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Electrochemical Reactivity in Room-Temperature Ionic Liquids

Chemical Reviews, 2008
A review. Physicochem. properties of ionic liqs. are discussed. Chem. and electrochem. reactivity in ionic liqs. is described including electrode reactions, electrode reaction kinetics, electrosynthesis, etc.
Hapiot, Philippe, Lagrost, Corinne
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Gas–liquid interface of room-temperature ionic liquids

Chemical Society Reviews, 2010
The organization of ions at the interface of ionic liquids and the vacuum is an ideal system to test new ideas and concepts on the interfacial chemistry of electrolyte systems in the limit of no solvent medium. Whilst electrolyte systems have numerous theoretical and experimental methods used to investigate their properties, the ionic liquids are ...
Cherry S, Santos, Steven, Baldelli
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Sonochemistry and Sonoluminescence of Room-Temperature Ionic Liquids

Journal of the American Chemical Society, 2003
The sonication of ionic organic liquids leads to decomposition of the liquids. Multibubble sonoluminescence spectra and headgas analysis reveal a variety of decomposition products from the sonolysis of N,N'-dialkylimidazolium ionic liquids. The decomposition is a result of acoustic cavitation, which generates localized hot spots from the implosive ...
James D, Oxley   +2 more
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Viscoelastic properties of room temperature ionic liquids

The Journal of Chemical Physics, 2008
The sound absorption coefficient α and sound velocity νS have been measured for 1-alkyl-3-methylimidazolium hexafluorophosphate [Cnmim]PF6, with n=8,6,4 and 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide [C4 mim]TFSI, at the frequencies of 11.3, 34.9, and 57.7MHz in the temperature range from 293to393K. From the obtained α and available
Wataru, Makino   +4 more
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Quinones Electrochemistry in Room-Temperature Ionic Liquids

The Journal of Physical Chemistry B, 2010
The two-step electrochemical reduction of tetrachloro-1,2-benzoquinone (chloranil), 2-methyl-1,2-benzoquinone (toluquinone), and 9,10-anthraquinone in two room-temperature ionic liquids is addressed by means of voltammetry on a platinum electrode. For the subsequent quinone/radical anion (Q/Q(•-)) and radical anion/dianion (Q(•-)/Q(2-)) redox reactions,
Viktoriya A, Nikitina   +2 more
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Surface chemistry of room-temperature ionic liquids

Physical Chemistry Chemical Physics, 2007
In many applications of room-temperature ionic liquids, it has been recognized that the interface is a vital component. In electrochemistry, for instance, the electron transfer is significant to the efficiency of the solar cell and is very much dependent on the behavior of a given interface.
Cesar, Aliaga   +2 more
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Synthesis and Catalysis in Room-Temperature Ionic Liquids

ChemInform, 2002
AbstractFor Abstract see ChemInform Abstract in Full Text.
P. J. Smith, A. Sethi, T. Welton
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Vaporisation of an ionic liquid near room temperature

Physical Chemistry Chemical Physics, 2010
The temperature at which the vapour phase of the ionic liquids (ILs) 1-ethyl-3-methylimidazolium bis[(trifluoromethane)sulfonyl]imide, [C(2)C(1)Im][Tf(2)N], and 1-ethyl-3-methylimidazolium ethylsulfate, [C(2)C(1)Im][EtOSO(3)], can be detected was investigated using line-of-sight mass spectrometry (LOSMS).
Kevin R J, Lovelock   +3 more
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Structure of room temperature ionic liquids

Journal of Physics: Condensed Matter, 2016
The structure of room temperature ionic liquids is studied using molecular dynamics simulations and integral equation theory. Three ionic liquids 1-alkyl-3-methylimidazolium hexfluorophosphate, [C n MIM] [PF6], for n  =  1, 4, and 8, are studied using a united atom model of the ions. The primary interest is a study of the pair correlation functions and
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Novel Room Temperature Inorganic Ionic Liquids

European Journal of Inorganic Chemistry, 2004
AbstractNew inorganic ionic liquids (IIL) consisting of an inorganic polyoxometalate anion with the Keggin structure and a sodium cation, that is Na13[Ln(TiW11O39)2]·xH2O [where Ln = lanthanide (type 1)], Na5[MTiW11O39]·xH2O and Na6[MTiW11O39]·xH2O [where M = transition metal (type 2)], were prepared and their physicochemical properties were ...
Liyi Dai   +3 more
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