Results 11 to 20 of about 484,472 (264)
3D Printing of Solvent-Free Supramolecular Polymers [PDF]
Additive manufacturing has significantly changed polymer science and technology by engineering complex material shapes and compositions. With the advent of dynamic properties in polymeric materials as a fundamental principle to achieve, e.g., self ...
Harald Rupp, Wolfgang H. Binder
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4-Sulfanyl-1,2,3-triazole as a Powerful Ligand in CuAAC to Synthesize 1,4-Substituted 1,2,3-Triazoles Under Solvent-Free and Low Catalyst Loading [PDF]
4-Sulfanyl-1,2,3-triazole (L1) accelerated the solvent-free CuAAC efficiently with low catalyst loading (0.1 mol% for common azides and 1 mol% for sulfonyl azides). L1 exhibited higher catalytic activity compared to 1,4-substituted 1,2,3-triazole without
Jie Shen +8 more
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Solvent‐Free Synthesis of Peptides [PDF]
A crush on sweetness ! A novel solvent-free methodology for the synthesis of peptides was developed: the coupling of an urethane protected N-carboxy anhydride (UNCA) of an aminoacid with another aminoacid derivative gave a protected dipeptide in very high yield under ball-milling conditions. The reaction is taking place in the solid state. This solvent-
Declerck, Valérie +3 more
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Scalable solvent-free production of liposomes [PDF]
Abstract Objectives A major challenge faced with the manufacture of liposomes is the high volumes of organic solvents used during manufacturing. Therefore, we have implemented an organic solvent-free production method for drug-loaded liposomes and demonstrated its applicability with both aqueous core ...
Khadke, Swapnil +5 more
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Predicting the activity coefficients of free-solvent for concentrated globular protein solutions using independently determined physical parameters. [PDF]
The activity coefficient is largely considered an empirical parameter that was traditionally introduced to correct the non-ideality observed in thermodynamic systems such as osmotic pressure.
Devin W McBride, Victor G J Rodgers
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Solvent-free autocatalytic supramolecular polymerization [PDF]
Abstract Solvent-free chemical manufacturing is one of the awaited technologies for addressing an emergent issue of serious environmental pollution. Here, we report "solvent-free autocatalytic supramolecular polymerization (SF-ASP)", where a phthalonitrile derivative with hydrogen-bonding side chains as the monomer is autocatalytically ...
Zhen Chen +9 more
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Solvent‐Free Photobiocatalytic Hydroxylation of Cyclohexane [PDF]
AbstractThe use of neat reaction media, that is the avoidance of additional solvents, is the simplest and the most efficient approach to follow in biocatalysis. Here, we show that unspecific peroxygenase from Agrocybe aegerita (AaeUPO) can hydroxylate the neat model substrate cyclohexane.
Markus Hobisch +8 more
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Solvent-free synthesis of propargylamines: an overview
This review focuses on solvent-free methodologies for the synthesis of propargylamines, a versatile class of compounds with numerous applications.
Ravi Manujyothi +2 more
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Microwave assisted solvent free synthesis of 1,3-diphenylpropenones
Background 1,3-Diphenylpropenones (chalcones) are well known for their diverse array of bioactivities. Hydroxyl group substituted chalcones are the main precursor in the synthesis of flavonoids.
Sarma Jadab C, Kakati Dwipen
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The roles of counterions, solvent types and extraction temperatures on the selectivity of 18-crown-6 (L) toward alkaline earth salts MX2 (M = Ca, Sr, Ba; X = Cl-, NO3-) have been studied by density functional method at B3LYP level of theory in gas and ...
Saprizal Hadisaputra +3 more
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