Results 111 to 120 of about 9,389 (255)

Ring-closing metathesis of heteroatom-substituted dienes

open access: yes, 2006
The ring-closing metathesis (RCM) of dienes that contain at least one participating heteroatom-substituted olefin is reviewed (olefins substituted with O, N, S, P, Si, B, and halogen atoms will be considered).
Satcharoen, Vachiraporn   +1 more
core  

Stereoselective Total Syntheses of (3,5)-Sonnerlactone and (3,5)-Sonnerlactone

open access: yesNatural Product Communications, 2017
A highly convergent and concise total syntheses of (3 R ,5 R )-Sonnerlactone and (3 R ,5 S ) Sonnerlactone from a readily available L -malic acid is described. The following series of reactions such as Barbier allylation, photochemical esterification and
Supriya Ghanty   +2 more
doaj   +1 more source

Recent Advancements in Ring Closing Olefin Metathesis

open access: yes, 1997
A short overview on recent developments in ring closing metathesis (RCM) of 1,ω-dienes to cycloalkenes is provided, with particular emphasis on applications to natural product synthesis and the preparation of olfactory perfume ingredients. These examples
Fürstner, A.
core   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Tandem Ring Opening−Ring Closing Metathesis of Cyclic Olefins

open access: yes, 2016
Ruthenium alkylidene 1 has been utilized in the tandem ring opening−ring closing metathesis of cyclic olefins. This reaction produces a bicyclic molecule from a cyclic olefin.
William J. Zuercher (13844)   +2 more
core   +2 more sources

Biotinylated Metathesis Catalysts: Synthesis and Performance in Ring Closing Metathesis [PDF]

open access: yes, 2019
Nine biotinylated Grubbs-Hoveyda and Grubbs-type metathesis catalysts were synthesized and evaluated in ring closing metathesis reactions of N-tosyl diallylamine and 5-hydroxy-2-vinylphenyl acrylate.
Kajetanowicz, Anna   +3 more
core  

Ruthenium-Catalyzed Ring-Opening and Ring-Closing Enyne Metathesis

open access: yes, 2016
When a CH2Cl2 solution of an enyne containing the cycloalkene moiety was stirred in the presence of ruthenium−carbene complex (10 mol %) at room temperature under ethylene gas (1 atm), ring-opening and ring-closing metathesis occurred to afford cyclized ...
Tsuyoshi Kitamura (2693950)   +1 more
core   +1 more source

Distinct Ligand‐ and Metal‐Centered Phosphorescence in a Terbium Carbazolyl Complex

open access: yesChemistry – A European Journal, EarlyView.
Terbium and lanthanum carbazolide complexes show two distinct modes of luminescence: Strongly temperature‐dependent narrow‐line terbium emission could be induced. In addition, both the terbium and the lanthanum complexes show broad‐line interligand emission processes with excited states of microsecond life‐time.
Xiaofei Sun   +9 more
wiley   +1 more source

Domino ring-opening metathesis–ring-closing metathesis of bicyclo[2.2.2]octene derivatives: scope and limitations

open access: yes, 2012
Domino metathesis involving ring-opening metathesis–ring-closing metathesis (ROM–RCM) of a bicyclo[2.2.2]octene derivative having an appropriate alkene chain, expected to produce a 7/6 fused bicyclic system, provided a decalin system in contrast to ROM ...
Bose, Sritama   +2 more
core   +1 more source

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