Results 61 to 70 of about 160,515 (349)

Iodine-catalyzed Transformation of Aryl-substituted Alcohols under Solvent-free and highly concentrated Reaction Conditions

open access: yesActa Chimica Slovenica, 2017
Iodine-catalyzed transformations of alcohols under solvent-free reaction conditions (SFRC) and under highly concentrated reaction conditions (HCRC) in the presence of various solvents were studied in order to gain insight into the behavior of the ...
Marjan Jereb, Dejan Vražič
doaj   +1 more source

Erythropoietin modulates hepatic inflammation, glucose homeostasis, and soluble epoxide hydrolase and epoxides in high‐fat diet‐induced obese mice

open access: yesFEBS Open Bio, EarlyView.
Erythropoietin administration suppresses hepatic soluble epoxide hydrolase (sEH) expression, leading to increased CYP‐derived epoxides. This is associated with a shift in hepatic macrophage polarization characterized by reduced M1 markers and increased M2 markers, along with reduced hepatic inflammation, suppressed hepatic lipogenesis, and attenuated ...
Takeshi Goda   +12 more
wiley   +1 more source

A Study of Amino Acid Metabolism and the Production of Higher Alcohols and Their Esters in Sparkling Wines

open access: yesFermentation
The presented article is focused on the study of amino acid metabolism and the related production of fusel alcohols and their esters in the secondary fermentation of sparkling wines.
Štěpán Tesařík   +3 more
doaj   +1 more source

Heterobimetallic Complexes as Catalyst Precursors for the Oppenauer-Type Oxidation of Alcohols

open access: yesCHIMIA, 2005
A heterobimetallic Ru(II)-Rh(I) complex has been identified as a potent catalyst precursor for the Oppenauer-type oxidation of alcohols. With 0.1–0.5 mol% of this complex and K2CO3 as the co-catalyst, it is possible to oxidize secondary and ...
Sébastien Gauthier, Kay Severin
doaj   +1 more source

Structural features and reactivity of (sparteine)PdCl_2: a model for selectivity in the oxidative kinetic resolution of secondary alcohols [PDF]

open access: yes, 2008
The chiral ligand (−)-sparteine and PdCl_2 catalyze the enantioselective oxidation of secondary alcohols to ketones and thus effect a kinetic resolution.
Stoltz, Brian M., Trend, Raissa M.
core   +2 more sources

Isohexide and sorbitol-derived, enzymatically synthesized renewable polyesters with enhanced Tg [PDF]

open access: yes, 2016
Sugar-based polyesters derived from sorbitol and isohexides were obtained via solvent-free enzymatic catalysis. Pendant hydroxyl groups, coming from the sorbitol units, were present along the polyester backbone, whereas the two isohexides, namely ...
Gustini, Liliane   +4 more
core   +2 more sources

Cutaneous Melanoma Drives Metabolic Changes in the Aged Bone Marrow Immune Microenvironment

open access: yesAging and Cancer, EarlyView.
Melanoma, the deadliest form of skin cancer, increasingly affects older adults. Our study reveals that melanoma induces changes in iron and lipid levels in the bone marrow, impacting immune cell populations and increasing susceptibility to ferroptosis.
Alexis E. Carey   +12 more
wiley   +1 more source

From‐Neutral‐to‐Neutral Reductive Radical Coupling of Non‐Activated Alcohols and Styrenes

open access: yesChemistryEurope, 2023
A reductive radical coupling reaction between non‐activated aliphatic alcohols and styrenes has been discovered through the use of low‐valent Ti‐mediated C−O bond homolysis.
Dr. Takuya Suga   +2 more
doaj   +1 more source

Deoxygenative Borylation of Secondary and Tertiary Alcohols [PDF]

open access: yesAngewandte Chemie International Edition, 2019
AbstractTwo different approaches for the deoxygenative radical borylation of secondary and tertiary alcohols are presented. These transformations either proceed through a metal‐free silyl‐radical‐mediated pathway or utilize visible‐light photoredox catalysis. Readily available xanthates or methyl oxalates are used as radical precursors.
Florian W. Friese, Armido Studer
openaire   +2 more sources

Impact of APOE ε4 Genotype Load on Cognitive Function and Lipid Metabolism in Patients With Cerebral Small Vessel Disease

open access: yesAnnals of Clinical and Translational Neurology, EarlyView.
ABSTRACT Background Apolipoprotein ε4 (APOE ε4) is a potent genetic risk factor for Alzheimer's disease (AD). However, its role in cerebral small vessel disease (CSVD) remains unclear. Given the clinical and pathological similarities between CSVD and AD, this study aimed to investigate the associations of APOE ε4 gene dosage with cognitive function and
Tingru Jin   +6 more
wiley   +1 more source

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