Results 21 to 30 of about 2,114 (259)

Selective ring-opening metathesis polymerization (ROMP) of cyclobutenes. Unsymmetrical ladderphane containing polycyclobutene and polynorbornene strands

open access: yesBeilstein Journal of Organic Chemistry, 2019
At 0 °C in THF in the presence of Grubbs first generation catalyst, cyclobutene derivatives undergo ROMP readily, whereas norbornene derivatives remain intact. When the substrate contains both cyclobutene and norbornene moieties, the conditions using THF
Yuan-Zhen Ke   +3 more
doaj   +1 more source

Translation, linguistic and cultural adaptation, reliability and validity of the Radboud Oral Motor Inventory for Parkinson's Disease – ROMP questionnaire

open access: yesArquivos de Neuro-Psiquiatria
Objective: To translate and linguistically and culturally adapt to Brazilian Portuguese, and verify the reliability and validity of the Radboud Oral Motor Inventory for Parkinson's Disease (ROMP).
Monia Presotto   +3 more
doaj   +1 more source

ROMP‐based boron nitride composites

open access: yesJournal of Applied Polymer Science, 2017
ABSTRACTThe present work focuses on the investigation of the thermal and dielectric properties of composites obtained by surface‐modified hexagonal boron nitride (hBN) and ring‐opening metathesis polymerization (ROMP) based polymer. A new kind of high performance composites was developed based on using amino silane functionalized hBN (AS‐hBN) and ...
Keziban Hüner   +4 more
openaire   +4 more sources

Simple activation by acid of latent Ru-NHC-based metathesis initiators bearing 8-quinolinolate co-ligands

open access: yesBeilstein Journal of Organic Chemistry, 2016
A straightforward synthesis utilizing the ring-opening metathesis polymerization (ROMP) reaction is described for acid-triggered N,O-chelating ruthenium-based pre-catalysts bearing one or two 8-quinolinolate ligands.
Julia Wappel   +4 more
doaj   +1 more source

Branched Polymers via ROMP of Termimers [PDF]

open access: yesMacromolecular Rapid Communications, 2016
Today's olefin metathesis catalysts show high reactivity, selectivity, and functional group tolerance and allow the design of new syntheses of precisely functionalized polymers. Here the synthesis of a new end-capping reagent is investigated allowing the introduction of a highly reactive activated ester end-group at the polymer chain end as well as its
Hanik Nils, Kilbinger A.F.M.
openaire   +3 more sources

Application of olefin metathesis in the synthesis of functionalized polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials

open access: yesBeilstein Journal of Organic Chemistry, 2019
This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials.
Patrycja Żak, Cezary Pietraszuk
doaj   +1 more source

In Situ Study of Resistive Switching in a Nitride‐Based Memristive Device

open access: yesAdvanced Functional Materials, EarlyView.
In situ TEM biasing experiment demonstrates the volatile I‐V characteristic of MIM lamella device. In situ STEM‐EELS Ti L2/L3 ratio maps provide direct evidence of the oxygen vacancies migrations under positive/negative electrical bias, which is critical for revealing the RS mechanism for the MIM lamella device.
Di Zhang   +19 more
wiley   +1 more source

Chemoselective Sequential Polymerization: An Approach Toward Mixed Plastic Waste Recycling

open access: yesAdvanced Functional Materials, EarlyView.
Inspired by biological protein metabolism, this study demonstrates the closed‐loop recycling of mixed synthetic polymers via ring‐closing depolymerization followed by a chemoselective sequential polymerizations process. The approach recovers pure polymers from mixed feedstocks, even in multilayer formats, highlighting a promising strategy to overcome a
Gadi Slor   +5 more
wiley   +1 more source

Development and testing of a novel survey to assess Stakeholder-driven Community Diffusion of childhood obesity prevention efforts

open access: yesBMC Public Health, 2018
Background Involving groups of community stakeholders (e.g., steering committees) to lead community-wide health interventions appears to support multiple outcomes ranging from policy and systems change to individual biology.
Ariella R. Korn   +12 more
doaj   +1 more source

SI‐bioATRP in Mesoporous Silica for Size‐Exclusion Driven Local Polymer Placement

open access: yesAdvanced Functional Materials, EarlyView.
An enzyme‐catalyzed surface‐initiated atom transfer radical polymerization (SI‐bioATRP) of an anionic monomer within mesoporous silica particles, using hemoglobin as a catalyst, allows for controlling the location of the formed polymer via size‐exclusion effects between the nanopores and the biomacromolecules, thereby opening routes to functional ...
Oleksandr Wondra   +8 more
wiley   +1 more source

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