Alkene Hydrogenation by a Cationic, Nine‐Coordinate Molybdenum(VI) Pentahydride Catalyst
Chemistry – A European Journal, EarlyView.While late 3d metals dominate efforts to replace precious metals in homogeneous hydrogenation, molybdenum has remained largely ignored. This work reveals that a nine‐coordinate pentahydrido molybdenum complex can hydrogenate a broad range of alkenes efficiently, demonstrating that early‐metal polyhydrides can serve as genuine catalysts rather than mere
Arno Estival +9 more
wiley +1 more source
Design of Fuel‐Dependent, Complex‐Coacervate‐Based Synthetic Cells
Chemistry – A European Journal, EarlyView.Fuel‐dependent synthetic cells form and persist only in the presence of chemical fuel, decaying under starvation. We establish design rules for hexapeptide‐based coacervates, showing that tryptophan enhances polyanion binding, extends lifetime, and reduces waste sensitivity.
Anna‐Lena Holtmannspötter +9 more
wiley +1 more source
Distinct contributions of hippocampal pathways in learning regularities and exceptions revealed by functional footprints. [PDF]
Proc Natl Acad Sci U S AGumus M, Mack ML.
europepmc +1 more source
Chemistry – A European Journal, EarlyView.This study introduces PROSPECT, a 2D solid‐state NMR method that correlates MHz‐wide, low‐γ anisotropic powder patterns. PROSPECT operates by progressively depleting a shared 1H dipolar‐order reservoir via two independently stepped cross‐polarizing offsets, yielding homonuclear and heteronuclear correlations without requiring direct transfers or even ...
Rihards Aleksis, Lucio Frydman
wiley +1 more source
Next-Generation Target Discovery in ESKAPE Pathogens: An AI-Driven Framework from Omics-Based to Systems-Level Modeling and Clinical Translation. [PDF]
Antibiotics (Basel)Chines E +9 more
europepmc +1 more source
N─H or O─H Bond Activation With a Bicyclic Si4 Ring Compound
Chemistry – A European Journal, EarlyView.The bicyclic Si4 ring compound with zwitterionic character reacts with NH3, H2O, and selected alcohols to give functionalized saturated silicon rings, siliconoid clusters with unsubstituted Si atoms, or simple 1,3‐addition products. The experimentally observed reactivity could be rationalized based on results from mechanistic calculations employing ...
Michael Quest +7 more
wiley +1 more source
Effect of low-dose, high-frequency advanced life support training versus annual full-day training on simulation-based resuscitation performance: a randomized controlled trial. [PDF]
BMC Med EducMoll L, Riessen R, Dahlmann P, Häske D.
europepmc +1 more source
Discovery of an Atypical Arp2/3 Complex in Malaria Parasites Sheds New Light on Nuclear Actin
Cytoskeleton, EarlyView.ABSTRACT The Arp2/3 complex is a key actin nucleator essential for cytoskeletal dynamics in eukaryotes. Previously believed absent in apicomplexan parasites, we recently identified an atypical Arp2/3 complex in malaria parasites consisting of five divergent subunits and a putative kinetochore‐associated factor.
Franziska Hentzschel +2 more
wiley +1 more source
ZNF827 pleiotropic cardiovascular risk locus involves regulation by nuclear factor-1. [PDF]
Clin Sci (Lond)Liu Y +7 more
europepmc +1 more source
Stochastic Gradient Descent in High Dimensions for Multi‐Spiked Tensor PCA
Communications on Pure and Applied Mathematics, EarlyView.ABSTRACT We study the high‐dimensional dynamics of online stochastic gradient descent (SGD) for the multi‐spiked tensor model. This multi‐index model arises from the tensor principal component analysis (PCA) problem with multiple spikes, where the goal is to estimate the unknown signal vectors within the N$N$‐dimensional unit sphere through maximum ...
Gérard Ben Arous +2 more
wiley +1 more source