Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2
By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin +3 more
wiley +2 more sources
WEE1 kinase inhibition to overcome acquired resistance to targeted therapies in colorectal cancer. [PDF]
Buzo K +18 more
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A mechanically adaptive interface enhances the stability and cycling performance of lithium metal all‐solid‐state batteries, particularly under low pressure. The interface design synergistically integrates indium fluoride with polyrotaxane, where the inorganic component effectively suppresses lithium dendrite formation and the organic component ...
Jihoon Oh +3 more
wiley +2 more sources
Photocatalytic <i>In Situ</i> Activation of Bench-Stable Saccharides: A General Synthetic Strategy for <i>C</i>-Glycosyl Bicyclo[1.1.1]pentanes. [PDF]
Qi C, Dell'Amico L, Goti G.
europepmc +1 more source
Rheological evolution of a trachybasalt from Mt. Etna under slow cooling. [PDF]
Di Fiore F, Vona A.
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Extracorporeal Cytokine Hemadsorption for the Treatment of Severe Steroid Refractory Cytokine Release Syndrome Secondary to T-Cell Immunotherapy for B-Cell Malignancies: A Case Series. [PDF]
Cavallaro G +12 more
europepmc +1 more source
IL1R2 Deficiency Unleashes Neutrophil-Mediated Antitumor Potential in Sarcoma. [PDF]
Mariancini A +21 more
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One half of the sprinting coin: the oxygen transport cascade of a 91-yr-old female world-record sprinter. [PDF]
Colosio M +10 more
europepmc +1 more source
The other half of the sprinting coin: the neuromuscular profile of a 91-yr-old female world record sprinter. [PDF]
Colosio M +12 more
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