Results 101 to 110 of about 7,506 (232)

Twist and Shine: The Impact of Halogen Substitution on Thiele Hydrocarbon's Optical Properties

open access: yesAngewandte Chemie, Volume 138, Issue 6, 2 February 2026.
Halogenation in Thiele hydrocarbons strongly influences structure and excited‐state dynamics. Depending on substitution, “boat” folded forms show large Stokes shifts and strong solvatochromism, while planar “butterfly” derivatives exhibit near‐unity photoluminescence yields.
Angela Punzi   +11 more
wiley   +2 more sources

Solvatochromic Polarity, Physicochemical Properties, and Spectral Analysis of New Triple NADES-Based on Urea–Glycerol

open access: yesMolecules
In the present study, ten type-V natural deep eutectic solvents (NADESs) were synthesized and comprehensively characterized, based on urea as a hydrogen-bond acceptor and three different groups of donors—glycerol, organic carboxylic acids, and ...
Sezan Ahmed   +5 more
doaj   +1 more source

Primer to Voltage Imaging With ANNINE Dyes and Two-Photon Microscopy

open access: yesFrontiers in Cellular Neuroscience, 2019
ANNINE-6 and ANNINE-6plus are voltage-sensitive dyes that when combined with two-photon microscopy are ideal for recording of neuronal voltages in vivo, in both bulk loaded tissue and the dendrites of single neurons. Here, we describe in detail but for a
Bernd Kuhn, Christopher J. Roome
doaj   +1 more source

Preferential solvation of 4-(4-nitrophenylazo) aniline in alcohol-dioxane binary solvent mixture [PDF]

open access: yes, 2012
Electronic spectroscopy is a suitable method for studying solvation. It has been observed that maximum energy of electronic transition of various solutes depends to a great extent on the local environment around the solute.
Behera, Susanta Kumar, Sahoo, Anupam
core  

Synthesis, electrochemical and spectroscopic properties of molybdenum complexes bearing 5-alkoxy-thiophenic or- bithiophenic groups [PDF]

open access: yes, 2005
Trans-[FMo{NN=CH(5´-R-thienyl)}(dppe)2][BF4] (R = OMe and OEt) and trans[FMo{NN=CH(5’-R-2,2’-bithienyl)}(dppe)2][BF4] (R = OMe, OEt and O(iPr)) were synthesised in good yields by reacting 2-formyl-5-alkoxylthiophenes and 5-formyl-5 ...
Ashwell   +22 more
core   +1 more source

Controlling Aggregation‐Induced Emission by Sterics in Nitrogen–Boron–Nitrogen (NBN)‐Doped Tetraphenylethylene‐Like Molecular Propellers

open access: yesChemistry – A European Journal, EarlyView.
Nitrogen–boron–nitrogen (NBN)‐substituted molecular propellers are presented as structural framework for aggregation induced emission (AIE) applications. Steric hindrance is revealed to steer maximum‐AIE behavior, leading to refined control over assembly‐induced luminescence.
Nico Groß   +4 more
wiley   +1 more source

Emissive Liquid Crystalline Boron C,N‐Chelates: Synthesis, Self‐assembly, and Photophysical Properties

open access: yesChemistry – A European Journal, EarlyView.
Novel emissive liquid crystalline boron C,N‐chelates were prepared by integrating mesogenic units into the boron C,N‐core. Depending on the substituent at the boron, stable SmA or N mesophases were achieved while maintaining intense blue emission with excellent quantum yields (61%–100%).
Franziska Müller   +7 more
wiley   +1 more source

BORAZANs:  Tunable Fluorophores Based on 2-(Pyrazolyl)aniline Chelates of Diphenylboron [PDF]

open access: yes, 2007
The reaction between 2-pyrazolyl-4-X-anilines, H(pzAnX), (X = para-OMe (L1), Me (L2), H (L3), Cl (L4), CO2Et (L5), CF3 (L6), CN (L7)) and triphenylboron in boiling toluene affords the respective, highly emissive N,N‘-boron chelate complexes, BPh2(pzAnX) (
Gardinier, James R.   +6 more
core   +1 more source

An interpretation of fluctuations in enzyme catalysis rate, spectral diffusion, and radiative component of lifetimes in terms of electric field fluctuations [PDF]

open access: yes, 2007
Time-dependent fluctuations in the catalysis rate ({delta}k(t)) observed in single-enzyme experiments were found in a particular study to have an autocorrelation function decaying on the same time scale as that of spectral diffusion {delta}{omega}0(t ...
Adcock   +26 more
core   +2 more sources

T‐Shaped 8‐Aryl(ethynyl)‐Substituted Psoralens With Tunable Charge‐Transfer Absorption

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Starting from 8‐methoxypsoralen, new 8‐arylated and 8‐alkynylated psoralen derivatives are accessible by cross‐coupling. These T‐shaped π‐expanded chromophores are luminescent and photophysics reveal a highly polar excited state with tunable charge‐transfer character.
Lena T. Leusch, Thomas J. J. Müller
wiley   +1 more source

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