Results 41 to 50 of about 40,348 (311)

Revisiting Stability Criteria in Ball‐Milled High‐Entropy Alloys: Do Hume–Rothery and Thermodynamic Rules Equally Apply?

Advanced Engineering Materials, Volume 27, Issue 6, March 2025.
The stability criteria affecting the formation of high‐entropy alloys, particularly focusing in supersaturated solid solutions produced by mechanical alloying, are analyzed. Criteria based on Hume–Rothery rules are distinguished from those derived from thermodynamic relations. The formers are generally applicable to mechanically alloyed samples.
Javier S. Blázquez, Alejandro F. Manchón‐Gordón, Antonio Vidal‐Crespo, Rafael Caballero‐Flores, Jhon J. Ipus, Clara F. Conde   +5 more
wiley   +1 more source

Synthesis and characterisation of Ruthenium(II) tris(heteroleptic) complexes containing a triazole ligand [PDF]

, 2003
The synthesis, spectroscopic and electrochemical characterisation of Ru(II) tris(heteroleptic) mononuclear and dinuclear complexes are described. Special attention is paid to the introduction of a triazole ligand to the metal sphere.
Mulhern, Declan
core  

Photocatalytic Atom Transfer Radical Addition to Olefins Utilizing Novel Photocatalysts

Molecules, 2019
Photocatalysis is a rapidly evolving area of research in modern organic synthesis. Among the traditional photocatalysts, metal-complexes based on ruthenium or iridium are the most common.
Errika Voutyritsa, Ierasia Triandafillidi, Nikolaos V. Tzouras, Nikolaos F. Nikitas, Eleftherios K. Pefkianakis, Georgios C. Vougioukalakis, Christoforos G. Kokotos   +6 more
doaj   +1 more source

Emerging Molecular Receptors for the Specific-Target Delivery of Ruthenium and Gold Complexes into Cancer Cells

Molecules, 2021
Cisplatin and derivatives are highly effective in the treatment of a wide range of cancer types; however, these metallodrugs display low selectivity, leading to severe side effects.
João Franco Machado, João D. G. Correia, Tânia S. Morais   +2 more
doaj   +1 more source

Field Report from Collaborative Research Center 1625: Heterogeneous Research Data Management Using Ontology Representations

Advanced Engineering Materials, EarlyView.
A unified research data management framework for heterogeneous materials data is presented. The system integrates multimodal datasets using ontologies and knowledge graphs, enabling interoperability and FAIR (findable, accessible, interoperable, reusable) data principles. By linking data across scales and workflows, it supports reproducible, Artifitial
Doaa Mohamed, Samuel García Vázquez, Behnam Mardani, Victor Dudarev, Alfred Ludwig, Maribel Acosta, Markus Stricker   +6 more
wiley   +1 more source

Dinuclear thiolato-bridged arene ruthenium complexes: from reaction conditions and mechanism to synthesis of new complexes

, 2020
Several dinuclear thiophenolato-bridged arene ruthenium complexes [(η(6)-p-MeC(6)H(4)Pr(i))(2)Ru(2)(μ(2)-SC(6)H(4)-R)(3)](+) (R = H, NO(2), F) could so far only be obtained in fair yields using the synthetic route established in the early 2000s.
Ninova, Silviya, Primasová, Hedvika, Furrer, Julien, De Capitani, Mario, Daepp, Jana, Aschauer, Ulrich   +5 more
core   +1 more source

Magnetic‐Field Control of Surface States in CoFe2O4 Thin Films for Nitrate Electroreduction to Ammonia

Advanced Functional Materials, EarlyView.
Magnetic‐field‐assisted CVD of heterometallic single‐source precursors modulates thin‐film surface electronic structure and interfacial charge transfer. Field‐grown (Cobalt ferrite‐1T)CF‐1T films exhibit stabilized electronic states, lower kinetic barriers, and markedly enhanced nitrate‐to‐ammonia electrocatalysis versus (Cobalt ferrite‐0T) CF‐0T ...
Touraj Karimpour, Younes Mousazade, Simon Diel, Shilendra Kumar Sharma, Tisita Das, Nathália C. Verissimo, Thomas Fischer, Ziyaad Aytuna, Andreas Lichtenberg, Sudip Chakraborty, Marcel Risch, Sanjay Mathur   +11 more
wiley   +1 more source

Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

, 2014
Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes ...
Sinopoli, Alessandro, Uppal, Baljinder S., Welby, Christine E., Bartley, Harry, Armitage, Georgina K., Elliott, Paul I P, Elliott, Paul I.   +6 more
core   +1 more source

Ultrasmall High‐Entropy Materials: Nanoscale Effects, Synthesis, and Mechanistic Insights

Advanced Functional Materials, EarlyView.
This review article focuses on sub‐10 nm high‐entropy materials that combine nanoscale design with complex compositions for next‐generation applications. ABSTRACT Ultrasmall high‐entropy nanomaterials (USHENMs, <10 nm) merge multicomponent chemistry with size‐dependent effects, forming a distinct class of materials with unprecedented properties.
Yueyue He, Wenbo Wang, Simon Schweidler, Yanjiao Ma, Ben Breitung, Torsten Brezesinski   +5 more
wiley   +1 more source

Natureza da ligação Ru-NO em novos nitrosilo complexos de rutênio com ligantes quelantes CCC e CNC contendo carbenos [PDF]

, 2015
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2015.Compostos capazes de liberar ou sequestrar óxido nítrico são promissores agentes ...
Coimbra, Daniel Fernando
core