Scandium and Dimethylaminopyridine Catalyzed Dehydrative Coupling of Secondary Benzylic and Primary Alcohols to Synthesize Unsymmetrical Ethers [PDF]
We developed a direct catalytic condensation of benzylic alcohols and primary alcohols to synthesize unsymmetrical ethers in one step, catalyzed by scandium triflate and p-dimethylaminopyridine (DMAP).
Julia, Duncan +3 more
core +2 more sources
Catalytic Friedel–Crafts Reactions of Unactivated Secondary Alcohols: Site-Selective ortho-Alkylation of Phenols [PDF]
A combination of catalytic ZnCl2 and catalytic CSA enables the first site-selective Friedel–Crafts alkylation of phenolic derivatives with unactivated secondary alcohols.
Kevin, Kou +4 more
core +2 more sources
Source code, input files, and generic output files for molecular simulations in "Enthalpy of Mixing and Liquid Structure for Mixtures of Primary and Secondary Alcohols: Molecular Simulations and COSMO-SAC Calculations".The enthalpy of mixing provides ...
Siepmann, J. Ilja, Chang, Chun-Kai
core +1 more source
Highly Efficient Kinetic Resolution of Aryl-Alkenyl Alcohols by Ru-Catalyzed Hydrogen Transfer
No matter through asymmetric reduction of ketones or kinetic resolution of secondary alcohols, enantioselective synthesis of the corresponding secondary alcohols is challenging when the two groups attached to the prochiral or chiral centers are spatially
Yipeng You +3 more
doaj +1 more source
Hypersensitivity to secondary alcohols
No abstract ...
S, Fregert +5 more
openaire +2 more sources
Fe3O4@SiO2/AEPTMS/Fe(OTf)3: An efficient superparamagnetic nanocatalyst for the protecting of alcohols [PDF]
Fe3O4@SiO2/AEPTMS/Fe(OTf)3 is a stable, effective, and magnetic nanocatalyst easily prepared and characterized using FT-IR spectroscopy, SEM, TEM, and VSM techniques. This nanocatalyst was successfully applied for trimethylsilylation of numerous alcohols
Somayeh Mehdigholami +1 more
doaj +1 more source
Naturally occurring long-chain β-hydroxyketones
A fraction comprising about 0.7% of the extractable surface lipids of cabbage (Brassica oleracea) leaves was isolated and identified as a mixture of isomeric βhydroxyketones consisting mainly of 14-keto-16-hydroxynonacosane and 15-keto-13 ...
HARALD H.O. SCHMID, PATRICIA C. BANDI
doaj +1 more source
Amano-PS-IM-catalyzed mechanochemical enzymatic acylative kinetic resolution of secondary alcohols [PDF]
Mechanochemical enzymatic acylative kinetic resolution of secondary alcohols using ball milling represents a highly efficient and sustainable approach for the synthesis of chiral esters and alcohols with high enantioselectivity.
Koji Kubota +3 more
doaj +1 more source
Takotsubo cardiomyopathy secondary to alcohol withdrawal
Physical, mental, and emotional stressors have been well known to adversely affect cardiac function. A rare complication of such stressors is stress cardiomyopathy, otherwise known as takotsubo cardiomyopathy. First identified in Japan in the 1990s, takotsubo cardiomyopathy classically presents with systolic dysfunction and apical ballooning.
Ahmed, Faizan +3 more
openaire +2 more sources
Ruthenium-Catalyzed Self-Coupling of Secondary Alcohols
A simple catalytic method for self-coupling of secondary alcohols leading to the synthesis of β-branched ketones under mild conditions is reported. Well-defined ruthenium pincer complex catalyzed the reactions.
Raman Vijaya Sankar (12014432) +2 more
core +1 more source

