Results 51 to 60 of about 1,293,336 (371)

Reação da cânfora com boroidreto de sódio: uma estratégia para o estudo da estereoquímica da reação de redução Reaction of camphor with sodium borohydride: a strategy to introduce the stereochemical issues of a reduction reaction

open access: yesQuímica Nova, 2010
Reduction of camphor to a mixture of borneol and isoborneol was performed using NaBH4 as the reducing agent under suitable conditions. Although more effective reduction was accomplished using toxic methanol, an alternative non-toxic ethanolic system is ...
Péricles B. Alves, Mauricio M. Victor
doaj   +1 more source

Studies on the sulfation of cellulose α-lipoate and ability of the sulfated product to stabilize colloidal suspensions of gold nanoparticles [PDF]

open access: yes, 2015
© 2015 Elsevier Ltd. A versatile method for the synthesis of cellulose α-lipoate with a low degree of substitution (DS) has been developed using N,N-dimethylacetamide (DMA)/LiCl as a solvent and N,N′-carbonyldiimidazole (CDI) as an esterification reagent.
Cheng, Fei   +4 more
core   +2 more sources

Nanomaterial Integration at Liquid–Liquid Interfaces for Green Catalysis

open access: yesAdvanced Materials, EarlyView.
Functional nanomaterials assembled at liquid–liquid interfaces create dual‐role platforms serving as emulsion stabilizers and catalytic sites, offering enhanced reaction kinetics with improved catalyst recovery and recyclability. This review examines design strategies, structure‐performance relationships, and industrial implementation prospects of ...
Bokgi Seo   +6 more
wiley   +1 more source

Bleaching of Wool with Sodium Borohydride [PDF]

open access: yesJournal of Engineered Fibers and Fabrics, 2009
An untreated wool fabric was bleached both with sodium borohydride (SBH) in the presence of sodium bisulphite (SBS) solution and with a commercial H2O2 bleaching method.
Duygu Yilmazer, MSc.   +1 more
doaj  

Quantification of Nε-(2-Furoylmethyl)-L-lysine (furosine), Nε-(Carboxymethyl)-L-lysine (CML), Nε-(Carboxyethyl)-L-lysine (CEL) and total lysine through stable isotope dilution assay and tandem mass spectrometry [PDF]

open access: yes, 2015
The control of Maillard reaction (MR) is a key point to ensure processed foods quality. Due to the presence of a primary amino group on its side chain, lysine is particularly prone to chemical modifications with the formation of Amadori products (AP), Nε-
Fiore, Alberto   +3 more
core   +5 more sources

Stretchable and Strain‐Tolerant Gold‐Coated Fibrous Biosensor for Superoxide Anion Monitoring

open access: yesAdvanced Materials Technologies, EarlyView.
A breathable, stretchable gold nanomesh–TPU fiber platform is developed via controlled electroless deposition, enabling uniform through‐thickness conductivity while preserving porosity. Functionalized with superoxide dismutase, the system achieves selective, real‐time electrochemical detection of superoxide with high sensitivity, mechanical durability,
Jafar M. Batayneh, Ahyeon Koh
wiley   +1 more source

Natural Products Inspired Scaffold Diversification Leads to Unnatural Molecular Warhead and Covalent Strategy to Modulating Protein Function through Electrophilic Bromine Transfer

open access: yesAdvanced Science, EarlyView.
We report a new thiolate‐reactive α,α‐gem‐dibromo lactam warhead that activates transcription factor Nrf2 and demonstrates anti‐inflammatory activities, which have implications in cancer, neurodegeneration, and cardiovascular diseases. RNA‐seq illuminated detailed transcriptional profiles, and chemical reactions with cysteine‐containing compounds ...
Beau R. Brummel   +16 more
wiley   +1 more source

Alcohol deoxygenation in the presence of SiO2@FeSO4 nanocomposite

open access: yesResults in Chemistry
SiO2@FeSO4 nanocomposite was studied as a nanocatalyst for deoxygenation of alcohols. Alcohols were converted to alkanes by removing oxygen in the presence of SiO2@FeSO4 nanocatalyst.
Leyla Bagheri, Mina Jabbarnejad
doaj   +1 more source

The Effect of Reducing Agent for Synthesizing Palladium Nanoparticle on Carbon Nanotube Support and Its Superior Catalytic Activity towards Methanol Oxidation Reaction

open access: yesECS Advances, 2023
In this report, we have synthesized carbon nanotube supported palladium nanoparticles (CNT-Pd) by using different reducing agents such as sodium borohydride (SBH), hydrazine monohydrate (HY) and ascorbic acid (AA) for the methanol oxidation reaction (MOR)
Sabina Yasmin   +3 more
doaj   +1 more source

Rehydrogenation of Sodium Borates to Close the NaBH4-H2 Cycle: A Review

open access: yesEnergies, 2021
In 2007, the US Department of Energy recommended a no-go on NaBH4 hydrolysis for onboard applications; however, the concept of a NaBH4-H2-PEMFC system has the potential to become a primary source for on-demand power supply.
Helder X. Nunes   +3 more
doaj   +1 more source

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