Ruthenium-catalyzed β-alkylation of secondary alcohols with primary alcohols
The catalytic properties of a series of ruthenium complexes for β-alkylation of secondary alcohols with primary alcohols were studied. The catalytic activities of the ruthenium complexes were found to be dependent on the auxiliary ligands.
Jia, Guochen, Bai, Wei
core +1 more source
Metastatic niche shaped by host factors influences disseminated cancer cell fate
Metastasis is shaped not only by cancer cells but also by the environments they encounter. This review explores how factors such as aging, diet, the microbiome, lifestyle, and environmental exposures remodel organ‐specific niches in the lung, liver, bone, and brain, influencing where metastatic cells survive, remain dormant, or grow, and ultimately ...
Gwennan Delyth Ward +2 more
wiley +1 more source
Cobalt-catalyzed peri-selective alkoxylation of 1-naphthylamine derivatives
A cobalt-catalyzed C(sp2)–H alkoxylation of 1-naphthylamine derivatives has been disclosed, which represents an efficient approach to synthesize aryl ethers with broad functional group tolerance.
Jiao-Na Han +7 more
doaj +1 more source
SYNTHESIS OF SECONDARY ALCOHOL COMPOUNDS FROM SAFROLE AND METHYLEUGENOL
Synthesis of secondary alcohols compound from safrole and methyleugenol has been achieved through conversion of allyl group to alcohol.The reaction of safrole and methyleugenol with mercuric acetate in aqueous tetrahydrofuran, followed by in situ ...
Hanoch J Sohilait +2 more
doaj +1 more source
Stereospecific Oxidation of Secondary Alcohols by Human Alcohol Dehydrogenases
The human liver alpha alpha alcohol dehydrogenase exhibits a different substrate specificity and stereospecificity for secondary alcohols than the human beta 1 beta 1, and gamma 1 gamma 1 or horse liver alcohol dehydrogenases. All of the enzymes efficiently oxidize primary alcohols, but alpha alpha oxidizes secondary alcohols far more efficiently than ...
C L, Stone, T K, Li, W F, Bosron
openaire +2 more sources
Oxidation of alcohols using CoFe204@APTES@Ni(OH)2 [PDF]
Oxidation of alcohols using CoFe204@APTES@Ni(OH)2 was characterised by AAS, FT-IR, UV/Vis, XRD, TEM, FESEM, N2 adsorption, and VSM analyses. The catalyst was recovered by magnetic separation and reused four times without significant loss of catalytic ...
Bhat, Pooja +2 more
core
LUNAR is a liver‐specific long noncoding RNA (lncRNA) that is highly expressed in normal liver but becomes epigenetically silenced in hepatocellular carcinoma through promoter hypermethylation. Loss of LUNAR is associated with NOTCH activation, epithelial–mesenchymal transition, and metastasis, whereas restoring LUNAR restrains metastatic progression ...
Se Ha Jang +9 more
wiley +1 more source
Selective oxidation of some primary and secondary benzylic alcohols to the corresponding carbonyl compounds with a Cu(III) complex [PDF]
The selective oxidation of benzylic alcohols to the corresponding carbonyl compounds is described. In alkaline solution, the oxidation reagent potassium tetrasodium diperiodatocuprate(III) dodecahydrate (KNa4[Cu(HIO6)2]×12H2O) reacts with primary and ...
VLADAN KOSTIC +2 more
doaj +3 more sources
Application of secondary atmospheric distillation technology in reducing the content of higher alcohols in original liquor of strong-flavor Baijiu [PDF]
In order to reduce the higher alcohols content in original liquor of strong-flavor (Nongxiangxing) Baijiu, secondary atmospheric distillation of original liquor of strong-flavor Baijiu was carried out by tower distillation equipment, the effects of ...
GUO Taohong, DONG Yun, ZHANG Juan, JIA Xiaolong, ZHANG Zhiliang
doaj +1 more source
Primary depressives with secondary alcoholism compared with alcoholics and depressives
While a subset of depressed patients are believed to "self-medicate" their depression with alcohol, there are no studies comparing the phenomenological and diagnostic characteristics of patients with primary depression and secondary alcoholism with those of patients with depression or alcoholism alone.
E, Leibenluft +3 more
openaire +2 more sources

