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The effects of solvents on chemical phenomena is complex because there are various solute-solvent interaction mechanisms. Solvatochromism refers to the effects of solvents on the spectra of probes. The study of this phenomenon sheds light on the relative
Omar A. El Seoud
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Assessing the pharmacological potential of selected xanthene derivatives [PDF]
A convenient and efficient approach toward the synthesis of seven aromatically substituted xanthendiones 1‒7 and one structurally-related xanthenone 8 through condensation of dimedone and the appropriate aromatic aldehyde is reported.
Lazić Anita M. +3 more
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Solvent, substituents and pH effects towards the spectral shifts of some highly colored indicators [PDF]
The solvatochromic responses of six indicators namely Sudan orange, Alizarin yellow R, Aurin tricarboxylic acid, Alizarin yellow GG, Titan yellow and Eriochrome black-T, dissolved in seven solvents of different polarities, have been measured at room ...
Masoud Mamdouh S. +2 more
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Twisting intramolecular charge transfer (TICT) is a common nonradiative relaxation pathway for a molecule with a flexible substituent, effectively reducing the fluorescence quantum yield (FQY) by swift twisting motions.
Jiawei Liu, Cheng Chen, Chong Fang
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Viscosity-Sensitive Solvatochromic Fluorescent Probes for Lipid Droplets Staining
Lipid droplets (LDs) are simple intracellular storage sites for neutral lipids and exhibit important impact on many physiological processes. For example, the changes in the polar microenvironment inside LDs could affect physiological processes, such as ...
Mao-Hua Wang +3 more
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The concept of “solvent polarity” is widely used to explain the effects of using different solvents in various scientific applications. However, a consensus regarding its definition and quantitative measure is still lacking, hindering progress in solvent-
William E. Acree, Andrew S. I. D. Lang
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Effect of Counterion on the Solvatochromic Properties of Heteroleptic Chelate Copper(II) Complexes
A series of heteroleptic chelate copper(II) complexes of the type [Cu(L)(acac)]X where acac = acetylacetonate; L = N,N′-1,6-bis(2-fluorophenyl)-2,5-diazahexane; X=CIO4-, BPh4-, PF6-, and BF4- have been prepared and characterized by elemental analyses, IR
Hamid Golchoubian, Hakimeh Fazilati
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Solvatochromism of N-aryl-phenylacetamides
Amide derivates are biologically active compounds and they are widely used in all spheres of life. Therefore, it is very important to know their physical-chemical properties.
Suzana Lj. Apostolov +2 more
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Solvatochromism and electrophilicity
Abstract Solvatochromic dyes that exhibit a negative or a positive behaviour may be distinguished and their solvatochromism predicted with the aid of DFT-based indices, such as their electrophilicity ω , hardness η and by the Fukui electrophilic functions f G + of the donor and acceptor moieties of the molecule, calculated in the ...
Caroli Rezende, Marcos +3 more
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Solvatochromism Study on the Copper(II) Complexes Containing 3–Substituted Derivatives of Acetylacetonate Ligands [PDF]
Solvatochromic properties of a series of bis(3–substituted derivatives of acetylacetone) copper(II) (X-acacH , X = Cl, H. CH3) complexes were studied. All the complexes demonstrated negative solvatochromism.
Hamid Golchoubian, Fariba Khoshsiar
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