Titanium Imido Complexes with Tetradentate Schiff Base Ligands
New mono- and binuclear titanium imido complexes supported by tetradentate, dianionic N(2)O(2)-donor Schiff base ligands were prepared in good yield from the readily available [Ti(NBu(t))Cl(2)(py)(3)] (1a). Thus treatment of 1a with Na(2)[substituted-salen] gave monomeric [Ti(NBu(t))(substituted-salen)] where substituted-salen = Et(2)salen (2) or Bu(t)(
McInnes, J +3 more
openaire +2 more sources
Anion-Dependent Construction of Two Hexanuclear 3D-4F Complexes with a Flexible Schiff Base Ligand [PDF]
Two hexanuclear 3d-4f Ni-Eu and Cu-Eu complexes [Eu4Ni2L2(OAc)(12)(EtOH)(2)] (1) and [Eu4Cu2L2(OAc)(12)]center dot 2H(2)O (2) are reported which are formed from the salen type Schiff-base ligand H2L (H2L = N,N'-bis(3-methoxysalicylidene)butane-1,4 ...
Andruh +42 more
core +1 more source
The Mn(II), Co(II), Ni(II) and Cu(II) complexes of (Z)-N'((1H-indol-3-yl)methylene)nicotinohydrazide Schiff base: synthesis, characterization and biological evaluation [PDF]
Schiff bases being biological moieties possess diverse biological and pharmaceutical applications. Metal ions play an important role in various functions of the biological system as well as the human body.
Ankali, K. N. +5 more
core +1 more source
Fluorescent turn-on sensors based on pyrene-containing Schiff base derivatives for Cu2+ recognition: spectroscopic and DFT computational studies [PDF]
A new fluorescent chemosensor L1, pyrene containing long chain Schiff base derivative in 1-position has been synthesized. Similarly, the receptors L2 and L3 are also designed in order to compare the binding ability for detection of Cu2+.
Georghiou, Paris E. +8 more
core +1 more source
Neutral low-dimensional assemblies of a Mn(III) schiff base complex and octacyanotungstate(V) : synthesis, characterization, and magnetic properties [PDF]
International audienceTwo novel low-dimensional molecular magnetic materials were prepared by the self-assembly of 3d- and 5d-metal complexes. These are the first neutral heterobimetallic cyanobridged compounds involving one anisotropic Mn(III) Schiff ...
Majcher, Anna +3 more
core +1 more source
In the title dinuclear complex, [CuGd(C20H22N2O4)(NO3)3], the CuII ion is located in the inner N2O2 cavity of the Schiff base ligand and adopts a distorted square-planar geometry.
Christopher Chan +4 more
doaj +1 more source
Use of metal catalysts bearing Schiff base macrocycles for the ring opening polymerization (ROP) of cyclic esters [PDF]
© 2017 by the authors. Schiff base macrocycles are emerging as useful scaffolds for binding two or more catalytic metals in close proximity. Such coordination chemistry allows for the evaluation of potentially beneficial catalytic cooperative effects. In
Redshaw, Carl
core +2 more sources
CYTOTOXIC AND ANTICANCER STUDIES OF AN OXYGEN AND NITROGEN DONOR NOVEL SCHIFF BASE LIGAND AND ITS COPPER (II) COMPLEX [PDF]
A selected solid complex of the Schiff base ligand derived from Glutaric anhydride with Cu(II) ion was synthesized and characterized by FT-IR, Electronic, ESR Spectral Analyses, Magnetic susceptibility and Molar Conductance Measurements.
Arumugam AP +2 more
doaj +1 more source
Syntheses, Structures, and Photoluminescence of 1-D Lanthanide Coordination Polymers [PDF]
Five new lanthanide 1-D coordination polymers are reported which are formed from flexible salen type Schiff-base ligands H(2)L and H(2)L' (H(2)L = N, N(1)-ethylene bis(salicylideneimine); H(2)L' = N,N(1)-bis(3-methoxysalicylidene) ethylene-1,2-diamine ...
Jones, Richard A. +3 more
core +1 more source
Synthesis, spectral characterization, in-vitro microbiological evaluation and cytotoxic activities of novel macrocyclic bis hydrazone [PDF]
A macrocyclic hydrazone Schiff base was synthesized by reacting 1,4-dicarbonyl phenyl dihydrazide with 2,6-diformyl-4-methyl phenol and a series of metal complexes with this new Schiff base were synthesized by reaction with Co(II), Ni(II) and Cu(II ...
Avaji, P.G. +4 more
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