Results 31 to 40 of about 4,021 (220)

Predicting Solvatochromism of Chromophores in Proteins through QM/MM and Machine Learning

open access: yes
Solvatochromism occurs in both homogeneous solvents and more complex biological environments such as proteins. While in both cases the solvatochromic effects report on the surroundings of the chromophore, their interpretation in proteins becomes more ...
Patrizia, Mazzeo   +4 more
core   +3 more sources

Anti-quenching NIR-II molecular fluorophores for in vivo high-contrast imaging and pH sensing

open access: yesNature Communications, 2019
Fluorophores operating in the second near-infrared window suffer from solvatochromism-caused fluorescence quenching in biological aqueous solution. Here, the authors synthesized a series of pH-responsive pentamethine cyanine fluorophores that afford ...
Shangfeng Wang   +7 more
doaj   +1 more source

Design of Promising aza-BODIPYs for Bioimaging and Sensing

open access: yesDesigns, 2022
The obtainment of new luminophores for molecular sensorics of biosystems is becoming one of the urgent tasks in the field of chemical synthesis. The solution to each practical problem imposes its own limitations in the design of new structures with ...
Dmitry Merkushev   +5 more
doaj   +1 more source

Uncovering Aggregation‐Induced Emission in Carbon Dots for Color‐Changing Hydrogels and Information Encryption

open access: yesAngewandte Chemie, EarlyView.
Red‐emissive carbon dots (R‐CDs) exhibiting aggregation‐induced emission (AIE) and aggregation‐caused quenching (ACQ) effects are synthesized from citric acid and urea. They display weak blue fluorescence in water but strong red emission in DMF due to aggregation.
Jiafeng Wan   +11 more
wiley   +2 more sources

New electroactive asymmetrical chalcones and therefrom derived 2-amino- / 2-(1H-pyrrol-1-yl)pyrimidines, containing an N-[ω-(4-methoxyphenoxy)alkyl]carbazole fragment: synthesis, optical and electrochemical properties

open access: yesBeilstein Journal of Organic Chemistry, 2017
In this paper we present a synthetic approach to six new D–π–A–D conjugated chromophores containing the N-[ω-(4-methoxyphenoxy)alkyl]carbazole fragment. Such readily functionalizable heterocycle as carbazole was used as a main starting compound for their
Daria G. Selivanova   +6 more
doaj   +1 more source

Synthesis of novel multifunctional carbazole-based molecules and their thermal, electrochemical and optical properties

open access: yesBeilstein Journal of Organic Chemistry, 2020
Two novel carbazole-based compounds 7a and 7b were synthesised as potential candidates for application in organic electronics. The materials were fully characterised by NMR spectroscopy, mass spectrometry, FTIR, thermogravimetric analysis, differential ...
Nuray Altinolcek   +5 more
doaj   +1 more source

Synthesis of Novel Aqua ƞ4-NNNO/Cu(II) Complexes as Rapid and Selective Oxidative Catalysts for O-Catechol: Fluorescence, Spectral, Chromotropism and Thermal Analyses

open access: yesCrystals, 2021
A new tetradentate Schiff base (SB), (E)-4-fluoro-2-(1-((2-(piperazin-1-yl)ethyl)imino)ethyl)phenol, was synthesized from condensation of 2-(1-piperazinyl)ethylamine and 5-fluoro-2-hydroxyacetophenone.
Amjad M. Shraim   +5 more
doaj   +1 more source

Regulation of Fluorescence Solvatochromism To Resolve Cellular Polarity upon Protein Aggregation

open access: yes, 2021
Common solvatochromic fluorophores exhibit a bathochromic fluorescence emission wavelength shift accompanied by intensity attenuation due to the presence of nonradiative decay pathways at the excited state.
Wang Wan (1901359)   +21 more
core   +1 more source

A BODIPY-Bridged Bisphenoxyl Diradicaloid: Solvent-Dependent Diradical Character and Physical Properties

open access: yesMolecules, 2019
We report a new boron dipyrromethene (BODIPY)-bridged bisphenoxyl diradicaloid (2), which showed closed-shell diamagnetic character in less polar solvents such as dichloromethane but open-shell diradical character with paramagnetic activity in the very ...
Fang Miao, Hoa Phan, Jishan Wu
doaj   +1 more source

A Family of Ethyl N-Salicylideneglycinate Dyes Stabilized by Intramolecular Hydrogen Bonding: Photophysical Properties and Computational Study

open access: yesMolecules, 2021
In this work we report solvatochromic and luminescent properties of ethyl N-salicylideneglycinate (1), ethyl N-(5-methoxysalicylidene)glycinate (2), ethyl N-(5-bromosalicylidene)glycinate (3), and ethyl N-(5-nitrosalicylidene)glycinate (4) dyes.
Larisa E. Alkhimova   +2 more
doaj   +1 more source

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