Results 11 to 20 of about 2,249 (138)

SOLVATOCROMISMO E AS ESCALAS EMPÍRICAS DE POLARIDADE DO SOLVENTE: UMA REVISÃO [PDF]

open access: yesQuímica Nova, 2023
The term solvatochromism is used to describe the changes in the optical properties of a dye molecule by influence of the solvent characteristics. Solvatochromic shifts are governed by intermolecular interactions between solute-solvent that can be either ...
Ingrid Maliszewski Paczkowski   +1 more
doaj   +1 more source

Mechanochemical Activation of a Bridged-Exciplex Optical Force Probe. [PDF]

open access: yesAdv Sci (Weinh)
A bridged‐exciplex optical force probe is synthesized, switching from solvatochromic charge‐transfer emission in the latent state to intense locally excited emission upon activation. This dual photophysical response with additional changes in quantum yield and fluorescence lifetime enables precise environmental sensing and distinct optical readouts ...
Schumann R   +8 more
europepmc   +2 more sources

Synthesis and Solvatochromism of Oxazolone Derivative: Combining Organic Synthesis and Physical Organic Chemistry in a Single Experiment

open access: yesOrbital: The Electronic Journal of Chemistry, 2022
This work presents a proposal of experimental activity involving organic synthesis and solvatochromism of an organic molecule, correlating the content of organic chemistry and physical organic chemistry.
Taianne D’Angelo Korb   +2 more
doaj   +1 more source

Novel Method for Characterizing Humic Substances Using Fluorescent Solvatochromism. [PDF]

open access: yesSensors (Basel)
Charge-transfer-type fluorochromes, which exhibit shifts in fluorescence intensity and emission wavelength in response to solvent polarity changes, have been widely employed to investigate solute–solvent interactions. Humic substances (HSs) are naturally
Sazawa K   +6 more
europepmc   +2 more sources

Computational Quantification of the Zwitterionic/Quinoid Ratio of Phenolate Dyes for Their Solvatochromic Prediction

open access: yesMolecules, 2022
Solvatochromic dyes are utilized in various chemical and biological media as chemical sensors. Unfortunately, there is no simple way to predict the type of solvatochromism based on the structure of the dye alone, which restricts their design and ...
Andrés Aracena, Moisés Domínguez
doaj   +1 more source

N,N-Dimethyl-4-amino-2,1,3-benzothiadiazole: Synthesis and Luminescent Solvatochromism

open access: yesChemistry Proceedings, 2021
N,N-Dimethyl-4-amino-2,1,3-benzothiadiazole (BTDNMe2) was synthesized from the commercially available 2,1,3-benzothiadiazole (BTD) by nitration in a sulfonitric mixture, followed by a reduction of the nitro group and subsequent methylation with ...
Valentina Ferraro   +2 more
doaj   +1 more source

Photophysical Behavior and Sensing Response of Chalcone Containing Pyrene moiety [PDF]

open access: yesDelta Journal of Science, 2021
D–π–A dye composed of pyrene and thiophene units was synthesized and characterized using elemental, FT-IR, and mass analyses. The solvatochromic response was investigated in different solvents of various polarities.
Fathy Hassan   +4 more
doaj   +1 more source

Design of Promising aza-BODIPYs for Bioimaging and Sensing

open access: yesDesigns, 2022
The obtainment of new luminophores for molecular sensorics of biosystems is becoming one of the urgent tasks in the field of chemical synthesis. The solution to each practical problem imposes its own limitations in the design of new structures with ...
Dmitry Merkushev   +5 more
doaj   +1 more source

Synthesis of Novel Aqua ƞ4-NNNO/Cu(II) Complexes as Rapid and Selective Oxidative Catalysts for O-Catechol: Fluorescence, Spectral, Chromotropism and Thermal Analyses

open access: yesCrystals, 2021
A new tetradentate Schiff base (SB), (E)-4-fluoro-2-(1-((2-(piperazin-1-yl)ethyl)imino)ethyl)phenol, was synthesized from condensation of 2-(1-piperazinyl)ethylamine and 5-fluoro-2-hydroxyacetophenone.
Amjad M. Shraim   +5 more
doaj   +1 more source

A Family of Ethyl N-Salicylideneglycinate Dyes Stabilized by Intramolecular Hydrogen Bonding: Photophysical Properties and Computational Study

open access: yesMolecules, 2021
In this work we report solvatochromic and luminescent properties of ethyl N-salicylideneglycinate (1), ethyl N-(5-methoxysalicylidene)glycinate (2), ethyl N-(5-bromosalicylidene)glycinate (3), and ethyl N-(5-nitrosalicylidene)glycinate (4) dyes.
Larisa E. Alkhimova   +2 more
doaj   +1 more source

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