Selective hydrogenation via precise hydrogen bond interactions on catalytic scaffolds. [PDF]
Nat Commun, 2023 Abstract The active site environment in enzymes has been known to affect catalyst performance through weak interactions with a substrate, but precise synthetic control of enzyme inspired heterogeneous catalysts remains challenging.
Shi S +5 more
europepmc +6 more sources
Selective hydrogenation through phosphazide formation. [PDF]
RSC AdvThe selective hydrogenation of ketones without any reaction at the azide moiety is disclosed. A key factor in the success of the reaction is the formation of phosphazides and catalyst poisoning.
Yasuda T, Yoshida S.
europepmc +2 more sources
Highly selective hydrogenation of furfural over supported Pt nanoparticles under mild conditions [PDF]
, 2015 The selective liquid phase hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on SiO₂, ZnO, γ-Al2O₃, CeO₂ is reported under extremely mild conditions.
Durndell, Lee J. +6 more
core +1 more source
Development of covalent triazine frameworks as heterogeneous catalytic supports [PDF]
, 2019 Covalent triazine frameworks (CTFs) are established as an emerging class of porous organic polymers with remarkable features such as large surface area and permanent porosity, high thermal and chemical stability, and convenient functionalization that ...
Krishnaraj, Chidharth +3 more
core +1 more source
Highly active iridium(I) complexes for the selective hydrogenation of carbon-carbon multiple bonds [PDF]
, 2011 New iridium(I) complexes, bearing a bulky NHC/phosphine ligand combination, have been established as extremely efficient hydrogenation catalysts that can be used at low catalyst loadings, and are compatible with functional groups which are often ...
Andersson, Shalini +5 more
core +1 more source
Palladium-bismuth intermetallic and surface-poisoned catalysts for the semi-hydrogenation of 2-methyl-3-butyn-2-ol [PDF]
, 2015 The effects of poisoning of Pd catalysts with Bi and annealing in a polyol (ethylene glycol) were studied on the semi-hydrogenation of 2-methyl-3-butyn-2-ol (MBY).
Anderson, James A. +4 more
core +1 more source
Ultrasound- and microwave-assisted preparation of lead-free palladium catalysts: effects on the kinetics of diphenylacetylene semi-hydrogenation [PDF]
, 2015 The effect of environmentally benign enabling technologies such as ultrasound and microwaves on the preparation of the lead-free Pd catalyst has been studied.
Bonrath, Werner +6 more
core +1 more source
Liquid-phase hydrogenation of bio-refined succinic acid to 1,4-butanediol using bimetallic catalysts [PDF]
, 2019 open access articleDevelopment of a Crotalaria juncea based biorefinery produce large quantity of waste glycerol after trans-esterification of the juncea seeds.
Baidya, P.K. +3 more
core +7 more sources
Palladium nanoparticles by electrospinning from poly(acrylonitrile-co-acrylic acid)-PdCl2 solutions. Relations between preparation conditions, particle size, and catalytic activity [PDF]
, 2004 Catalytic palladium (Pd) nanoparticles on electrospun copolymers of acrylonitrile and acrylic acid (PAN-AA) mats were produced via reduction of PdCl2 with hydrazine.
Basu B. +21 more
core +3 more sources
Selective hydrogenation in trickle-bed reactor. Experimental and modelling including partial wetting. [PDF]
, 2003 A steady state model of a trickle bed reactor is developed for the consecutive hydrogenation of 1,5,9-cyclododecatriene on a Pd/Al2O3 catalyst. Various experiments have shown that the selectivity of this reaction towards the product of interest is much ...
Delmas, Henri +3 more
core +3 more sources