Atomic Layer Deposition of Metallic Molybdenum Dioxide Thin Films Enabling High‐k Rutile Capacitors
Advanced Materials Interfaces, EarlyView.The first direct atomic layer deposition (ALD) process of molybdenum dioxide (MoO2) thin films is reported using molybdenum(II) acetate dimer (Mo2(OAc)4) and oxygen (O2) as precursors at 235°C–275°C. The films are crystalline, exceptionally pure, and conductive.
Alexey Ganzhinov +8 more
wiley +1 more source
Stabilizing Electrochemical Interfaces With Multifunctional Cobalt Nitride Layers
Advanced Materials Interfaces, EarlyView.Cobalt nitrides emerged recently as an interesting class of earth‐abundant oxygen evolution catalysts. Herein, plasma‐enhanced atomic layer deposition is used to synthesize multifunctional cobalt nitride layers that simultaneously protect and catalytically activate photoelectrode surfaces.
Matthias Kuhl +7 more
wiley +1 more source
Sensitive and Spatially‐Resolved Electrochemiluminescence via Micropatterning
Advanced Materials Interfaces, EarlyView.The use of a simple silica nanoparticle surface coating and patterning process can transform ordinary gold electrodes into multiplexed ECL sensing electrodes. Through spatially confined droplet formation and local ECL emission, it is possible to perform multiple analyses simultaneously from individual locations as well as intensify the ECL signal by as
Yuliang Shao +12 more
wiley +1 more source
Xenes for Sustainable Energy: A Roadmap From First‐Principles Design to Practical Deployment
Advanced Materials Interfaces, EarlyView.Emerging 2D Xenes are advancing from theoretical predictions toward practical energy‐storage and conversion technologies through the integration of first‐principles modelling, experimental synthesis, electrochemical validation, and AI‐assisted materials design, enabling accelerated discovery of high‐performance and sustainable electrochemical systems ...
Onur Karaman, Ceren Karaman
wiley +1 more source
Ruthenium(II)-enabled para-selective C–H difluoromethylation of anilides and their derivatives
Nature Communications, 2018 Selective para-functionalization of substituted arenes is a formidable challenge in homogeneous catalysis. Here, the authors achieved the para-selective C-H difluoromethylation of anilides, indolines and tetrahydroquinolines with a ruthenium catalyst in ...
Chunchen Yuan +6 more
doaj +1 more source
Light Switchable Ionic Conductivity of Arylazopyrazole Modified Polysiloxanes
Advanced Materials Technologies, EarlyView.We present a polysiloxane functionalized with a novel arylazopyrazole dye that undergoes reversible photoisomerization. Upon lithium bis(trifluoromethanesulfonyl)imide addition and UV irradiation, the polymer exhibits a shift in tan(d) toward higher frequencies and enhanced ionic conductivity.
Malte S. Beccard +7 more
wiley +1 more source
High mass accuracy analytical applications of Fourier transform ion cyclotron resonance mass spectrometry [PDF]
The performance capabilities of Fourier transform ion cyclotron resonance (FTICR) mass spectrometry are higher than any other type of mass spectrometer, making this technique suitable for a range of analytical applications.
Wills, Rebecca Helen
core
Síntese e estudo das propriedades fotofísicas do ligante [1,2,5]selenodiazol[3,4-F][1,10]fenantrolina e seus complexos de ferro (II) e európio (III) [PDF]
, 2015 Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2015.Nesta tese de doutorado foi aprimorada a metodologia para o preparo do ligante [1,2,5 ...
Braga, Hugo de Campos
core
Synthesis of the ruthenium (II) compounds containing the pic ligand.
, 2013 Synthesis of the ruthenium (II) compounds containing the pic ligand.
Gustavo V. Poelhsitz (416074) +11 more
core +1 more source
, 2020 Ruthenium organometallic compounds represent an attractive avenue in developing alternatives to platinum-based chemotherapeutic agents. While evidence has been presented indicating ruthenium-based compounds interact with isolated DNA in vitro, it is ...
Niece, Madison B +5 more
core +1 more source