Results 61 to 70 of about 29,055 (307)

Advancing Tandem Organic Solar Cells With Ternary Acceptor Control for High‐Power Modules and Solar‐to‐Ammonia Conversion

open access: yesAdvanced Functional Materials, EarlyView.
Tandem organic solar cells with optimized ternary acceptor engineering achieved a power conversion efficiency of 15.53% and enabled a high‐voltage mini‐module (Voc 6.11 V). Integration into a bias‐free PV‐EC system further demonstrated efficient solar‐to‐ammonia (STA) conversion (97% Faradaic Efficiency, 4± 2% STA efficiency), highlighting scalable ...
Seyeong Song   +11 more
wiley   +1 more source

Syntheses of Macromolecular Ruthenium Compounds: A New Approach for the Search of Anticancer Drugs

open access: yesInorganics, 2014
The continuous rising of the cancer patient death rate undoubtedly shows the pressure to find more potent and efficient drugs than those in clinical use.
Andreia Valente, M. Helena Garcia
doaj   +1 more source

Construction of emissive ruthenium(II) metallacycle over 1000 nm wavelength for in vivo biomedical applications

open access: yesNature Communications, 2022
Ruthenium (Ru(II)) compounds are of interest as platinum drug replacements but have suffered from suboptimal therapeutic efficiency. Here, the authors design a Ru(II) metallacycle with NIR excitation and emission wavelengths and demonstrate application ...
Yuling Xu   +7 more
doaj   +1 more source

Toward Fast Proton Shuttling in Acidic Oxygen Evolution Reaction

open access: yesAdvanced Functional Materials, EarlyView.
This review establishes proton transfer dynamics as a descriptor governing acidic OER activity, moving beyond the kinetic constraints derived from the proton coupled electron transfer. We discuss how deprotonation governs classical mechanisms, including adsorbate evolution mechanism (AEM), lattice oxygen mechanism (LOM) and oxide path mechanism (OPM ...
Ashish Gaur   +3 more
wiley   +1 more source

Ruthenium(II)–Cyclopentadienyl-Derived Complexes as New Emerging Anti-Colorectal Cancer Drugs

open access: yesPharmaceutics, 2022
Colorectal cancer (CRC) is one of the most common malignancies and one of the leading causes of cancer-related death worldwide, urging the need for new and more efficient therapeutic approaches. Ruthenium complexes have emerged as attractive alternatives
Catarina Teixeira-Guedes   +4 more
doaj   +1 more source

Coupling Anodic Activity and Stability at Ni‐Based Non‐Oxide Catalysts via Coordinating Alcohol Oxidation and Oxygen Evolution

open access: yesAdvanced Functional Materials, EarlyView.
A cooperative and competitive interrelationship between alcohol oxidation (AOR) and water oxidation (OER) was observed on a typical anode catalyst of Ni2P. In situ Raman spectroscopy and electrochemical analyses revealed a specific complementary mechanism between them, in which OER and AOR critically contribute to the activity and stability of anodic ...
Yong Yan   +10 more
wiley   +1 more source

Studies On An Aerobic Oxidation Of Dibenzothiophene And Related Compounds Using Ruthenium Catalyst

open access: yesArchives of Metallurgy and Materials, 2015
An aerobic oxidation of dibenzothiophene and related compounds using a catalytic amount of ruthenium chloride in hydrocarbon solvents at 80°C for 20 h gave the corresponding sulfones in almost quantitative yields.
Morishita Y., Murata S., Sunada S.
doaj   +1 more source

Support‐Controlled Reaction Pathways via Dynamic Sulfur‐Mediated Interfaces for Selective Urea Electrolysis

open access: yesAdvanced Functional Materials, EarlyView.
Sulfur‐doped graphitized carbon nanofibers act as adaptive catalyst–support platforms, enabling dynamic sulfur‐mediated reconstruction and strong metal–support interactions. This unique behavior enhances catalyst stability and controls reaction pathways, achieving highly selective urea oxidation (∼92% N2) coupled with efficient hydrogen evolution ...
Melanie Guillén‐Soler   +4 more
wiley   +1 more source

Aqueous Two‐Phase Bioinks for Discrete Packing and Compartmentalization of 3D Bioprinted Cells

open access: yesAdvanced Healthcare Materials, EarlyView.
Aqueous two‐phase systems (ATPS) enable the formation of biomimetic interfaces crucial for tissue engineering. However, clinical translation remains limited by the challenge of precisely controlling cellular compartmentalization. Here, we developed ATPS biomaterial inks for 3D bioprinting allowing tuneable droplet formation via NaCl modulation.
Martina Marcotulli   +17 more
wiley   +1 more source

Ruthenium-Catalyzed Regioselective 1,4-Hydroboration of Pyridines

open access: yes, 2016
Simple ruthenium precursor [Ru­(p-cymene)­Cl2]2 1 catalyzed regioselective 1,4-dearomatization of pyridine derivatives using pinacolborane is reported. Two catalytic intermediates, [Ru­(p-cymene)­Cl2Py] 2 and [Ru­(p-cymene)­Cl2(P­(Cy)3)] 3, involved in ...
Akash Kaithal (1520332)   +2 more
core   +1 more source

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