupling in interfaced 3D nanowires of opposite chirality leads to even more complex topological spin states, such as fractional ...
John Fullerton +11 more
wiley +1 more source
Advanced Functional Materials, EarlyView.Cu‐based catalysts as a cornerstone in advancing sustainable energy technologies are fully reviewed in this manuscript, highlighting their potential in photo‐ and electrocatalysis. It includes metallic copper, copper oxides, copper sulfides, copper halide perovskites, copper‐based metal–organic frameworks (MOFs), and covalent organic frameworks (COFs),
Jéssica C. de Almeida +16 more
wiley +1 more source
Тонкие химические технологии, 2008 Interaction of Rhodium(III) Chloride complexes with Formaldehyde into the sulphate and chloric solutions has been studied. Probably stages of reducing process that proceeds with metal Rhodium formation has been suggested.
T. M. Buslaeva +3 more
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