Results 41 to 50 of about 1,055,415 (308)

Advances in selective hydrogenation of nitrobenzene toward p-aminophenol

open access: yesSustainable Chemistry for Climate Action
p-Aminophenol is an important intermediate for dyestuff, medical and rubber. Selective hydrogenation of nitrobenzene is a green and environmentally friendly preparation process for the p-aminophenol synthesis.
Jinzhi Lu, Hao Wang, Xiao Cai, Yan Zhu
doaj   +1 more source

An Efficient Continuous Flow Synthesis for the Preparation of N-Arylhydroxylamines: Via a DMAP-Mediated Hydrogenation Process

open access: yesMolecules, 2023
The selective hydrogenation of nitroarenes to N-arylhydroxylamines is an important synthetic process in the chemical industry. It is commonly accomplished by using heterogeneous catalytic systems that contain inhibitors, such as DMSO.
Jianli Chen   +7 more
doaj   +1 more source

Ruthenacycles and Iridacycles as Catalysts for Asymmetric Transfer Hydrogenation and Racemisation [PDF]

open access: yes, 2010
Ruthenacycles, which are easily prepared in a single step by reaction between enantiopure aromatic amines and [Ru(arene)Cl2]2 in the presence of NaOH and KPF6, are very good asymmetric transfer hydrogenation catalysts.
Ben L. Feringa   +53 more
core   +1 more source

Facile synthesis of biomass-based carbon materials nano-Ni-based catalysts and its application in selective hydrogenation of alkynes [PDF]

open access: yes, 2021
The development of high efficiency, excellent selectivity, and super activity metal catalyst for chemical selective hydrogenation of alkynes to olefin is of great significance in the field of the chemical industry.
Jianguo, liu   +2 more
core   +1 more source

Breaking scaling relationships in alkynol semi-hydrogenation by manipulating interstitial atoms in Pd with d-electron gain

open access: yesNature Communications, 2022
Circumventing the linear scaling relationship in the semi-hydrogenation is challenging. Here the authors report a method for breaking the scaling relationships using ordered mesoporous carbon-supported Pd nanocatalysts with d-electron gain by p-block ...
Yang Yang   +10 more
doaj   +1 more source

Iridium-Catalyzed asymmetric hydrogenation : A: Studies on the synthesis of pyrazine-based P,N Ligands, B: Diastereoselective hydrogenation of chiral cyclohexenes [PDF]

open access: yes, 2016
The synthesis of a new ligand class of pyrazine based ligands and their attempted complexation with iridium to form dimeric complexes is presented. Furthermore, the synthesis of chiral cyclohexenes by enantioselective Diels-Alder reactions is shown ...
Scheil, Robin
core   +1 more source

Internal lattice oxygen sites invert product selectivity in electrocatalytic alkyne hydrogenation over copper catalysts

open access: yesNature Communications
Copper-based catalysts exhibit excellent performance of electrocatalytic alkynes hydrogenation, especially for the selective alkynes hydrogenation toward alkenes.
Mengyu Li   +11 more
doaj   +1 more source

Hyperosmotic stress induces PARP1‐mediated HPF1‐dependent mono(ADP‐ribosyl)ation

open access: yesFEBS Letters, EarlyView.
Sorbitol‐induced hyperosmotic stress rapidly induces reversible mono(ADP‐ribosyl)ation (MARylation) on PARP1 without the signs of genotoxic signaling. We show that PARP1 autoMARylation is HPF1 dependent and forms hydroxylamine‐resistant O‐glycosidic linkages.
Anna Georgina Kopasz   +11 more
wiley   +1 more source

Selective Hydrogenation of Acetylene over a MoP Catalyst

open access: yes, 2011
Selective Hydrogenation of Acetylene over a MoP CatalystA MoP catalyst was prepared by high temperature hydrogen reduction. Its properties were investigated by X-ray diffraction and in-situ X-ray photoelectron spectroscopy.
Jiang Zongxuan   +5 more
core   +1 more source

Identification of Copper as an Ideal Catalyst for Electrochemical Alkyne Semi-hydrogenation

open access: yes, 2022
Selective removal of ∼1% acetylene impurity from ethylene is an essential process to prevent the poisoning of the Ziegler–Natta catalyst in polyethylene production.
Cheng Cai (4684924)   +5 more
core   +2 more sources

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