Manganese(I)-Catalyzed Cross-Coupling of Ketones and Secondary Alcohols with Primary Alcohols [PDF]
ACS Omega, 2019 Catalytic cross-coupling of ketones and secondary alcohols with primary alcohols is reported. An abundant manganese-based pincer catalyst catalyzes the reactions.
Suhas Shahaji Gawali +3 more
doaj +3 more sources
CALB Immobilized onto Magnetic Nanoparticles for Efficient Kinetic Resolution of Racemic Secondary Alcohols: Long-Term Stability and Reusability [PDF]
Molecules, 2019 In this study, an immobilization strategy for magnetic cross-linking enzyme aggregates of lipase B from Candida antarctica (CALB) was developed and investigated. Magnetic particles were prepared by conventional co-precipitation.
Xiu Xing +6 more
doaj +2 more sources
Deoxygenative Borylation of Secondary and Tertiary Alcohols [PDF]
Angewandte Chemie - International Edition, 2019 AbstractTwo different approaches for the deoxygenative radical borylation of secondary and tertiary alcohols are presented. These transformations either proceed through a metal‐free silyl‐radical‐mediated pathway or utilize visible‐light photoredox catalysis. Readily available xanthates or methyl oxalates are used as radical precursors.
Armido Studer
exaly +3 more sources
Determination of the Absolute Configuration of Secondary Alcohols in a Compound Mixture via the Application of Competing Enantioselective Acylation Coupled with LC/MS Analysis [PDF]
PharmaceuticsThe determination of natural product stereochemistry plays a significant role in drug discovery and development. Understanding the stereochemistry of natural products is essential for predicting and optimizing their interactions with biological targets ...
Bum Soo Lee +5 more
doaj +2 more sources
Molecules, 2023 For the creation of adaptable carbonyl compounds in organic synthesis, the oxidation of alcohols is a crucial step. As a sustainable alternative to the harmful traditional oxidation processes, transition-metal catalysts have recently attracted a lot of ...
Abeer Nasser Al-Romaizan +8 more
doaj +1 more source
Wine secondary aroma: understanding yeast production of higher alcohols [PDF]
Microbial Biotechnology, 2017 Special Issue: Thematic Issue: From complex waste to plastic value.Contribution of yeasts to the sensory attributes of fermented foods and beverages goes far beyond sugar consumption and ethanol and carbon dioxide production.
Ramon Gonzalez, Pilar Morales
doaj +2 more sources
Highly Enantiomerically Enriched Secondary Alcohols via Epoxide Hydrogenolysis. [PDF]
OrganometallicsIn this paper, we report the development of ruthenium-catalyzed hydrogenolysis of epoxides to selectively give the branched (Markovnikov) alcohol products.
Borden OJ +7 more
europepmc +2 more sources
Scientific Opinion on Flavouring Group Evaluation 7, Revision 4 (FGE.07Rev4):Saturated and unsaturated aliphatic secondary alcohols, ketones and esters of secondary alcohols and saturated linear or branched-chain carboxylic acids from chemical group 5 [PDF]
EFSA Journal, 2012 <p>The Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids of the European Food Safety Authority was requested to evaluate 49 flavouring substances in the Flavouring Group Evaluation 07, including additional five substances in
EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
doaj +1 more source
, 2023 Source code, input files, and generic output files for molecular simulations in "Enthalpy of Mixing and Liquid Structure for Mixtures of Primary and Secondary Alcohols: Molecular Simulations and COSMO-SAC Calculations".The enthalpy of mixing provides ...
Siepmann, J. Ilja, Chang, Chun-Kai
core +1 more source
Highly Efficient Kinetic Resolution of Aryl-Alkenyl Alcohols by Ru-Catalyzed Hydrogen Transfer
Molecules, 2021 No matter through asymmetric reduction of ketones or kinetic resolution of secondary alcohols, enantioselective synthesis of the corresponding secondary alcohols is challenging when the two groups attached to the prochiral or chiral centers are spatially
Yipeng You +3 more
doaj +1 more source