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Fluorescent Silver Nanoclusters in Condensed DNA
ChemPhysChem, 2013AbstractWe study the formation and fluorescent properties of silver nanoclusters encapsulated in condensed DNA nanoparticles. Fluorescent globular DNA nanoparticles are formed using a dsDNA–cluster complex and polyallylamine as condensing agents. The fluorescence emission spectrum of single DNA nanoparticles is obtained using tip‐enhanced fluorescence ...
Ivan L, Volkov +5 more
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A complementary palette of fluorescent silver nanoclusters
Chemical Communications, 2010We report the synthesis and photophysical properties of silver-nanoclusters templated on DNA, with fluorescence excitation and emission at distinct wavelengths that are tuned to common laser excitation wavelengths.
Jaswinder, Sharma +4 more
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Ferrocenyl Functionalized Silver-Chalcogenide Nanoclusters
Inorganic Chemistry, 2011New (chalcogenoethyl)ferrocenylcarboxalate functionalized silver chalcogenide nanoclusters were synthesized using a combination of silylated chalcogen reagents at low temperatures. The addition of E(SiMe(3))(2) to reaction mixtures of FcC{O}OCH(2)CH(2)ESiMe(3) (E = S, Se) and (Ph(3)P)(2)·AgOAc affords nanoclusters with approximate molecular formulas ...
MacDonald, D. G. +2 more
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A Sodalite‐Type Silver Orthophosphate Cluster in a Globular Silver Nanocluster
Angewandte Chemie International Edition, 2020AbstractThe synthesis and structure of a giant 102‐silver‐atom nanocluster (NC) 1 is presented. X‐ray structural analysis reveals that 1 features a multi‐shelled metallic core of Ag6@Ag24@Ag60@Ag12. An octahedral Ag6 core is encaged by a truncated octahedral Ag24 shell.
Chenglong Deng +9 more
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Color Tunability and Electrochemiluminescence of Silver Nanoclusters
Angewandte Chemie International Edition, 2009AbstractColorful clusters: Silver nanoclusters consisting of only a few atoms exhibit large chemical‐environment‐responsive shifts of their optical absorption and emission bands, that is, large solvatochromism (see picture). The photophysical characteristics and electrochemiluminescence of the Ag clusters give them remarkable advantages over larger ...
Isabel, Díez +8 more
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A Polyoxochromate Templated 56-Nuclei Silver Nanocluster
Inorganic Chemistry, 2020Most of polyoxometallates (POMs) templated silver nanoclusters recorded so far are polyoxomolybdates and polyoxotungstates; however, as congeneric polyoxochromates, they are rarely observed in silver nanoclusters. Herein, a high-nuclearity polyoxochromate, (CrIII4CrVI8O36)12-, is uncovered in a novel silver nanocluster (SD/Ag56a) as an anion template ...
Zhi Wang +8 more
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Thermodynamic properties of silver nanoclusters
Inorganic Materials, 2012Icosahedral models of magic number silver clusters have been constructed using molecular dynamics simulations with the Doyama-Kogure potential. We have calculated the energy, heat capacity, entropy, Gibbs energy change, and excess surface energy as functions of cluster size and temperature. The vibrational contributions to the heat capacity and entropy
A. N. Sirenko, D. K. Belashchenko
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A nanocluster beacon based on the template transformation of DNA-templated silver nanoclusters
Chemical Communications, 2016We developed a novel light-up nanocluster beacon for sensitive and selective DNA detection based on the template transformation by shuttling dark Ag nanoclusters to a bright scaffold through hybridization.
Ye, Teng +4 more
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Photoactivated Fluorescence from Individual Silver Nanoclusters
Science, 2001Fluorescence microscopy of nanoscale silver oxide (Ag 2 O) reveals strong photoactivated emission for excitation wavelengths shorter than 520 nanometers. Although blinking and characteristic emission patterns demonstrate single-nanoparticle observation, large-scale dynamic color changes were also observed, even from
L A, Peyser +3 more
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Fluorescent silver nanoclusters stabilized by DNA scaffolds
Chemical Communications, 2014Fluorescent silver nanoclusters, in particular DNA stabilized (templated) silver nanoclusters, have attracted much attention because of their molecule-like optical properties, strong fluorescence and good biocompatibility. In this feature article, we summarize the DNA stabilized silver nanoclusters from the viewpoints of synthesis, optical properties ...
Zhiqin, Yuan +3 more
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