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A Generalized Theory for the Structural and Spatial Mapping of Energy, Entropy, and Free Energy. [PDF]
Gilson MK +6 more
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Thermodynamics of Solution of Histidine
Thermochimica Acta, 2006Abstract The enthalpies of solution of l -histidine in water at 288.15–318.15 K and 0.003–0.15 mol kg −1 were measured. The enthalpies of solution were found to be independent of the solute molality up to ∼0.1 mol kg −1 . Standard enthalpies and heat capacities of solution were computed.
Andrey V Kustov
exaly +2 more sources
Statistical Thermodynamics of Solutions
The Journal of Chemical Physics, 1956A new approach to the statistical problem of solutions is presented, which combines the main ideas of the cell method and of the theorem of corresponding states. The basic assumption is that the cell partition function of a molecule in the solution may be formally expressed by the same function as in pure liquid, but with other well-defined values of ...
Prigogine, Ilya +2 more
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The thermodynamics of solutions
Pure and Applied Chemistry, 1989Abstract
D. Feakins +3 more
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2008
This chapter begins the discussion of open systems for which the fundamental relation introduced in Chapter 2 needs to be modified to U = U(S, V, n1, n2 …), where ni is the mole numbers of the component i, thus leading to a new intrinsic thermodynamic property known as the chemical potential, μi, and formulation of chemical equilibrium in terms of this
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This chapter begins the discussion of open systems for which the fundamental relation introduced in Chapter 2 needs to be modified to U = U(S, V, n1, n2 …), where ni is the mole numbers of the component i, thus leading to a new intrinsic thermodynamic property known as the chemical potential, μi, and formulation of chemical equilibrium in terms of this
openaire +2 more sources

