Results 51 to 60 of about 40,348 (311)

The Adsorption of Ru-Based Dyes on the TiO2 Surface to Enhance the Photovoltaic Efficiency of Dye-Sensitized Solar Cell Devices

open access: yesMolecules
Adsorption of mononuclear tris(bipyridine) ruthenium(II) complexes and binuclear tris(bipyridine) ruthenium(II) complexes equipped with carboxyl groups (-COOH) on the (111) surface of TiO2 crystal in anatase form was modeled using Monte Carlo simulations,
Malgorzata Makowska-Janusik   +4 more
doaj   +1 more source

Preparation of Ruthenium Dithiolene Complex/Polysiloxane Films and Their Responses to CO Gas

open access: yesMolecules, 2018
To develop advanced materials using metal complexes, it is better to prepare metal complexes contained in composite or hybrid films. To achieve this purpose, we synthesized ruthenium complexes with dihalogen-substituted benzendithiolate ligands, [(η6 ...
Satoru Tsukada   +3 more
doaj   +1 more source

Toward Fast Proton Shuttling in Acidic Oxygen Evolution Reaction

open access: yesAdvanced Functional Materials, EarlyView.
This review establishes proton transfer dynamics as a descriptor governing acidic OER activity, moving beyond the kinetic constraints derived from the proton coupled electron transfer. We discuss how deprotonation governs classical mechanisms, including adsorbate evolution mechanism (AEM), lattice oxygen mechanism (LOM) and oxide path mechanism (OPM ...
Ashish Gaur   +3 more
wiley   +1 more source

Ammine Complexes of Ruthenium

open access: yesPlatinum Metals Review, 1969
Ammines not previously described, and simple routes to others which have earlier been difficult to prepare, have been discovered as a result of the isolation of the bivalent ruthenium ammine hexammineruthenium(II) chloride and a study of its reactions. Certain of these compounds could have commercial significance, for example in electrodeposition or in
F. M. Lever, A. R. Powell
openaire   +2 more sources

SYNTHESIS AND CHARACTERIZATION OF FULLERENE-PYRIDYL ARENE RUTHENIUM COMPLEXES

open access: yesStudia Universitatis Babes-Bolyai Chemia, 2015
Association of [60]fullerene with arene ruthenium moieties has been achieved for the first time. Two fullerenopyrrolidine derivatives (Npyr-C60) were synthesized via a 1,3-dipolar cycloaddition, and coordinated to arene ruthenium complexes to form two ...
Divambal APPAVOO   +2 more
doaj  

Ruthenium-based complexes as anti-tumor agents

open access: yesJournal of Health Sciences
Extensive research into platinum-based chemotherapeutics has been underway for decades with ruthenium-based complexes emerging as interesting and potent candidates.
Amir Herić   +5 more
doaj   +1 more source

Ruthenium Polypyridine Complexes Combined with Oligonucleotides for Bioanalysis: A Review

open access: yesMolecules, 2014
Ruthenium complexes are among the most interesting coordination complexes and they have attracted great attention over the past decades due to their appealing biological, catalytic, electronic and optical properties.
Shuyu Zhang, Yubin Ding, Hui Wei
doaj   +1 more source

Chiral ruthenium(II) polypyridyl complexes: stabilization of g-quadruplex DNA, inhibition of telomerase activity and cellular uptake. [PDF]

open access: yesPLoS ONE, 2012
Two ruthenium(II) complexes, Λ-[Ru(phen)(2)(p-HPIP)](2+) and Δ-[Ru(phen)(2)(p-HPIP)](2+), were synthesized and characterized via proton nuclear magnetic resonance spectroscopy, electrospray ionization-mass spectrometry, and circular dichroism ...
Qianqian Yu   +6 more
doaj   +1 more source

Support‐Controlled Reaction Pathways via Dynamic Sulfur‐Mediated Interfaces for Selective Urea Electrolysis

open access: yesAdvanced Functional Materials, EarlyView.
Sulfur‐doped graphitized carbon nanofibers act as adaptive catalyst–support platforms, enabling dynamic sulfur‐mediated reconstruction and strong metal–support interactions. This unique behavior enhances catalyst stability and controls reaction pathways, achieving highly selective urea oxidation (∼92% N2) coupled with efficient hydrogen evolution ...
Melanie Guillén‐Soler   +4 more
wiley   +1 more source

Probing ground and excited state properties of ruthenium (II) and osmium (II) polypyridyl complexes [PDF]

open access: yes, 2002
The area of ruthenium(H) and osmium(H) polypyridyl chemistry has been the subject of intense investigation over the last half century. In chapter 1, topics relevant to the studies presented in this thesis are introduced.
Browne, Wesley R.
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