Results 51 to 60 of about 24,483 (311)

An unexpected alternative viologen electron mediator site in tungsten‐containing formate dehydrogenase

open access: yesFEBS Letters, EarlyView.
An unexpected alternative interaction site for ethyl viologen was identified in formate dehydrogenase 1 from Methylorubrum extorquens. Combined mutagenesis, kinetic analysis, and docking revealed that aromatic residues near an iron–sulfur cluster enable flavin mononucleotide‐independent electron transfer, offering a framework for engineering improved ...
Eleni G. Poloniataki, Yong Hwan Kim
wiley   +1 more source

Phosphoinositides and inositol phosphates as molecular glues

open access: yesFEBS Letters, EarlyView.
Inositol phosphates (IPs) and phosphoinositides (PIPs) regulate diverse eukaryotic processes. Beyond recruiting signaling proteins or acting as structural cofactors, recent studies suggest they mediate protein–protein interactions as natural molecular glues.
Aleshia Seaton‐Terry   +9 more
wiley   +1 more source

Preparação e atividade catalítica de agregados nanoestruturados de metais nobres estabilizados por surfactantes dipolares iônicos baseados no anel imidazol [PDF]

open access: yes, 2012
Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas. Programa de Pós-Graduação em Química.O presente trabalho descreve a aplicação de uma classe especial de surfactantes para a síntese de nanopartículas ...
Souza, Bruno Silveira de
core  

Three phosphatase families form a community: The phosphohydrolases that act upon inositol pyrophosphates

open access: yesFEBS Letters, EarlyView.
Inositol pyrophosphates are energy‐rich signaling molecules that perform critical functions in cells. Three different families of phosphatases hydrolyze the β phosphate of the inositol pyrophosphate molecules: two have narrow specificities and one is promiscuous.
Ronda J. Rolfes
wiley   +1 more source

Strain-Released Hydrogenation of Donor-Acceptor Cyclopropane and Cyclobutane via Electrochemical Site Selective Carbonyl Reduction

open access: yes, 2023
An external oxidant or reductant, acid-free electrochemical protocol is established towards the hydrogenation of strained rings at room temperature and atmospheric pressure. After control experiments, it is revealed that the reaction is initiated via the
Nakshatra, Banerjee   +3 more
core   +1 more source

Reconstructing enzyme evolution by protein engineering

open access: yesFEBS Letters, EarlyView.
Natural enzyme evolution can be retraced by protein engineering methods such as directed evolution, rational design, and ancestral sequence reconstruction. These approaches reveal how enzymes emerged from ligand‐binding scaffolds, developed varying substrate preferences, formed oligomeric complexes, adapted to environmental changes, and evolved novel ...
Lukas Drexler   +2 more
wiley   +1 more source

Tumour–host interactions in Drosophila: mechanisms in the tumour micro‐ and macroenvironment

open access: yesMolecular Oncology, EarlyView.
This review examines how tumour–host crosstalk takes place at multiple levels of biological organisation, from local cell competition and immune crosstalk to organism‐wide metabolic and physiological collapse. Here, we integrate findings from Drosophila melanogaster studies that reveal conserved mechanisms through which tumours hijack host systems to ...
José Teles‐Reis, Tor Erik Rusten
wiley   +1 more source

Selective ensembles in supported palladium sulfide nanoparticles for alkyne semi-hydrogenation

open access: yesNature Communications, 2018
Developing robust catalysts for alkyne semi-hydrogenation remains a challenge. Here, the authors introduce a scalable protocol to prepare crystal phase and orientation controlled Pd3S nanoparticles supported on carbon nitride, exhibiting unparalleled ...
Davide Albani   +6 more
doaj   +1 more source

Catalytic Performance of Ru/polymer Catalyst in the Hydrogenation of Furfural to Furfuryl Alcohol

open access: yesChemical Engineering Transactions, 2020
Furfural (FF) is one of the main components of bio-oil obtained by the treatment of lignocellulose biomass. Furfural alcohol (FA) as the main product of the selective FF hydrogenation is a source of value-added chemicals.
Mikhail Sulman   +8 more
doaj   +1 more source

Application of Hydrogen Selective Membranes to IGCC

open access: yesEnergy Procedia, 2013
AbstractThis study considers the integration of Pd-based H2-selective membranes in integrated gasifier combined cycles (IGCC) from both technical and economical point of view. The selected gasification system is based on Shell technology. Two different dry feeding systems are investigated: the first is a state-of-the- art nitrogen-based lock hopper ...
MANZOLINI, GIAMPAOLO   +3 more
openaire   +3 more sources

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