Results 51 to 60 of about 2,249 (138)

Use of DFT Calculations as a Tool for Designing New Solvatochromic Probes for Biological Applications

Liquids
The intramolecular charge transfer behavior of push–pull dyes is the origin of their sensitivity to environment. Such compounds are of interest as probes for bioimaging and as biosensors to monitor cellular dynamics and molecular interactions. Those that
Cynthia M. Dupureur
doaj   +1 more source

PET-Driven Fluorescence Modulation in Halochromic Styryl Hemicyanine Dyes Targeting DNA Minor Groove

Molecules
A new series of styryl hemicyanine dyes featuring substituted N-phenylpiperazine end groups was synthesized using an environmentally friendly procedure.
Teodora Aleksandrova, Aleksandar Pashev, Sonia Ilieva, Raimundo Gargallo, Diana Cheshmedzhieva, Aleksey Vasilev   +5 more
doaj   +1 more source

New Water-Soluble Poly(propylene imine) Dendrimer Modified with 4-Sulfo-1,8-naphthalimide Units: Sensing Properties and Logic Gates Mimicking

Sensors, 2023
A new water-soluble poly(propylene imine) dendrimer (PPI) modified with 4-sulfo-1,8-naphthalimid units (SNID) and its related structure monomer analog (SNIM) has been prepared by a simple synthesis.
Awad I. Said, Desislava Staneva, Ivo Grabchev   +2 more
doaj   +1 more source

Low‐Threshold Red Lasing in Diketopyrrolopyrrole‐Based Organic Semiconductor Films

Angewandte Chemie International Edition, EarlyView.
Low‐threshold organic semiconductor lasers (OSLs) in the red region are achieved using diketopyrrolopyrrole (DPP) derivatives (DPA‐DPPMe and HMAT‐d‐DPP). Molecular design enables precise control of radiative‐decay and molecular orientation, suppressing optical losses and enhancing gain.
Youhei Chitose, Ryota Zenke, Takuma Saeki, Hsin‐Yi Wei, Rahul Murali, Shota Fukuma, Yusei Kaya, Gomathi Vinayakam Mageswari, Sai Santosh Kumar Raavi, Ja‐Hon Lin, Tzu‐Chau Lin, Chihaya Adachi   +11 more
wiley   +1 more source

β‐Ketonitrile‐Modified Prodan Derivatives as Large‐Stokes‐Shift Solvatochromic Fluorophores With Enhanced Brightness and Ratiometric Thermometric Response

Chemistry – A European Journal, EarlyView.
We report a systematic study of β‐ketonitrile–modified Prodan‐type solvatochromic fluorophores. The β‐ketonitrile substitution induces marked bathochromic shifts in absorption and emission and significantly enhances fluorescence quantum yields in nonpolar solvents.
Hiroaki Asakawa, Takuya Tanaka, Kensei Konishi, Gen‐ichi Konishi   +3 more
wiley   +1 more source

The UV-Visible Absorption Spectra of Coumarin and Nile Red in Aqueous Solution: A Polarizable QM/MM Study

Molecules
We present a comprehensive computational study of the UV-visible absorption spectra of 7-methoxycoumarin and Nile red in aqueous solution. Our fully atomistic workflow couples classical molecular dynamics (MD) with polarizable QM/MM based on fluctuating ...
Tommaso Giovannini, Matteo Ambrosetti, Chiara Cappelli   +2 more
doaj   +1 more source

Tailoring Liquid Crystalline Self‐Assembly and Photophysical Properties of Unsymmetrical Fluorenones via Polar Terminal Groups

Chemistry – A European Journal, EarlyView.
Novel liquid crystalline fluorenones bearing various head groups were synthesized and characterized. By alteration of the head group, N, SmC, or SmA phases were obtained, and emission properties could be tuned depending on solvent or temperature. ABSTRACT In this work, a series of novel unsymmetrical fluorenone derivatives bearing various head groups ...
Falk Feucht, Franziska Müller, Johanna Osterbrink, Anna Zens, Yann Molard, Sabine Laschat   +5 more
wiley   +1 more source

Proximal Steric Shielding Unlocks High Solid‐State Luminescence in Quinoxaline‐Fused Pyrene Heteroacenes

Chemistry – A European Journal, EarlyView.
Proximal steric tuning of quinoxaline‐fused pyrene heteroacenes enables soluble derivatives that exhibit solid‐state photoluminescence quantum yields (PLQYs) up to 82%, surpassing previous benchmarks. This work reveals key structure–property relationships for next‐generation, processable organic emitters in advanced optoelectronic applications ...
Rafiq Ahamed, Sonal Patil, Madhusudan Dutta, Godi Kiran Venkata Sai, Sergey Fisher, Anil Bhadke, Rama Krishna Gamidi, Susnata Pramanik, Tomáš Šolomek, Sudhakar Gaikwad   +9 more
wiley   +1 more source

Real‐Time In Situ Imaging of Aggregation‐Induced Emission and Solvent‐Guided Morphogenesis of a “V‐Shaped” 4‐Amino‐1,8‐Naphthalimide Tröger's Base Supramolecular Scaffold

Small Science
The influence of solvent polarity on the self‐assembly processes and its effect on the morphological outcome of self‐assembled aggregates is another domain that requires a comprehensive study.
Sankarasekaran Shanmugaraju, Deivasigamani Umadevi, Aramballi J. Savyasachi, Chris S. Hawes, Jonathan A. Kitchen, Gavin J. McManus, Thorfinnur Gunnlaugsson   +6 more
doaj   +1 more source

Synthesis and Photophysical Properties of Star‐Shaped Triphenylamine Trimers Functionalized With BODIPY and Subphthalocyanine Chromophores

Chemistry – A European Journal, EarlyView.
This study investigates how molecular topology influences the photophysical properties of star‐shaped, threefold‐symmetric triphenylamine (TPA) derivatives functionalized with three BODIPY or SubPc units. Their absorption spectra exhibit minimal solvatochromism, whereas their fluorescence intensity is strongly dependent on solvent polarity.
Habiba Boughanmi, Paula de la Rubia, Jamel‐Eddine Khiari, Tomás Torres, José García‐Calvo   +4 more
wiley   +1 more source