Results 111 to 120 of about 17,231 (260)
European Journal of Inorganic Chemistry, EarlyView.The preparation of soluble and stable metal M2+ dications only stabilized by weakly coordinating anions, that is, M[WCA]2 salts, is an emerging field that, beyond its fundamental interest, holds promise in reactivity due to the high electrophilicity of the central M2+ center.
Samuel Dagorne +3 more
wiley +1 more source
Synthesis of the A-F Fragment of the Pacific Ciguatoxin CTX3C by Iterative Ring-Closing Metathesis and Tsuji-Trost Allylation. [PDF]
Chemistry, 2023 Triantafyllakis M +4 more
europepmc +1 more source
Synthesis of a Carbon‐Linked Acyldepsipeptide Derivative
European Journal of Organic Chemistry, EarlyView.The synthesis of a methylene‐linked acyldepsipeptide (ADEP) is reported. Success relied upon an improve method to generate a versatile vinyl glycine methyl ester synthon and a rationally optimized Grubb’s metathesis. NMR and in silico studies revealed an unusual trans–trans proline orientation for this new unnatural ADEP analog, advancing the ...
Katelyn G. Stevens-Davis +6 more
wiley +1 more source
Silicon Catalyzed C-O Bond Ring Closing Metathesis of Polyethers. [PDF]
Angew Chem Int Ed Engl, 2022 Ansmann N, Thorwart T, Greb L.
europepmc +1 more source
Toward a simulation approach for alkene ring-closing metathesis : scope and limitations of a model for RCM [PDF]
, 2011 A published model for revealing solvent effects on the ring-closing metathesis (RCM) reaction of di-Et diallylmalonate 7 has been evaluated over a wider range of conditions, to assess its suitability for new applications.
Adjiman C. S. +33 more
core +1 more source
Macromolecular Rapid Communications, EarlyView.It is reported the design of biobased sustainable, smart, and functional adhesives achieved dispersing recycled carbon fibers into biobased epoxy monomer. ABSTRACT The development of sustainable, smart, and functional adhesives is crucial in advancing environmentally friendly materials.
Alberto Cellai +6 more
wiley +1 more source
Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers [PDF]
, 2007 A strategy for the formation of mechanically interlocked polymers is presented. Ring-closing olefin metathesis has been shown to provide a very high yielding route to [c2]daisy-chains suitably functionalized to allow their one-step conversion to ...
Grubbs, Robert H. +3 more
core +1 more source
Macromolecular Rapid Communications, EarlyView.Metathesis‐derived cyclopentene epoxides enable strictly alternating, scrambling‐free ring‐opening copolymerization with phthalic thioanhydride, yielding well‐defined polythioesters with molecular weights up to ∼38 kg/mol. Their performance extends to oxygen‐based anhydrides and selective terpolymerizations. Direct comparisons with all‐oxygen analogues
Niracha Tangyen +3 more
wiley +1 more source
Enantioselective Synthesis of the Ethyl Analog of the Marine Alkaloid Haliclorensin C
Molecules, 2019 The enantioselective synthesis (3.7% overall yield in nine steps from 2) and biological screening of the ethyl analog of the macrocyclic marine alkaloid haliclorensin C (compound 5) are reported.
Guillaume Guignard +4 more
doaj +1 more source
ChemistryOpen, EarlyView.Targeting a nucleotide‐sensitive groove on Hsp70 that binds the Bim BH3 helix, we integrate structures, biophysics, and SAR from peptides, fragments, and phenalene‐dicarbonitrile “wedges.” These disrupt the Hsp70–Bim complex with sub‐µM cellular engagement and in vivo activity while sparing Hsp90/mortalin.
Emadeldin M. Kamel +5 more
wiley +1 more source