Results 21 to 30 of about 58,921 (259)

Selective oxidation of some primary and secondary benzylic alcohols to the corresponding carbonyl compounds with a Cu(III) complex [PDF]

open access: yesJournal of the Serbian Chemical Society, 2005
The selective oxidation of benzylic alcohols to the corresponding carbonyl compounds is described. In alkaline solution, the oxidation reagent potassium tetrasodium diperiodatocuprate(III) dodecahydrate (KNa4[Cu(HIO6)2[12H2O] reacts with primary and ...
Bugarčić Zorica M.   +2 more
doaj   +3 more sources

SYNTHESIS OF SECONDARY ALCOHOL COMPOUNDS FROM SAFROLE AND METHYLEUGENOL

open access: yesIndonesian Journal of Chemistry, 2010
Synthesis of secondary alcohols compound from safrole and methyleugenol has been achieved through conversion of allyl group to alcohol.The reaction of safrole and methyleugenol with mercuric acetate in aqueous tetrahydrofuran, followed by in situ ...
Hanoch J Sohilait   +2 more
doaj   +1 more source

Structure‐forward targeting of claudins with synthetic binders

open access: yesFEBS Letters, EarlyView.
Claudins form the paracellular barriers between epithelial and endothelial tissues at tight junctions and are targets for molecular binders with the goal of modulating barrier permeability. Claudin‐binding molecules are relevant in drug delivery or in altering claudin interactions with disease‐causing proteins.
Alex J. Vecchio
wiley   +1 more source

Cobalt-catalyzed peri-selective alkoxylation of 1-naphthylamine derivatives

open access: yesBeilstein Journal of Organic Chemistry, 2018
A cobalt-catalyzed C(sp2)–H alkoxylation of 1-naphthylamine derivatives has been disclosed, which represents an efficient approach to synthesize aryl ethers with broad functional group tolerance.
Jiao-Na Han   +7 more
doaj   +1 more source

Application of secondary atmospheric distillation technology in reducing the content of higher alcohols in original liquor of strong-flavor Baijiu [PDF]

open access: yesZhongguo niangzao
In order to reduce the higher alcohols content in original liquor of strong-flavor (Nongxiangxing) Baijiu, secondary atmospheric distillation of original liquor of strong-flavor Baijiu was carried out by tower distillation equipment, the effects of ...
GUO Taohong, DONG Yun, ZHANG Juan, JIA Xiaolong, ZHANG Zhiliang
doaj   +1 more source

Stereospecific Oxidation of Secondary Alcohols by Human Alcohol Dehydrogenases

open access: yesJournal of Biological Chemistry, 1989
The human liver alpha alpha alcohol dehydrogenase exhibits a different substrate specificity and stereospecificity for secondary alcohols than the human beta 1 beta 1, and gamma 1 gamma 1 or horse liver alcohol dehydrogenases. All of the enzymes efficiently oxidize primary alcohols, but alpha alpha oxidizes secondary alcohols far more efficiently than ...
C L, Stone, T K, Li, W F, Bosron
openaire   +2 more sources

Dimethyl fumarate combined with cisplatin at subcytotoxic doses sensitizes cervical cancer toward ferroptosis and apoptosis through GSH restriction and p53 (re)activation

open access: yesMolecular Oncology, EarlyView.
Dimethyl fumarate (DMF) reduces growth of HPV‐positive cervical cancer spheroids and induces ferroptosis in cervical cancer cells via blocking SLC7A11/Glutathione (GSH) axis. Combination of subcytotoxic doses of DMF and cisplatin (CDDP) further suppresses spheroid growth and drives cell death in 2D culture models.
Carolina Punziano   +6 more
wiley   +1 more source

Primary depressives with secondary alcoholism compared with alcoholics and depressives

open access: yesComprehensive Psychiatry, 1993
While a subset of depressed patients are believed to "self-medicate" their depression with alcohol, there are no studies comparing the phenomenological and diagnostic characteristics of patients with primary depression and secondary alcoholism with those of patients with depression or alcoholism alone.
E, Leibenluft   +3 more
openaire   +2 more sources

Epigenetic silencing of the liver‐specific lncRNA LUNAR promotes liver cancer progression via NOTCH activation

open access: yesMolecular Oncology, EarlyView.
LUNAR is a liver‐specific long noncoding RNA (lncRNA) that is highly expressed in normal liver but becomes epigenetically silenced in hepatocellular carcinoma through promoter hypermethylation. Loss of LUNAR is associated with NOTCH activation, epithelial–mesenchymal transition, and metastasis, whereas restoring LUNAR restrains metastatic progression ...
Se Ha Jang   +9 more
wiley   +1 more source

An Efficient and Selective Solvent-free Oxidation of Alcohols by Shaking with Chromium Trioxide Supported on Aluminium Silicate

open access: yesMolecules, 2005
A selective oxidation of primary alcohols to the corresponding aldehydes by shaking with chromium trioxide supported on aluminium silicate at room temperature under solvent free conditions is reported.
Y. Fu, L. Ping, L. Zhu, J. Lou, L. Huang
doaj   +1 more source

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