Results 121 to 130 of about 17,231 (260)

Design and synthesis of novel bis-annulated caged polycycles via ring-closing metathesis: pushpakenediol

open access: yesBeilstein Journal of Organic Chemistry, 2014
Intricate caged molecular frameworks are assembled by an atom economical process via a Diels–Alder (DA) reaction, a Claisen rearrangement, a ring-closing metathesis (RCM) and an alkenyl Grignard addition.
Sambasivarao Kotha   +1 more
doaj   +1 more source

2,3‐Dichloro‐5,6‐Dicyano‐1,4‐Benzoquinone (DDQ)‐Mediated CC Bond Formation: Redox Strategies from Stoichiometric to Catalytic Systems

open access: yesChemistryOpen, EarlyView.
2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone serves as a versatile oxidant and redox catalyst for CC bond formation through hydride abstraction or single‐electron transfer. Stoichiometric and catalytic systems enable benzylic, allylic, and aromatic CH activation under mild, metal‐free conditions, providing sustainable routes to complex and bioactive ...
Dohoon Cha, Sun‐Joon Min
wiley   +1 more source

A Simple Nickel Catalyst Enabling an E‐Selective Alkyne Semihydrogenation [PDF]

open access: yes, 2019
Stereoselective alkyne semihydrogenations are attractive approaches to alkenes, which are key building blocks for synthesis. With regards to the most atom economic reducing agent dihydrogen (H 2 ), only few catalysts for the challenging E ‐selective ...
Kaewmee, Benyapa   +3 more
core   +1 more source

Diverse reactivity of maleimides in polymer science and beyond

open access: yesPolymer International, Volume 74, Issue 4, Page 296-306, April 2025.
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick   +2 more
wiley   +1 more source

Alkene Metathesis Catalysis: A Key for Transformations of Unsaturated Plant Oils and Renewable Derivatives

open access: yesOil & Gas Science and Technology, 2016
This account presents the importance of ruthenium-catalysed alkene cross-metathesis for the catalytic transformations of biomass derivatives into useful intermediates, especially those developed by the authors in the Rennes (France) catalysis team in ...
Dixneuf Pierre H.   +2 more
doaj   +1 more source

Advanced sol-gel process for efficient heterogeneous ring-closing metathesis. [PDF]

open access: yesSci Rep, 2021
Aharon S   +5 more
europepmc   +1 more source

Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents

open access: yesPolymer International, EarlyView.
The process of anionic polymerization of β‐myrcene in hydrocarbon solvents was examined by kinetic studies and quantum chemical calculations. Abstract The kinetics of anionic polymerization of β‐myrcene initiated by sec‐butyllithium were examined in saturated and unsaturated hydrocarbon solvents, i.e. cyclohexane, cyclohexene, 4‐vinylcyclohexene and dl‐
Alexander Rösler   +4 more
wiley   +1 more source

Ru complexes of Hoveyda–Grubbs type immobilized on lamellar zeolites: activity in olefin metathesis reactions

open access: yesBeilstein Journal of Organic Chemistry, 2015
Hoveyda–Grubbs type catalysts with cationic tags on NHC ligands were linker-free immobilized on the surface of lamellar zeolitic supports (MCM-22, MCM-56, MCM-36) and on mesoporous molecular sieves SBA-15.
Hynek Balcar   +5 more
doaj   +1 more source

Home - About - Disclaimer - Privacy