Results 71 to 80 of about 5,884,585 (302)

Ruthenium-Coordinated Spirolactams via Intramolecular Nucleophilic Addition to η6-Arene Metal Complexes

open access: yes, 2016
Cyclohexadienyl ruthenium(II) complexes incorporating an azaspirocyclic ring system have been prepared from (η6-N-benzyl acetoacetamide)CpRu(II) precursors via an intramolecular nucleophilic aromatic addition/enolate trapping reaction sequence.
John J. Coniglio (2646712)   +2 more
core   +1 more source

Chemical Strategies for Multistimuli Responsive Dynamic Covalent Materials in Regenerative Medicine

open access: yesAdvanced Healthcare Materials, EarlyView.
Multistimuli responsive dynamic covalent materials integrate reversible chemistry with the complex chemical, mechanical, and biochemical cues of regenerative environments. This review highlights chemical strategies based on orthogonal dynamic bonds, multicomponent networks, and hierarchical architectures to regulate mechanics, degradation, and ...
Saurabh Joshi   +2 more
wiley   +1 more source

Revisiting ruthenium scorpionate chemistry: Reactivity of bis(3,5-dimethylpyrazol-1-yl)acetic acid toward organoruthenium(II) precursors

open access: yesActa Chimica Slovenica
The reactivity of the scorpionate ligand bis(3,5-dimethylpyrazol-1-yl)acetic acid (L1H) toward organoruthenium(II) precursors was investigated. Reactions of chlorido and bromido p-cymene ruthenium dimers afforded the corresponding complexes in which L1H
Mihaela Rebernik Gracej   +2 more
doaj   +1 more source

Advances in 3D Bioprinting for Breast Cancer Modeling: Tumor Microenvironment, Metastasis, and Drug Screening

open access: yesAdvanced Healthcare Materials, EarlyView.
Three‐dimensional bioprinting transforms breast cancer modeling from simple constructs into spatially organized, multicellular, perfused, and patient‐derived platforms. This review shows how bioinks, cellular composition, architecture, and flow govern tumor behavior and drug response, while revealing why complexity alone is insufficient without ...
Mustafa Nakipoglu   +7 more
wiley   +1 more source

Recoveries of Ru(III) and Co(II) by Solvent Extraction and Ion Exchange from Tungsten Carbide-Cobalt Scrap through a HCl Leaching Solution

open access: yesMetals, 2019
The addition of ruthenium to tungsten carbide-cobalt hard metals improves their mechanical properties. Since ruthenium is a platinum group metal, the recovery of ruthenium together with cobalt from the scrap of hard metals is of great importance.
Hyeong Hun Ahn, Man Seung Lee
doaj   +1 more source

Ruthenium-Catalyzed Selective Hydrogenation of Epoxides to Secondary Alcohols

open access: yes, 2019
A ruthenium­(II)-catalyzed highly selective Markovnikov hydrogenation of terminal epoxides to secondary alcohols is reported. Diverse substitutions on the aryl ring of styrene oxides are tolerated.
Subramanian Thiyagarajan (4264885)   +1 more
core   +1 more source

Lignin Mimicking Protein Methylation Augments the Efficacy of FOLFOX Chemotherapy by Anchoring Thymidylate Synthase

open access: yesAdvanced Materials, EarlyView.
Lignin‐mimicking protein methylation can enhance the efficacy and mitigate the toxicity of the classic FOLFOX chemotherapy regimen. ABSTRACT FOLFOX has served as the standard chemotherapy regimen for advanced stages, specifically in the treatment of pancreatic, colorectal, and bladder cancers.
Shiyao Song   +14 more
wiley   +1 more source

Rational Design of Organo-Ruthenium Anticancer Compounds

open access: yesCHIMIA, 2005
Organometallic ruthenium(II)-arene complexes are currently attracting increasing interest as anticancer compounds with the potential to overcome drawbacks of traditional drugs like cisplatin with respect to resistance, selectivity, and toxicity.
Christian Gossens   +2 more
doaj   +1 more source

Hydrogen generation from the methanolysis of ammonia borane catalyzed by in situ generated, polymer stabilized ruthenium(0) nanoclusters

open access: yes, 2011
Addressed herein is the detailed study on in situ generation of poly(N-vinyl-2-pyrrolidone) (PVP) stabilized ruthenium(0) nanoclusters and their catalysis in the methanolysis of ammonia borane (AB).
Metin, Onder   +2 more
core   +1 more source

Single‐Chromophore Homojunction Organic Solar Cells: A Path to Simplicity and Efficiency

open access: yesAdvanced Materials, EarlyView.
This perspective discusses how the intrinsic optoelectronic properties of organic semiconductors, their molecular packing in the solid‐state, and internal energetic gradients within a device can enable free‐charge carrier generation in homojunction organic solar cells.
Shaun McAnally   +2 more
wiley   +1 more source

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