Synthesis of Substituted Tetrafluorocyclobutenes and Their Ring-Opening Metathesis/Ring-Closing Metathesis to Dihydrofurans Bearing a Tetrafluoroethylene Unit. [PDF]
Kučnirová K +3 more
europepmc +1 more source
Cross Carbonyl‐Olefin Metathesis of Unactivated Olefins
A method for the olefination of aryl aldehydes with unactivated alkenes via cross carbonyl‐olefin metathesis is described. Reaction of an aldehyde substrate with a cis−1,2‐disubstituted or monosubstituted olefin using the HBF4 salt of 2,3‐diazabicyclo[2.2.2]octane results in high‐yielding olefination with exclusive trans stereoselectivity. The reaction
Jason Wu +2 more
wiley +1 more source
Programmable Artificial-Cellular Membrane Dynamics via Ring-Closing Metathesis. [PDF]
Hamaguchi R +3 more
europepmc +1 more source
Combining dichloro and diiodo ruthenium catalysts produces mixed chloro–iodo species via in situ halide exchange, resulting in a new, more efficient catalytic system. The mixed catalysts outperform their homo‐anionic counterparts, delivering enhanced activity, higher conversion, and strong suppression of isomerization under both thermal and ...
Nebal Alassad +3 more
wiley +1 more source
Efficient convergent synthesis of 1,3-diazepinone nucleosides by ring-closing metathesis and direct glycosylation. [PDF]
Hedger AK +5 more
europepmc +1 more source
Optimized Ring Closing Metathesis Reaction Conditions To Suppress Desallyl Side Products in the Solid-Phase Synthesis of Cyclic Peptides Involving Tyrosine(O-allyl). [PDF]
Gisemba SA, Aldrich JV.
europepmc +1 more source
The Versatile Structural World of Methanedi‐ and Trisulfonic Acid and Their Salts
The solid‐state structures of the CH4‐derived polysulfonic acids methanedisulfonic acid (MDSA) and methanetrisulfonic acid (MTSA) are presented for the first time. Additionally, a broad overview over possible MDS and MTS salts, containing mostly group I cations, is given and their solid‐state structures are analyzed, showing the structural versatility ...
Katrin Eppers +4 more
wiley +1 more source
A sequential esterification-ring closing metathesis-Nozaki-Hiyama-Kishi strategy for constructing a natural product-like library of tetrahydrofuran-containing macrolides. [PDF]
Driedger D, Wilson DM, Britton R.
europepmc +1 more source
Luminescent coordination polymers of Group 1 (Li, K, Cs) and 2 (Mg─Ba) cations with gold(I) iso‐maleonitriledithiolate ({Au2[S2C = C(CN)2]}2−) units were prepared; 1‐D aurophilic chains are present in all cases. The structures strongly depend on cation charge and size, with N‐cyano coordination observed in the Gp 1 and larger Gp 2 cations. Increasingly
Jefferson A. Pells +2 more
wiley +1 more source
This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis +2 more
wiley +2 more sources

