Reactive organoallyl species generated from aryl halides and allene: allylation of alpha,beta-unsaturated aldehydes and cyclic ketones employing Pd/In transmetallation processes [PDF]
, 2008 Allylation of α,β-unsaturated aldehydes and cyclic ketones promoted by Pd/In transmetallation processes has been studied. The unsaturated aldehydes underwent regioselective 1,2-addition to afford secondary homoally alcohols.
Anwar +56 more
core +2 more sources
Review of catalytic systems and thermodynamics for the Guerbet condensation reaction and challenges for biomass valorization [PDF]
, 2015 The Guerbet condensation reaction is an alcohol coupling reaction that has been known for more than a century. Because of the increasing availability of bio-based alcohol feedstock, this reaction is of growing importance and interest in terms of value ...
Gabriels, D +4 more
core +2 more sources
Scalable Green Approach Toward Fragrant Acetates
Molecules, 2020 The advantageous properties of ethylene glycol diacetate (EGDA) qualify it as a useful substitute for glycerol triacetate (GTA) for various green applications.
Eva Puchl’ová, Peter Szolcsányi
doaj +1 more source
Catalytic Oxidation of Secondary Alcohols [PDF]
, 2020 The dioxygen oxidation of alcohols over platinum catalysts has been known for a long time. While of potential importance in synthetic procedures, this process has never found extensive use except in carbohydrate oxidations. Some reasons for this is the fact that this reaction only appears to work well in an aqueous medium in the presence of rather ...
Robert L. Augustine, Lisa K. Doyle
openaire +5 more sources
Cobalt-catalyzed peri-selective alkoxylation of 1-naphthylamine derivatives
Beilstein Journal of Organic Chemistry, 2018 A cobalt-catalyzed C(sp2)–H alkoxylation of 1-naphthylamine derivatives has been disclosed, which represents an efficient approach to synthesize aryl ethers with broad functional group tolerance.
Jiao-Na Han +7 more
doaj +1 more source
Application of Transition Metal Catalysis to Small Molecule Synthesis [PDF]
, 2006 Over the past decade, transition metal catalysis has developed into a new field in organic synthesis, enabling numerous synthetic transformations that were previously not feasible.
Morrill, Christie
core +1 more source
Stereospecific Oxidation of Secondary Alcohols by Human Alcohol Dehydrogenases
Journal of Biological Chemistry, 1989 The human liver alpha alpha alcohol dehydrogenase exhibits a different substrate specificity and stereospecificity for secondary alcohols than the human beta 1 beta 1, and gamma 1 gamma 1 or horse liver alcohol dehydrogenases. All of the enzymes efficiently oxidize primary alcohols, but alpha alpha oxidizes secondary alcohols far more efficiently than ...
C L, Stone, T K, Li, W F, Bosron
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Primary depressives with secondary alcoholism compared with alcoholics and depressives
Comprehensive Psychiatry, 1993 While a subset of depressed patients are believed to "self-medicate" their depression with alcohol, there are no studies comparing the phenomenological and diagnostic characteristics of patients with primary depression and secondary alcoholism with those of patients with depression or alcoholism alone.
E, Leibenluft +3 more
openaire +2 more sources
EFSA Journal, 2016 Following a request from the European Commission, the EFSA Panel on Additives and Products or Substances used in Animal Feed (FEEDAP) was asked to deliver a scientific opinion on the safety and efficacy of 10 compounds belonging to chemical group 21 ...
EFSA Panel on Additives and Products or Substances used in Animal Feed (FEEDAP)
doaj +1 more source
Supported Gold Nanoparticles for Alcohols Oxidation in Continuous-Flow Heterogeneous Systems [PDF]
, 2017 Gold nanoparticles (AuNPs) were anchored on alkynyl carbamate-functionalized support materials having the suitable features for application as catalysts in continuous-flow packed bed reactors.
Ballarin, Barbara +9 more
core +2 more sources