Results 111 to 120 of about 5,884,585 (302)

Ruthenium-Catalyzed C–H Alkynylation of Aromatic Amides with Hypervalent Iodine–Alkyne Reagents

, 2016
An efficient C–H activation method for the ortho alkynylation of aromatic N-methoxyamides with hypervalent iodine–alkyne reagent using a ruthenium catalyst is described. The reaction proceeds under mild reaction conditions with broad substrate scope.
Parthasarathy Gandeepan (1429120), Chien-Hong Cheng (1429123), Ramadoss Boobalan (2862434)   +2 more
core   +1 more source

Fabrication of Aligned Polycaprolactone Nanofibrillar Bundles to Control Cell‐Mediated Collagen Deposition in Engineered Cartilage

Advanced Materials, EarlyView.
Melt electrofibrillation (MEF) enables the fabrication of nanofibrillar PCL scaffolds with defined architectures that guide cellular alignment and retention during cartilage tissue engineering. Unlike conventional melt electrowriting, MEF consistently directs collagen type II‐rich extracellular matrix organization, providing a tunable platform to ...
Alba Pueyo Moliner, Lennard Spauwen, James L. Martin Robinson, Ángela García Grech, Isabelle Martinier, Sara Grasselli, Aylin Kara Özenler, Matthias Ryma, Jürgen Groll, Mylène de Ruijter, Jos Malda   +10 more
wiley   +1 more source

Accelerated Materials Discovery Through In Situ X‐ray Diffraction: Solvothermal Formation of PdxMy (M═Si, Ge, Sn, Pb) Intermetallic Nanoparticles

Advanced Materials, EarlyView.
In situ PXRD data on solvothermal reactions accelerate materials discovery while simultaneously providing fundamental insights into complex crystal formation processes. Using PdxMy (M = Si, Ge, Sn, Pb) as an example, a general formation mechanism is identified, and specific synthesis strategies for ex situ preparation of SnPd2, Sn13Pd20, and SnPd ...
Anders Bæk Borup, Bo Brummerstedt Iversen   +1 more
wiley   +1 more source

Phase‐Engineered MoS2 Quantum Monolayer Catalysts

Advanced Materials, EarlyView.
A new type of catalyst model—phase‐engineered MoS2 quantum‐monolayer catalyst (∼0.8 nm thick, < 6 nm in the lateral size; switchable freely among metallic 1T, semiconducting 2H, and a hybrid phase of metallic‐semiconducting 1T‐2H)—is reported. It can efficiently and stably drive photochemical H2, syngas and ammonia synthesis as a catalyst or co ...
Ruijie Yang, Yingying Fan, Lillian Pernitsky, Mojtaba Ebrahimian Mashhadi, Ningxin Chen, Md. Mehadi Hassan, Zheng Li, Heng Zhao, Liang Mei, Zhiyuan Zeng, Zhangxing Chen, Jinguang Hu, Qingye Lu   +12 more
wiley   +1 more source

Recent Advances in Plasma‐Enhanced Atomic Layer Etching for Next‐Generation Nanofabrication

Advanced Materials Interfaces, EarlyView.
Continued semiconductor miniaturization demands atomic‐scale patterning and ultralow surface roughness beyond the capabilities of conventional reactive ion etching. This review highlights advances in isotropic and anisotropic plasma‐enhanced atomic layer etching since 2020, covering fundamental mechanisms, applications across major semiconductor ...
Shih‐Nan Hsiao
wiley   +1 more source

Metal Ruthenium Complexes Treat Spinal Cord Injury By Alleviating Oxidative Stress Through Interaction With Antioxidant 1 Copper Chaperone Protein

Advanced Science
Oxidative stress is a major factor affecting spinal cord injury (SCI) prognosis. A ruthenium metal complex can aid in treating SCI by scavenging reactive oxygen species via a protein‐regulated mechanism to alleviate oxidative stress.
Juanjuan Li, Cheng Peng, Caiqiang Huang, Li Wan, Ke Wang, Ping Wu, Tianjun Chen, Guodong Sun, Rui Guo, Hongsheng Lin, Zhisheng Ji   +10 more
doaj   +1 more source

Ruthenium (II)-coordinated supramolecular drug self-assembly for efficient combination chemotherapy

Supramolecular Materials
Combination chemotherapy has been considered a crucial approach in cancer treatment to address the limitations of traditional single-drug therapy. However, the common strategies that encapsulate therapeutic agents with different mechanisms into a single “
Haonan Ma, Yifan Jin, Jintao Li, Xuedong Xiao, Chengfei Liu, Wei Tian   +5 more
doaj   +1 more source

Interface Engineering of Porous Transport Layer‐Catalyst Layer in Proton Exchange Membrane Water Electrolyzers: A Comprehensive Review

Advanced Materials Interfaces, EarlyView.
The PTL–CL interface plays a decisive role in PEMWE performance by governing electron conduction, water supply, oxygen removal, catalyst utilization, and interfacial stability. This review summarizes interface‐related resistance sources, characterization methods, and engineering strategies, highlighting rational PTL–CL interface design for low‐cost ...
Aobo Wan, Zhengkai Tu
wiley   +1 more source

Ruthenium-Catalyzed Intramolecular Double Hydroalkoxylation of Internal Alkynes

, 2018
Intramolecular double hydroalkoxylation of internal alkynes could be achieved using a Grubbs-type ruthenium carbene complex or its modified species to deliver a series of bridged- and spiroacetal derivatives in moderate to good yields.
Shusuke Sachimori (6052535), Tomomi Watanabe (1596925), Haruhiko Fuwa (1443436), Kei Iio (6052532)   +3 more
core   +1 more source

Scalable Production of Disordered Nickel‐Iron‐Aluminum Oxides as Stable Anodes for Water Electrolysis: The Role of Aluminum

Advanced Materials Interfaces, EarlyView.
Solution precursor plasma spraying enables the scalable fabrication of porous and disordered nickel‐iron‐aluminum oxide coatings as precious‐metal‐free anodes. Aluminum inhibits crystal growth, optimizes local atomic sites, and enhances charge and ion transport to accelerate reaction kinetics, leading to excellent performance and operational stability.
Tugce Ustunel, Joakim Bäckström, Esdras J. Canto‐Aguilar, Mouna Rafei, Litty Thomas Manamel, Mahesh Ramakrishnan, Konstantin Klementiev, Nina Grunditz, Erik Zimmerman, Thomas Wågberg, Susanne Holmin, Eduardo Gracia‐Espino   +11 more
wiley   +1 more source