Results 31 to 40 of about 3,012,302 (181)

Feedback Optimization Strategy for Rotational Alignment Echo Spectroscopy

open access: yesAdvanced Photonics Research, 2023
The recent discovery of rotational echoes has contributed to extend the applications of field‐free molecular alignment to short time scales, namely to a temporal region preceding the first alignment revival of the molecule. Most echo measurements require
Manon Bournazel   +5 more
doaj   +1 more source

From the laboratory to the interstellar medium: a strategy to search for exotic molecules in space

open access: yesFrontiers in Astronomy and Space Sciences, 2023
The chemistry of the interstellar medium occurs under extreme conditions and can lead to the formation of exotic molecules. These are species that on Earth are unstable and/or highly reactive. Their discovery in space is usually based on the astronomical
Cristina Puzzarini   +4 more
doaj   +1 more source

Accuracy Meets Interpretability for Computational Spectroscopy by Means of Hybrid and Double-Hybrid Functionals

open access: yesFrontiers in Chemistry, 2020
Accuracy and interpretability are often seen as the devil and holy grail in computational spectroscopy and their reconciliation remains a primary research goal.
Vincenzo Barone   +3 more
doaj   +1 more source

Spectroscopic Characterization of 3-Aminoisoxazole, a Prebiotic Precursor of Ribonucleotides

open access: yesMolecules, 2022
The processes and reactions that led to the formation of the first biomolecules on Earth play a key role in the highly debated theme of the origin of life.
Alessio Melli   +8 more
doaj   +1 more source

Seven Conformations of the Macrocycle Cyclododecanone Unveiled by Microwave Spectroscopy

open access: yesMolecules, 2021
The physicochemical properties and reactivity of macrocycles are critically shaped by their conformations. In this work, we have identified seven conformations of the macrocyclic ketone cyclododecanone using chirped-pulse Fourier transform microwave ...
Ecaterina Burevschi, M. Eugenia Sanz
doaj   +1 more source

The challenging playground of astrochemistry: an integrated rotational spectroscopy - quantum chemistry strategy.

open access: yesPhysical Chemistry, Chemical Physics - PCCP, 2020
While it is now well demonstrated that the interstellar medium (ISM) is characterized by a diverse and complex chemistry, a significant number of features in radioastronomical spectra are still unassigned and call for new laboratory efforts, which are ...
C. Puzzarini, V. Barone
semanticscholar   +1 more source

Accurate Molecular Structure Determination by Femtosecond Degenerate Four-Wave Mixing

open access: yesCHIMIA, 2006
Femtosecond degenerate four-wave mixing (fs-DFWM) is a Raman scattering type of rotational coherence spectroscopy that can be utilized for the measurement of highly accurate rotational and centrifugal constants of nonpolar molecules.
Dominique S. Kummli   +2 more
doaj   +1 more source

Skeletal Torsion Tunneling and Methyl Internal Rotation: The Coupled Large Amplitude Motions in Phenyl Acetate

open access: yesMolecules, 2022
The rotational spectrum of phenyl acetate, CH3COOC6H5, is measured using a free jet absorption millimeter-wave spectrometer in the range from 60 to 78 GHz and two pulsed jet Fourier transform microwave spectrometers covering a total frequency range from ...
Lynn Ferres   +6 more
doaj   +1 more source

The Conformations of Isolated Gallic Acid: A Laser-Ablation Rotational Study

open access: yesMolecules, 2022
The rotational spectrum of laser-ablated gallic acid has been recorded using CP-FTMW spectroscopy. Two rotamers have been detected, and their rotational spectra have been assigned and analyzed to obtain the molecular spectroscopic parameters.
Andrés Verde   +2 more
doaj   +1 more source

Terahertz Rotational Spectroscopy [PDF]

open access: yesProceedings of the International Astronomical Union, 2005
The detection of interstellar molecules relies on the precise knowledge of spectral line positions from laboratory measurements. Technical developments of recent years have led to an extension of the accessible spectral range towards shorter wavelengths. New telescopes like SOFIA, the HIFI instrument aboard the Herschel satellite, and ALMA will be used
T. F. Giesen   +6 more
openaire   +1 more source

Home - About - Disclaimer - Privacy