Manganese(I)-Catalyzed Cross-Coupling of Ketones and Secondary Alcohols with Primary Alcohols [PDF]
ACS Omega, 2019 Catalytic cross-coupling of ketones and secondary alcohols with primary alcohols is reported. An abundant manganese-based pincer catalyst catalyzes the reactions.
Suhas Shahaji Gawali +3 more
doaj +3 more sources
CALB Immobilized onto Magnetic Nanoparticles for Efficient Kinetic Resolution of Racemic Secondary Alcohols: Long-Term Stability and Reusability [PDF]
Molecules, 2019 In this study, an immobilization strategy for magnetic cross-linking enzyme aggregates of lipase B from Candida antarctica (CALB) was developed and investigated. Magnetic particles were prepared by conventional co-precipitation.
Xiu Xing +6 more
doaj +2 more sources
Deoxygenative Borylation of Secondary and Tertiary Alcohols [PDF]
Angewandte Chemie - International Edition, 2019 AbstractTwo different approaches for the deoxygenative radical borylation of secondary and tertiary alcohols are presented. These transformations either proceed through a metal‐free silyl‐radical‐mediated pathway or utilize visible‐light photoredox catalysis. Readily available xanthates or methyl oxalates are used as radical precursors.
Armido Studer
exaly +3 more sources
Determination of the Absolute Configuration of Secondary Alcohols in a Compound Mixture via the Application of Competing Enantioselective Acylation Coupled with LC/MS Analysis [PDF]
PharmaceuticsThe determination of natural product stereochemistry plays a significant role in drug discovery and development. Understanding the stereochemistry of natural products is essential for predicting and optimizing their interactions with biological targets ...
Bum Soo Lee +5 more
doaj +2 more sources
Molecules, 2023 For the creation of adaptable carbonyl compounds in organic synthesis, the oxidation of alcohols is a crucial step. As a sustainable alternative to the harmful traditional oxidation processes, transition-metal catalysts have recently attracted a lot of ...
Abeer Nasser Al-Romaizan +8 more
doaj +1 more source
Wine secondary aroma: understanding yeast production of higher alcohols [PDF]
Microbial Biotechnology, 2017 Special Issue: Thematic Issue: From complex waste to plastic value.Contribution of yeasts to the sensory attributes of fermented foods and beverages goes far beyond sugar consumption and ethanol and carbon dioxide production.
Ramon Gonzalez, Pilar Morales
doaj +2 more sources
Scientific Opinion on Flavouring Group Evaluation 7, Revision 4 (FGE.07Rev4):Saturated and unsaturated aliphatic secondary alcohols, ketones and esters of secondary alcohols and saturated linear or branched-chain carboxylic acids from chemical group 5 [PDF]
EFSA Journal, 2012 <p>The Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids of the European Food Safety Authority was requested to evaluate 49 flavouring substances in the Flavouring Group Evaluation 07, including additional five substances in
EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
doaj +1 more source
One pot three component synthesis of α-methylated ketones from secondary and primary aryl alcohols [PDF]
, 2023 One pot three component synthesis of α-methylated ketones from secondary and primary alcohols via triple dehydrogenative method is presented here. This protocol uses a polystyrene supported catalyst and is reused for five runs without any drop in its ...
Krishnan, Venkatasubbaiah +5 more
core +2 more sources
Purification of fuel fractions of petroleum products from sulfur compounds
Trudy Odesskogo Politehničeskogo Universiteta, 2019 Significant damage to the environment causes burning of motor fuels. One of the most urgent problems for oil refineries around the world is the reduction of sulfur content, which directly affects the emission of sulfur oxides. The need for environmental
Віктор Васильович Лялін +1 more
doaj +5 more sources
Highly Enantiomerically Enriched Secondary Alcohols via Epoxide Hydrogenolysis. [PDF]
OrganometallicsIn this paper, we report the development of ruthenium-catalyzed hydrogenolysis of epoxides to selectively give the branched (Markovnikov) alcohol products.
Borden OJ +7 more
europepmc +4 more sources