Selective oxidation of some primary and secondary benzylic alcohols to the corresponding carbonyl compounds with a Cu(III) complex [PDF]
The selective oxidation of benzylic alcohols to the corresponding carbonyl compounds is described. In alkaline solution, the oxidation reagent potassium tetrasodium diperiodatocuprate(III) dodecahydrate (KNa4[Cu(HIO6)2]×12H2O) reacts with primary and ...
VLADAN KOSTIC +2 more
doaj +3 more sources
SYNTHESIS OF SECONDARY ALCOHOL COMPOUNDS FROM SAFROLE AND METHYLEUGENOL
Synthesis of secondary alcohols compound from safrole and methyleugenol has been achieved through conversion of allyl group to alcohol.The reaction of safrole and methyleugenol with mercuric acetate in aqueous tetrahydrofuran, followed by in situ ...
Hanoch J Sohilait +2 more
doaj +1 more source
Cobalt-catalyzed peri-selective alkoxylation of 1-naphthylamine derivatives
A cobalt-catalyzed C(sp2)–H alkoxylation of 1-naphthylamine derivatives has been disclosed, which represents an efficient approach to synthesize aryl ethers with broad functional group tolerance.
Jiao-Na Han +7 more
doaj +1 more source
Application of secondary atmospheric distillation technology in reducing the content of higher alcohols in original liquor of strong-flavor Baijiu [PDF]
In order to reduce the higher alcohols content in original liquor of strong-flavor (Nongxiangxing) Baijiu, secondary atmospheric distillation of original liquor of strong-flavor Baijiu was carried out by tower distillation equipment, the effects of ...
GUO Taohong, DONG Yun, ZHANG Juan, JIA Xiaolong, ZHANG Zhiliang
doaj +1 more source
Nickel-Catalyzed α‑Alkylation of Arylacetonitriles with Challenging Secondary Alcohols
Nickel(II) complex 1 was utilized as a sustainable catalyst for α-alkylation of arylacetonitriles with challenging secondary alcohols. Arylacetonitriles with a wide range of functional groups were tolerated, and various cyclic and acyclic secondary ...
Amareshwar Nanda (14321942) +3 more
core +1 more source
Ruthenium-catalyzed β-alkylation of secondary alcohols with primary alcohols
The catalytic properties of a series of ruthenium complexes for β-alkylation of secondary alcohols with primary alcohols were studied. The catalytic activities of the ruthenium complexes were found to be dependent on the auxiliary ligands.
Jia, Guochen, Bai, Wei
core +1 more source
Dimethyl fumarate (DMF) reduces growth of HPV‐positive cervical cancer spheroids and induces ferroptosis in cervical cancer cells via blocking SLC7A11/Glutathione (GSH) axis. Combination of subcytotoxic doses of DMF and cisplatin (CDDP) further suppresses spheroid growth and drives cell death in 2D culture models.
Carolina Punziano +6 more
wiley +1 more source
A comparative LFER study of the reactivity of pyridineacetic, pyridineacetic acids N-oxide and substituted phenylacetic acids with diazodiphenylmethane in various alcohols [PDF]
Rate constants have been determined for the reactions of diazodiphenylmethane (DDM) with 3- and 4-pyridineacetic acid, 3- and 4-pyridineacetic acid N-oxide and some meta- and para-substituted phenylacetic acids in twelve alcohols. The determined
Drmanić Saša Z. +2 more
doaj +3 more sources
A selective oxidation of primary alcohols to the corresponding aldehydes by shaking with chromium trioxide supported on aluminium silicate at room temperature under solvent free conditions is reported.
Y. Fu, L. Ping, L. Zhu, J. Lou, L. Huang
doaj +1 more source
14‐day casting‐induced immobilization reduced gastrocnemius muscle mass and increased non‐heme iron and ferritin heavy chain levels. Despite iron accumulation, transferrin receptor 1 and iron regulatory protein 2 were paradoxically upregulated. Lipid peroxidation was elevated without compensatory antioxidant responses.
Haruka Yokogawa +2 more
wiley +1 more source

