Results 81 to 90 of about 4,021 (220)

Carbonyl lock enables multi‐resonant organoboron framework with substantially enhanced spin‐flip and reduced emission bandwidth

open access: yesFlexMat, EarlyView.
Integrating carbonyl lock onto multi‐resonant organoboron emitters is found to go beyond conventional bridge unit. It can not only suppress the molecular relaxation as conventional bridge, but also substantially affect electronic engineering via carbonyl integration, activating multiple up‐conversion channels, thus leading to an accelerated spin‐flip ...
Tingfeng Chen   +7 more
wiley   +1 more source

Changes of phthalocyanine visible color caused by near-IR solvatochromism

open access: yes, 2018
Herein, we show that the Zn complex of 1,4,8,11,15,18,22,28-octakis(butoxy)phthalocyanine exhibits solvatochromism and characterize the corresponding visible color changes.
Shiori Uchiyama   +4 more
core   +1 more source

Mechanophores for Mechano‐Imaging in Polymeric Materials

open access: yesHelvetica Chimica Acta, EarlyView.
Mechanophore‐based mechanochromic systems convert mechanical forces in polymers into optical signals, enabling direct imaging of stress localization and molecular damage. This perspective highlights recent advances in mechanophore design and their use to probe local mechanics across diverse polymer matrices, and concludes by outlining opportunities for
Jess M. Clough
wiley   +1 more source

Solvatochromism of the Homoleptic Coordination Complex, Hexammine Nickel Tetrafluoroborate, [Ni(NH3)6][(BF4)2]: A Case of Solvatochromism and Hydrochromaticism as a Solvent Polarity Sensor

open access: yes, 2013
Chromotropism or color change of diverse organic and inorganic materials is an intriguing aspect of chemical research and the chemical industry.
Meguerdichian, Andrew G.
core   +1 more source

Synthesis and Solvatochromism of Substituted 4‑(Nitrostyryl)phenolate Dyes

open access: yes, 2015
4-(Nitrostyryl)­phenols 2a–9a were synthesized, and by deprotonation in solution, the solvatochromic phenolates 2b–9b were formed. Their absorption bands in the vis region of the spectra are due to π–π* electronic transitions, of an intramolecular charge-
Celso R. Nicoleti (1545667)   +10 more
core   +3 more sources

A Fluorescent Thermometer Based on a Pyrene-Labeled Thermoresponsive Polymer

open access: yesSensors, 2010
Thermoresponsive polymers that undergo a solubility transition by variation of the temperature are important materials for the development of ‘smart’ materials.
Ulrich S. Schubert   +3 more
doaj   +1 more source

Hybrid Quatsome‐Encapsulated Silver Nanoparticles as Stable Plasmonic Substrates for Surface‐Enhanced Raman Scattering

open access: yesJournal of Raman Spectroscopy, EarlyView.
In this work, silver nanoparticles encapsulated within quatsome membranes have shown to preserve their plasmonic properties for at least 165 days without aggregation. These hybrid nanostructures enable strong SERS enhancement of pyrene and Prodan by confining the molecules within a few nanometers from the silver surface.
Renato Cezar Peramezza Ribeiro   +10 more
wiley   +1 more source

C=O group versus C=C(CN)2 moiety from the viewpoint of electronic absorption and fluorescence spectroscopy

open access: yesВісник Харківського національного університету: Серія xімія
The effect of changing carbonyl group to methylidenepropanedinitrile moiety onto electronic absorption and fluorescence spectra was analyzed theoretically within DFT / TD-DFT scheme.
Andrey Doroshenko
doaj   +1 more source

Synthesis, characterization, aggregation-induced emission, solvatochromism and mechanochromism of fluorinated benzothiadiazole bonded to tetraphenylethenes

open access: yes, 2018
Fluorinated benzothiadiazole bonded to two tetraphenylethenes were synthesized. The compounds exhibited remarkable aggregation-induced emission, solvatochromism and mechanochromism.
Yu, Chin-Yang   +5 more
core   +1 more source

A green solvent processable, self‐doped N‐annulated perylene butyl tetraester applied as a solar cell cathode interlayer

open access: yesPolymer International, EarlyView.
A new organic molecular cathode interlayer is presented built upon the perylene butyl tetraester scaffold. The new molecule incorporates N‐annulation and a functional amine group to control optical, electrochemical and physical properties and delivers excellent solar cell performance. Abstract We report a new amino‐bay‐substituted, N‐annulated perylene
Kathryn M Wolfe   +7 more
wiley   +1 more source

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