Results 51 to 60 of about 38,942 (269)

Toward Fast Proton Shuttling in Acidic Oxygen Evolution Reaction

open access: yesAdvanced Functional Materials, EarlyView.
This review establishes proton transfer dynamics as a descriptor governing acidic OER activity, moving beyond the kinetic constraints derived from the proton coupled electron transfer. We discuss how deprotonation governs classical mechanisms, including adsorbate evolution mechanism (AEM), lattice oxygen mechanism (LOM) and oxide path mechanism (OPM ...
Ashish Gaur   +3 more
wiley   +1 more source

Aqueous Two‐Phase Bioinks for Discrete Packing and Compartmentalization of 3D Bioprinted Cells

open access: yesAdvanced Healthcare Materials, EarlyView.
Aqueous two‐phase systems (ATPS) enable the formation of biomimetic interfaces crucial for tissue engineering. However, clinical translation remains limited by the challenge of precisely controlling cellular compartmentalization. Here, we developed ATPS biomaterial inks for 3D bioprinting allowing tuneable droplet formation via NaCl modulation.
Martina Marcotulli   +17 more
wiley   +1 more source

Synthesis and photophysical studies of a multivalent photoreactive RuII-calix[4]arene complex bearing RGD-containing cyclopentapeptides

open access: yesBeilstein Journal of Organic Chemistry, 2018
Photoactive ruthenium-based complexes are actively studied for their biological applications as potential theragnostic agents against cancer. One major issue of these inorganic complexes is to penetrate inside cells in order to fulfil their function ...
Sofia Kajouj   +12 more
doaj   +1 more source

Electroluminescence in Ruthenium(II) Dendrimers [PDF]

open access: yesThe Journal of Physical Chemistry A, 2003
We have investigated the electroluminescent properties of polyamidoamine dendrimers containing pendant [Ru(bpy)3]+2 chromophores. Devices were made using indium tin oxide (ITO) and gold electrodes, and they were compared to devices made from [Ru(bpy)3]+2 films.
Jason A. Barron   +5 more
openaire   +1 more source

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

open access: yesAdvanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje   +7 more
wiley   +1 more source

Bacteria‐Responsive Nanostructured Drug Delivery Systems for Targeted Antimicrobial Therapy

open access: yesAdvanced Materials, EarlyView.
Bacteria‐responsive nanocarriers are designed to release antimicrobials only in the presence of infection‐specific cues. This selective activation ensures drug release precisely at the site of infection, avoiding premature or indiscriminate release, and enhancing efficacy.
Guillermo Landa   +3 more
wiley   +1 more source

Rational Design of Organo-Ruthenium Anticancer Compounds

open access: yesCHIMIA, 2005
Organometallic ruthenium(II)-arene complexes are currently attracting increasing interest as anticancer compounds with the potential to overcome drawbacks of traditional drugs like cisplatin with respect to resistance, selectivity, and toxicity.
Christian Gossens   +2 more
doaj   +1 more source

Osmium(II) and Ruthenium(II) complexes of tricyclohexylphosphine [PDF]

open access: yesRecueil des Travaux Chimiques des Pays-Bas, 1972
AbstractThe preparation of tricyclohexylphosphine complexes of osmium and ruthenium is reported. The reaction of K2OsCl6 or hydrated RuCl3 with tricyclohexylphosphine (PCy3) in 2‐methoxyethanol leads to the complexes MHCl(CO) (PCy3)2 with M = Os or Ru.
Moers, F.G., Langhout, J.P.
openaire   +3 more sources

Spin‐Split Edge States in Metal‐Supported Graphene Nanoislands Obtained by CVD

open access: yesAdvanced Materials, EarlyView.
Combining STM measurements and ab‐initio calculations, we show that zig‐zag edges in graphene nanoislands grown on Ni(111) by CVD retrieve their spin‐polarized edge states after intercalation of a few monolayers of Au. ABSTRACT Spin‐split states localized on zigzag edges have been predicted for different free‐standing graphene nanostructures.
Michele Gastaldo   +6 more
wiley   +1 more source

Combination of Ruthenium Complex and Doxorubicin Synergistically Inhibits Cancer Cell Growth by Down-Regulating PI3K/AKT Signaling Pathway

open access: yesFrontiers in Oncology, 2020
Combinational use of drugs has been a common strategy in cancer treatment because of synergistic advantages in reducing dose and toxicity, minimizing or delaying drug resistance.
Ke Lin   +7 more
doaj   +1 more source

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