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Hydrosilylation of Esters via a Titanocene(III) Borohydride-PMHS System: Scope, Limitations, and Mechanistic Insights. [PDF]

ACS Omega
Fianu G, Azar J, Bulted E, Jones E, Flowers RA.   +4 more
europepmc   +1 more source

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Recycling process of sodium metaborate to sodium borohydride

International Journal of Hydrogen Energy, 2003
Abstract Sodium borohydride ( NaBH 4 ) was synthesized by reacting sodium metaborate ( NaBO 2 ) with magnesium hydride ( MgH 2 ) or magnesium silicide ( Mg 2 Si ) by annealing (350– 750° C ) under high H 2 pressure (0.1– 7 MPa ) for 2– 4 h .
Yoshitsugu Kojima
exaly   +2 more sources

Sodium borohydride as a fuel for the future

Renewable and Sustainable Energy Reviews, 2011
Abstract In a time of unprecedented change in environmental, geopolitical and socio-economic world affairs, the search for new energy materials has become a topic of great relevance. Sodium borohydride, NaBH 4 , seems to be a promising fuel in the context of the future hydrogen economy.
Diogo M F Santos, Cesar A C Sequeira
exaly   +2 more sources

On the electrosynthesis of sodium borohydride

International Journal of Hydrogen Energy, 2010
Sodium borohydride (NaBH4) is a versatile reducing agent used in many industrial processes. These include organic and pharmaceutical synthesis, wastewater treatment, and paper pulp bleaching. Additionally, it is a unique material in its ability to carry large amounts of hydrogen in a safe and innocuous form.
D.M.F. Santos, C.A.C. Sequeira
openaire   +1 more source

Sodium Borohydride and Iodine

2013
(Sodium borohydride) [16940-66-2] (MW 37.83) InChI = 1S/BH4.Na/h1H4;/q-1;+1 InChIKey = YOQDYZUWIQVZSF-UHFFFAOYSA-N (Iodine) [7553-56-2] (MW 253.81) InChI = 1S/I2/c1-2 InChIKey = PNDPGZBMCMUPRI-UHFFFAOYSA-N (Sodium borohydride is used as a reducing reagent in organic synthesis) (Iodine is used as a ...
Jack D. Brown, Dustin Haddenham
openaire   +1 more source

The reduction of DPN+ and TPN+ with sodium borohydride

Biochimica et Biophysica Acta (BBA) - General Subjects, 1966
Abstract The reduction of the pyridine nucleotides with NaBH 4 has been examined and the primary reduction products, the 1,2-, 1,4-, and 1,6-dihydrophyridine nucleotides, have been characterized.
S, Chaykin, L, King, J G, Watson
openaire   +2 more sources

Reduction of Solid Benzophenones with Sodium Borohydride

Journal of Thermal Analysis and Calorimetry, 1998
The solvent-free reduction of benzophenone and five substituted benzophenones with sodium borohydride to the corresponding alcohols was studied by thermal analysis, X-ray powder diffractometry, NMR spectroscopy, and scanning electron microscopy. In most cases, the reaction occurs via liquid eutectic phases that are formed between the benzophenone and ...
Epple, Matthias, Ebbinghaus, Stefan
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Analytical monitoring of sodium borohydride

Analytical Methods, 2013
Sodium borohydride (NaBH4) determination, both qualitative and quantitative, is of great significance in a plethora of areas. These include NaBH4 for energy systems such as direct borohydride fuel cells and in hydrogen production and storage, as well as use as a reducing agent in organic and inorganic synthesis reactions or in electrodeposition ...
Biljana Šljukić, Diogo M. F. Santos, César A. C. Sequeira, Craig E. Banks   +3 more
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Chemoselective reductions with sodium borohydride

Canadian Journal of Chemistry, 1989
Under the appropriate reaction conditions, sodium borohydride is a highly chemoselective reducing agent. The order of reactivity among carbonyl groups is conjugated enones < ketones < conjugated aldehydes < aldehydes. In general, a carbonyl group of one type can be selectively reduced in the presence of a carbonyl group of a less reactive ...
Dale E. Ward, Chung K. Rhee
openaire   +1 more source