Results 101 to 110 of about 29,055 (307)

X-ray K-absorption studies of some ruthenium compounds

open access: yes, 1974
X-ray K-absorption studies of ruthenium in ruthenium metal,RuO2, K2(RuCl6) and K 4[Ru(CN)6]: 3H2O have been carried out using 400 mm bent crystal (mica) spectrograph.
Bhide, V. G., Kaicker, S. K.
core   +1 more source

Giant Orbital Rashba–Edelstein Effect in Crystalline Cu2O/Cu Heterostructures

open access: yesAdvanced Materials, EarlyView.
An enhanced orbital Rashba–Edelstein effect is demonstrated in a crystalline Cu2O/Cu heterostructure, compared to naturally oxidized CuOx structures, highlighting the critical role of crystallinity and interface control in orbital torque generation. The resulting spin torque conductivity exceeds that of Pt, indicating the potential of orbital torque ...
San Ko   +10 more
wiley   +1 more source

Light-responsive and Protic Ruthenium Compounds Bearing Bathophenanthroline and Dihydroxybipyridine Ligands Achieve Nanomolar Toxicity towards Breast Cancer Cells. [PDF]

open access: yesPhotochem Photobiol, 2022
Oladipupo OE   +17 more
europepmc   +1 more source

Machine Learning Accelerated Computational Design of Bio‐Inspired Catalysts in the Nitrogen Reduction Reaction

open access: yesAdvanced Materials, EarlyView.
We introduce a computational workflow that combines quantum chemical calculations and machine learning techniques to predict the catalytic performance of a wide range of catalysts in the nitrogen reduction reaction (NRR). The analysis of the trained models provides insights into the complex structure–activity relationship in experimental catalytic ...
Leonardo Di Ciano   +5 more
wiley   +1 more source

Synthesis and Characterization of Carbonyl–Ruthenium Trisubstituted-Germylene Compounds

open access: yesHeteroatom Chemistry
Owing to the remarkable physical properties and versatile chemistry of germanium, the synthesis of ruthenium–germylene compounds offers broad application potential and addresses important practical demands.
Peng Nie, Zhong-yu Xia
doaj   +1 more source

Synthesis and characterisation of Ruthenium(II) tris(heteroleptic) complexes containing a triazole ligand [PDF]

open access: yes, 2003
The synthesis, spectroscopic and electrochemical characterisation of Ru(II) tris(heteroleptic) mononuclear and dinuclear complexes are described. Special attention is paid to the introduction of a triazole ligand to the metal sphere.
Mulhern, Declan
core  

Co1/Ru Single‐Atom Alloy Catalyst for Sustainable Polypropylene Hydrogenolysis to Long‐Chain Liquid Products

open access: yesAdvanced Materials, EarlyView.
A titania‐supported Co1/Ru single‐atom alloy catalyst enables efficient polypropylene hydrogenolysis. Ru─Co─Ru motifs maintain Ru activity while suppressing excessive chain scission to gaseous products. Both virgin and waste plastics achieve high, environmentally and economically optimal C11+ liquid yields, supporting sustainable chemical recycling ...
Yuzhen Ge   +6 more
wiley   +1 more source

Organometallic half-sandwich iridium anticancer complexes [PDF]

open access: yes, 2011
The low-spin 5d6 IrIII organometallic half-sandwich complexes [(η5-Cpx)Ir(XY)Cl]0/+, Cpx = Cp*, tetramethyl(phenyl)cyclopentadienyl (Cpxph), or tetramethyl(biphenyl)cyclopentadienyl (Cpxbiph), XY = 1,10-phenanthroline (4−6), 2,2′-bipyridine (7−9 ...
Liu, Zhe   +34 more
core   +1 more source

Engineering CO2 Reduction Pathways via Alloy‐Support Interactions in Li‐CO2 Batteries

open access: yesAdvanced Materials, EarlyView.
Alloy‐support interactions in RuCu/NC induce interfacial charge redistribution and shift d‐band centers, steering CO2 reduction from Li2CO3 to metastable Li2C2O4. This pathway engineering lowers the rate‐determining barrier and suppresses carbonate formation, enabling high discharge voltage (3.23 V) in Li‐CO2 batteries with reduced overpotential (0.50 ...
Liang Sun   +8 more
wiley   +1 more source

Electrophilic Catalysis in Iodosylbenzene Oxidation of Aromatic Derivatives

open access: yesCHIMIA, 1986
The oxidation of activated aromatic compounds (phenols and hydroquinones) is catalyzed by BF3 or RuCl2(PPh3)3. The catalytic effect of the ruthenium is ascribed to electrophilic catalysis, due to complexation between iodosylbenzene and the Ru species ...
Paul Müller, David Manuel Gilabert
doaj   +1 more source

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