Results 171 to 180 of about 173,394 (296)

Mixed TiO2–SiO2 thin coatings for selective adsorption and sunlight‐powered photodegradation of cationic pollutants

open access: yesResponsive Materials, EarlyView.
Environmental pollution and water scarcity demand innovative purification methods. This study presents a sol‐gel approach to fabricate mixed silica–titania thin films joining photocatalytic activity with selective sorption capability. The films exhibit higher surface area, enhanced degradation of cationic and improved performance over bare titania ...
Andrea Lanfranchi   +13 more
wiley   +1 more source

Surface Engineering of Ti3C2Tx MXenes via Silanol Functionalization for Improved Electrochemical Performance

open access: yesSmall, EarlyView.
This study explores the covalent functionalization of Ti3C2Tx using 5,5′‐bis(triisopropoxysilyl)‐2,2′‐bipyridine in different solvents, revealing that only m‐xylene enables effective covalent bonding, ensuring structural stability and preventing layer swelling.
Abelardo Sánchez‐Oliva   +11 more
wiley   +1 more source

Solar‐Powered Water Depollution Through a Bioinspired Device Based on ZIF‐8 Loaded Macroporous Hydrogels Prepared via Ice‐Templating

open access: yesSmall, EarlyView.
ABSTRACT Water pollution poses a constant threat to the environment and is one of the central causes for global shortage of clean water. Metal–Organic Frameworks (MOFs) have emerged as highly efficient adsorbents; however, their application is limited by their common production as fine powders, which hinders recovery and reuse.
Katsuya Komiyama   +3 more
wiley   +1 more source

Impacts of Fluorination at the Ortho‐Position of Carboxy Groups on Tetrakis(biphenyl)ethene‐Based Hydrogen‐Bonded Framework

open access: yesSmall, EarlyView.
This work provides new findings on the effect of fluorination on the substitution of TPE derivatives and the modulation of the structure and fluorescence properties of hydrogen‐bonded organic framework (HOF) of F‐CBPE. ABSTRACT Fluorination of building block molecules is one of the effective engineering approaches to modulate molecular assembly in ...
Takuto Fujii   +8 more
wiley   +1 more source

Interplay Between Oxidation State, Intervalence Charge Transfer Transitions and Electronic Conductivity in a Series of Ru‐Based Metal–Organic Frameworks

open access: yesSmall, EarlyView.
Ru‐based square‐grid metal–organic frameworks undergo dramatic conductivity enhancements after chemical oxidation. The mixed‐valent states exhibit the highest conductivity values, which correlate with the appearance of intervalence charge transfer bands.
Wang Zhang   +12 more
wiley   +1 more source

Characterization of the Pore Environments in Covalent Organic Frameworks by Dynamic Spin Probe Exchange

open access: yesSmall, EarlyView.
Covalent organic frameworks (COFs) with alkyl or triethylene glycol pore linings are probed with water‐dissolved nitroxide radicals using CW EPR spectroscopy. Adsorption affinity, local polarity, and radical concentration inside the pores are quantified, revealing hydrogen bonding, dipolar, and π‐π interactions that govern guest binding, which ...
Sebastian Michler   +5 more
wiley   +1 more source

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