Results 51 to 60 of about 7,561 (220)

A BODIPY-Bridged Bisphenoxyl Diradicaloid: Solvent-Dependent Diradical Character and Physical Properties

open access: yesMolecules, 2019
We report a new boron dipyrromethene (BODIPY)-bridged bisphenoxyl diradicaloid (2), which showed closed-shell diamagnetic character in less polar solvents such as dichloromethane but open-shell diradical character with paramagnetic activity in the very ...
Fang Miao, Hoa Phan, Jishan Wu
doaj   +1 more source

Influence of plasmons on the luminescence properties of solvatochromic merocyanine dyes with different solvatochromism

open access: yesPhysical Chemistry Chemical Physics, 2023
The effect of localized surface plasmon resonance (LSPR) of a system consisting of a highly dipolar merocyanine dye and a silver nanoparticle (NP) was studied experimentally and theoretically.
Niyazbek Kh. Ibrayev   +7 more
openaire   +3 more sources

Experimental demonstration of the relationship between the second- and third-order polarizabilities of conjugated donor-acceptor molecules [PDF]

open access: yes, 1994
The dependence of the second- and third-order polarizabilities ((beta) and (gamma) ) on ground-state polarization was measured for a series of donor-acceptor polyenes using electric field induced second harmonic generation and third harmonic generation ...
Bourhill, Grant   +9 more
core   +1 more source

Highly Solvatochromic 7-Aryl-3-hydroxychromones

open access: yesThe Journal of Physical Chemistry Letters, 2012
Introduction of the dialkylaminophenyl group in position 7 of 3-hydroxychromone changes the orientation of the excited-state dipole moment and leads to superior solvatochromic properties (>170 nm emission shift in aprotic media). The excited-state intramolecular proton-transfer (ESIPT) reaction of 7-aryl-3-hydroxychromones is almost completely ...
Giordano, Luciana   +4 more
openaire   +4 more sources

Counterintuitive Fluorescence Blue Shift in Symmetry Breaking Dicationic Bis(indolium) with Two‐Photon Absorption Properties for NIR Living Cell Imaging

open access: yesAdvanced Materials, EarlyView.
Highly water‐soluble dicationic bis(indolium) dyes have been prepared, showing excellent two‐photon absorption and light emission. Their fluorescence behavior discloses an unusual increasing blue shift with increasing solvent polarity, which, in parallel, is beneficial for enhanced detection in biological media.
Carlos Benitez‐Martin   +5 more
wiley   +1 more source

A Simple, Quick, and Precise Procedure for the Determination of Water in Organic Solvents [PDF]

open access: yes, 1990
A procedure for the UV/VIS-spectroscopic determination of water by the use of a solvatochromic pyridiniumphenolate betaine is given. The water content of organic solvents is calculated by a two parameter equation from λmax of the dye.
Dimroth K.   +9 more
core   +1 more source

Attachable Solvatochromic Fluorophores and Bioconjugation Studies [PDF]

open access: yesOrganic Letters, 2013
The synthesis and utility of attachable cyclopenta[b]naphthalene solvatochromic fluorophores related to Prodan are described. Two fluorophores were selected for functionalization and bioconjugation studies. The skeletons were chemically modified to include reactive functional groups and showed minimal alteration of the optical properties when compared ...
Erica, Benedetti   +4 more
openaire   +2 more sources

Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials

open access: yesAdvanced Materials, EarlyView.
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella   +3 more
wiley   +1 more source

A High Sensitivity and Wide Dynamic Range Fiber-Optic Sensor for Low-Concentration VOC Gas Detection

open access: yesSensors, 2014
In this paper, we propose a volatile organic compound (VOC) gas sensing system with high sensitivity and a wide dynamic range that is based on the principle of the heterodyne frequency modulation method.
Md. Rajibur Rahaman Khan, Shin-Won Kang
doaj   +1 more source

Polarity-Dependent Twisted Intramolecular Charge Transfer in Diethylamino Coumarin Revealed by Ultrafast Spectroscopy

open access: yesChemosensors, 2022
Twisting intramolecular charge transfer (TICT) is a common nonradiative relaxation pathway for a molecule with a flexible substituent, effectively reducing the fluorescence quantum yield (FQY) by swift twisting motions.
Jiawei Liu, Cheng Chen, Chong Fang
doaj   +1 more source

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