Results 71 to 80 of about 21,947 (264)

Empowering alcohols as carbonyl surrogates for Grignard-type reactions

Nature Communications, 2020
Alcohols are more naturally abundant than carbonyl compounds, which in turn are well known for their reactivity in Grignard reactions. Here, the authors showcase a distinct Grignard-like reactivity by using alcohols as coupling partners with hydrazones ...
Chen-Chen Li, Haining Wang, Malcolm M. Sim, Zihang Qiu, Zhang-Pei Chen, Rustam Z. Khaliullin, Chao-Jun Li   +6 more
doaj   +1 more source

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

Advanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen, Zhanxi Fan, Jingjie Ge, Qiyuan He, Zhuangchai Lai, Jiawei Liu, Chaoliang Tan, Hua Zhang   +7 more
wiley   +1 more source

Biomolecular Interactions of Cytotoxic Ruthenium Compounds with Thiosemicarbazone or Benzothiazole Schiff Base Chelates. [PDF]

ChemMedChem, 2022
Maikoo S, Xulu B, Mambanda A, Mkhwanazi N, Davison C, de la Mare JA, Booysen IN.   +6 more
europepmc   +1 more source

Laplace‐Pressure‐Stabilized Rutile Solid‐Solution Catalysts for Acidic Water Oxidation: Enabling DSA‐Inspired Compositions

Advanced Materials, EarlyView.
The miscibility of foreign elements in rutile‐type IrO2 and SnO2 is greatly enhanced under high Laplace pressure, where their crystal size is reduced to the nanoscale. This enhancement leads to the successful synthesis of DSA‐composition solid‐solution nanocatalysts with notable durability during the acidic OER in water electrolysis.
Chang Hyun Park, Juneseo Ahn, Dongho Kim, Hyeonsoo Wi, Ki Hyun Park, Jun Seop Kim, Sangmyeong Lee, Sung‐Yoon Chung   +7 more
wiley   +1 more source

Photoinduced DNA Cleavage and Photocytotoxic of Phenanthroline-Based Ligand Ruthenium Compounds. [PDF]

Molecules, 2021
Hu X, Liu NY, Deng YQ, Wang S, Liu T, Liu XW.   +5 more
europepmc   +1 more source

Lead Halide Perovskite Photoelectrocatalysis

Advanced Materials, EarlyView.
Lead halide perovskite semiconductors have emerged as highly promising materials for solar fuel and chemical synthesis. This perspective discusses advances made in the rational photoelectrode design to improve solar‐to‐chemical conversion, product scope, and scalability.
Virgil Andrei
wiley   +1 more source

Light-responsive and Protic Ruthenium Compounds Bearing Bathophenanthroline and Dihydroxybipyridine Ligands Achieve Nanomolar Toxicity towards Breast Cancer Cells. [PDF]

Photochem Photobiol, 2022
Oladipupo OE, Brown SR, Lamb RW, Gray JL, Cameron CG, DeRegnaucourt AR, Ward NA, Hall JF, Xu Y, Petersen CM, Qu F, Shrestha AB, Thompson MK, Bonizzoni M, Webster CE, McFarland SA, Kim Y, Papish ET.   +17 more
europepmc   +1 more source

Giant Orbital Rashba–Edelstein Effect in Crystalline Cu2O/Cu Heterostructures

Advanced Materials, EarlyView.
An enhanced orbital Rashba–Edelstein effect is demonstrated in a crystalline Cu2O/Cu heterostructure, compared to naturally oxidized CuOx structures, highlighting the critical role of crystallinity and interface control in orbital torque generation. The resulting spin torque conductivity exceeds that of Pt, indicating the potential of orbital torque ...
San Ko, Jaimin Kang, Su Jae Kim, Hanhwi Jang, Do‐Kyeong Nam, Minseok Kang, Sunghoon Kim, Yeon Sik Jung, Se‐Young Jeong, Kab‐Jin Kim, Byong‐Guk Park   +10 more
wiley   +1 more source

Uniaxial Stress Enhanced Anisotropic Magnetoresistance and Superconductivity in the Kagome Superconductor LaRu3Si2

Advanced Materials, EarlyView.
We identify strong anisotropy in the upper critical field and magnetoresistance in the kagome superconductor LaRu3Si2, revealing pronounced electronic anisotropy. Uniaxial stress enhances magnetoresistance and Tc, with a positive correlation suggesting an electronic pairing mechanism.
P. Kral, V. Sazgari, Y. Ge, O. Gerguri, M. Spitaler, J.N. Graham, H. Nakamura, M. Bartkowiak, S. Nakatsuji, H. Luetkens, G. Simutis, G. Xu, Z. Guguchia   +12 more
wiley   +1 more source

Synthesis and Characterization of Carbonyl–Ruthenium Trisubstituted-Germylene Compounds

Heteroatom Chemistry
Owing to the remarkable physical properties and versatile chemistry of germanium, the synthesis of ruthenium–germylene compounds offers broad application potential and addresses important practical demands.
Peng Nie, Zhong-yu Xia
doaj   +1 more source