Results 101 to 110 of about 77,736 (258)

Nanostructured titanium dioxide-based photocatalysts for self-cleaning concrete: аssessment of effects of phase composition on photocatalytic activity of TiO2 [PDF]

open access: yesНанотехнологии в строительстве
Introduction. Currently, the development of photocatalytically active cement-based materials with self-cleaning properties is a promising area of building materials science.
Artemy S. Balykov   +3 more
doaj   +1 more source

Electrodynamics of the vanadium oxides VO2 and V2O3

open access: yes, 2008
The optical/infrared properties of films of vanadium dioxide (VO2) and vanadium sesquioxide (V2O3) have been investigated via ellipsometry and near-normal incidence reflectance measurements from far infrared to ultraviolet frequencies.
A. A. Schafgans   +12 more
core   +1 more source

Interfacial Ru–O–W Orbital Coupling Enables Lattice Oxygen Stabilization for Enhanced Acidic OER

open access: yesCarbon Energy, EarlyView.
A RuO2/WO3 electrocatalyst with strong interfacial Ru–O–W bonds exhibits optimized Ru–O interactions, enhancing intrinsic activity and stability for acidic OER. The WO3 support modulates the electronic structure of RuO2 and promotes oxo‐intermediate deprotonation, delivering a low overpotential of 203 mV at 10 mA cm−2 and sustained operation beyond 200 
Tongzhou Wang   +9 more
wiley   +1 more source

Photocatalytic degradation of alachlor by TiO2 nanoparticles from aqueous solutions under UV radiation

open access: yesJournal of Experimental Nanoscience, 2019
This study aimed to synthesise TiO2 nanoparticles (NPs) in pure rutile structure at moderate temperature without calcination and use them as the catalyst for alachlor removal under UV-C radiation.
Fatemeh Jamshidi   +3 more
doaj   +1 more source

Synthesis O-g-C3N4/TiO2 rutile composite material for photocatalytic application

open access: yesХімія, фізика та технологія поверхні, 2019
The development of novel materials ensuring the use of solar radiation as an inexhaustible source of renewable and environmentally friendly energy is one of the actual problems of materials science.
M. E. Bondarenko   +5 more
doaj   +1 more source

Bulk and Surface Magnetization of Co atoms in Rutile Ti_[1-x]Co_xO_[2-delta] Thin Films Revealed by X-Ray Magnetic Circular Dichroism

open access: yes, 2011
We have studied magnetism in Ti_[1-x]Co_xO_[2-\delta] thin films with various x and \delta by soft x-ray magnetic circular dichroism (XMCD) measurements at the Co L_[2,3] absorption edges. The estimated ferromagnetic moment by XMCD was 0.15-0.24 \mu\beta/
A Fujimori   +16 more
core   +1 more source

Photoelectrochemical Hydrogen Peroxide Production via Simultaneous Reduction and Oxidation Processes

open access: yesChemistry – A European Journal, EarlyView.
Hydrogen peroxide (H2O2) is an important chemical substance and also a promising carbon‐free clean fuel. The design of a sophisticated photoelectrochemical (PEC) reaction system enables the solar‐driven H2O2 production through simultaneous water oxidation and oxygen reduction processes (H2O2/H2O2‐PEC cells).
Tetsuro Soejima   +2 more
wiley   +1 more source

β‐Scission of Tertiary Alcohols on a Platinum‐Loaded Titanium Dioxide Photocatalyst for C─C Bond‐Forming Reactions

open access: yesChemistry – A European Journal, EarlyView.
A strategy for the Pt/TiO2‐photocatalyzed β‐scission of nonactivated 3° alcohols in the absence of external oxidants and additives was developed. A wide variety of C‐centered radicals were generated and subsequently engaged in C─C bond‐forming reactions.
Shu Sakurai   +3 more
wiley   +1 more source

On the Reaction Mechanism of Nitrate Radical and DMPO in Non‐aqueous Photocatalytic Media

open access: yesChemistry – A European Journal, EarlyView.
This work identifies 2‐oxo‐5,5‐dimethyl‐1‐pyrroline 1‐oxyl (DMPOX), formed via the selective oxidation of 5,5‐dimethyl‐1‐pyrroline N‐oxide (DMPO) by nitrate radicals (NO3•) in nonaqueous media, as a distinctive EPR fingerprint of NO3•. The DFT‐supported mechanism clarifies its formation pathway and highlights DMPOX detection as a robust tool for ...
Alessandro Gottuso   +4 more
wiley   +1 more source

Interfacial Engineering with Lithium Titanate on MCMB Anode for Lithium‐Ion Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Graphical illustration of lithium titanate modified artificial graphite anode to enhance the lithium ion diffusion and stabilise the electrode‐electrolyte interface, effectively suppressing the lithium plating and improving electrochemical performance.
Ruby Alphonse Raj   +3 more
wiley   +1 more source

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