Results 121 to 130 of about 938,190 (242)

Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents

open access: yesPolymer International, EarlyView.
The process of anionic polymerization of β‐myrcene in hydrocarbon solvents was examined by kinetic studies and quantum chemical calculations. Abstract The kinetics of anionic polymerization of β‐myrcene initiated by sec‐butyllithium were examined in saturated and unsaturated hydrocarbon solvents, i.e. cyclohexane, cyclohexene, 4‐vinylcyclohexene and dl‐
Alexander Rösler   +4 more
wiley   +1 more source

In Situ Curing‐Enabled 3D Printing of Continuous Fiber‐Reinforced Thermosetting Composites

open access: yesJournal of Polymer Science, EarlyView.
In situ curing‐enabled the 3D printing of continuous fiber/thermoset composites, which were reviewed. Particularly, four types of in situ curing, were discussed, including Radiation‐induced curing, photothermal curing, electrothermal curing, and frontal polymerization. AI‐integrated printing was also analyzed.
Xiaofei Wu   +2 more
wiley   +1 more source

A study of the ring opening metathesis polymerization of polycyclic aromatic monomers and cyclopentenes with well defined initiators [PDF]

open access: yes, 1994
This thesis describes studies into the ring opening metathesis polymerisation (ROMP) of polycyclic aromatic monomers and cyclopentenes. Chapter 1 reviews general aspects of ring opening metathesis polymerisation of relevance to the themes of this thesis.
Sugawara, Keiji
core  

Domino ring-opening metathesis–ring-closing metathesis of bicyclo[2.2.2]octene derivatives: scope and limitations

open access: yes, 2012
Domino metathesis involving ring-opening metathesis–ring-closing metathesis (ROM–RCM) of a bicyclo[2.2.2]octene derivative having an appropriate alkene chain, expected to produce a 7/6 fused bicyclic system, provided a decalin system in contrast to ROM ...
Bose, Sritama   +2 more
core   +1 more source

Ultrafast Mechanochemical Synthesis of Plasmonic Transition Metal Nitride Nanoparticles

open access: yesSmall, EarlyView.
Mechanochemistry enables ultrafast synthesis of plasmonic transition metal nitride nanoparticles in minutes rather than hours without external heat supply. The resulting mono‐ and mixed‐metal nitrides display tunable plasmonic absorption, demonstrating a potentially scalable route to refractory plasmonic materials.
Blaine G. Fiss   +3 more
wiley   +1 more source

Novel tandem ring-opening/ring-closing metathesis reactions of functionalized cyclohexenoids derived from (-)-α-pinene

open access: yes, 2002
The cyclohexenone (+)-2, readily obtained from (-)-α -pinene 1 was elaborated to (+)-3 in an attempt to construct the AB rings of taxoids employing the ring-closure metathesis (RCM) reaction as the key step.
Nandakumar, Jayakrishnan   +1 more
core   +1 more source

Sulfur‐ and Selenium‐Decorated Coumarins: Synthetic Strategies Involving Cyclization and Late‐Stage Functionalization

open access: yesThe Chemical Record, EarlyView.
Two decades of synthetic strategies for sulfur‐, selenium‐decorated coumarins are critically surveyed through 44 literature reports, with particular emphasis on derivatives functionalized at the C‐3 and C‐4 positions. This review reports the direct construction of the coumarin framework through cyclization processes and late‐stage functionalization of ...
Bruna R. Schneider   +6 more
wiley   +1 more source

Selective Domino Ring-Closing Metathesis−Cross-Metathesis Reactions between Enynes and Electron-Deficient Alkenes

open access: yes, 2016
A selective domino ring-closing metathesis (RCM)−cross-metathesis (CM) process between enynes and electron-deficient alkenes is reported. The conditions have been optimized for enynes 3 and methyl acrylate with catalyst IV.
Claire Vilain (3067122)   +3 more
core   +1 more source

Group 13 Aminopyridinato Complexes and Co─Al Heterobimetallics: Impact of Ligand Substituent and Metal Exchange on Thermal Behavior

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
A family of monometallic aluminum and gallium complexes supported by simple aminopyridinato ligands was synthesized and fully characterized by NMR spectroscopy and single‐crystal X‐ray diffraction. In addition, two Co─Al heterobimetallic complexes were synthesized and structurally characterized.
Pauline B. Lemp   +6 more
wiley   +1 more source

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