Results 251 to 260 of about 153,560 (299)
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Journal of Pharmaceutical Sciences, 1972
It is known that polar solvents penetrate the montmorillonite lattice and that multiple layers of solvent can exist between the silicate layers. It is shown here that the number of layers in the interlaminar spacing is different when the clay is equilibrated with liquid than when it is equilibrated with vapor.
J T, Carstensen, K S, Su
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It is known that polar solvents penetrate the montmorillonite lattice and that multiple layers of solvent can exist between the silicate layers. It is shown here that the number of layers in the interlaminar spacing is different when the clay is equilibrated with liquid than when it is equilibrated with vapor.
J T, Carstensen, K S, Su
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The Journal of Physical Chemistry B, 2018
Experiments have revealed that DNA solvation dynamics is characterized by multiple time scales ranging from a few picoseconds to a few hundred nanoseconds and in some cases even up to several microseconds. The last part of decay is not only slow but can also be described by a power law (PL).
Saumyak Mukherjee +3 more
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Experiments have revealed that DNA solvation dynamics is characterized by multiple time scales ranging from a few picoseconds to a few hundred nanoseconds and in some cases even up to several microseconds. The last part of decay is not only slow but can also be described by a power law (PL).
Saumyak Mukherjee +3 more
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Entropies of solvation of solvated electrons
The Journal of Physical Chemistry, 1991An expression is derived for the entropy of solvation of a solvated electron that can be evaluated directly from (1) an established correlation between the spectral energy and solvent energy of the solvated-electron system and (2) the entropy of the pure solvent.
Sidney Golden, Thomas R. Tuttle
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Solvation effects in partially solvated Grignard reagents
Journal of Organometallic Chemistry, 1999Abstract Grignard reagents were prepared from alkyl chlorides ( n -BuCl, i -PrCl, s -BuCl and t -BuCl) in toluene in the presence of one or less equivalents of various organic bases (ethers, triethylamine). Ultrasound was used to promote the process.
Ants Tuulmets, Dmitri Panov
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Interfacial solvation thermodynamics
Journal of Physics: Condensed Matter, 2016Previous studies have reached conflicting conclusions regarding the interplay of cavity formation, polarizability, desolvation, and surface capillary waves in driving the interfacial adsorptions of ions and molecules at air-water interfaces. Here we revisit these questions by combining exact potential distribution results with linear response theory ...
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Solvated electrons or solvated solvent anions?
Radiation Physics and Chemistry (1977), 1981Abstract Although the cavity or F-centre model for “trapped” or “solvated” electrons in polar solvents, both fluid and rigid, has gained wide acceptance, it has recently been suggested that a better model is one in which a solvent anion is solvated as such by the medium.
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2023
In this chapter, we discuss one central property of electrolytes, ion solvation, which not only determines the bulk behaviors of an electrolyte such as solubility, viscosity and ion transport, but also affects interfacial and interphasial properties such as electrochemical stability and interphase chemistries. The preferential solvation of working ions
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In this chapter, we discuss one central property of electrolytes, ion solvation, which not only determines the bulk behaviors of an electrolyte such as solubility, viscosity and ion transport, but also affects interfacial and interphasial properties such as electrochemical stability and interphase chemistries. The preferential solvation of working ions
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Solvation of Radical Cations in Water—Reactive or Unreactive Solvation?
Chemistry, 2000The solvation and reaction of ethylene radical cation in aqueous solution has been studied with Car-Parrinello molecular dynamics simulations. All ab initio simulations were performed using a system of 56 water and one ethylene molecule. Using a favorable symmetrically solvated radical cation as the starting point of the simulation a fast addition of ...
Mohr, M. +3 more
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"Protein Engineering, Design and Selection", 1989
W G, Richards, P M, King, C A, Reynolds
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W G, Richards, P M, King, C A, Reynolds
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Solvated electrons: what is solvated?
The Journal of Physical Chemistry, 1991Thomas R. Tuttle, Sidney Golden
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