Results 71 to 80 of about 544,006 (376)
Recent Development on the Detection and Monitoring of Chemical Intermediates by Ambient Mass Spectrometry [PDF]
Along with the development of science and technology, chemical reactions exhibit an important role in various fileds including synthesis, chemical engineering, energy, environment, biology and medicine.
GE Xi-yang1+3 more
doaj
To systematically study the effects of the number of d electrons of the first transition metal ions (Fe, Co, Ni, Cu and Zn) on the formation and stability of metal flavonoid complexes, we took the quercetin/M2+ complex as a model system to investigate ...
Yuanzhen Liu, Mingquan Guo
doaj +1 more source
Cerebrospinal fluid, neuroinflammation, and electrospray ionization mass spectrometry [PDF]
This commentary is on the original article by Yan et al. on pages 552–559 of this issue.
openaire +3 more sources
Determination of parabens in human urine by liquid chromatography coupled with electrospray ionization tandem mass spectrometry [PDF]
A simple and sensitive method was developed for the simultaneous determination of methyl, ethyl,n-propyl,n-butyl, and benzyl parabens in human urine by liquid chromatography coupled with electrospray ionization tandem mass spectrometry (LC-ESI-MS/MS).
Fu, Jiamo+6 more
core +1 more source
Synthetic cells are engineered herein to respond to an external chemical messenger by the activation of intracellular catalysis. The chemical messenger molecules are catalytically generated by an extracellular enzyme or a mineral surface, whereas the intracellular catalysis emerges via direct enzyme activation or via protein refolding.
Dante G. Andersen+5 more
wiley +1 more source
Proton Dynamics in Protein Mass Spectrometry [PDF]
Native electrospray ionization/ion mobility-mass spectrometry (ESI/IM-MS) allows an accurate determination of low-resolution structural features of proteins. Yet, the presence of proton dynamics, observed already by us for DNA in the gas phase, and its impact on protein structural determinants, have not been investigated so far.
arxiv +1 more source
Mass-Resolved Electronic Circular Dichroism Ion Spectroscopy [PDF]
DNA and proteins are chiral: their three-dimensional structure cannot be superimposed with its mirror image. Circular dichroism spectroscopy is widely used to characterize chiral compounds, but data interpretation is difficult in the case of mixtures. We recorded for the first time the electronic circular dichroism spectra of DNA helices separated in a
arxiv +1 more source
Zinc(II) coordination complexes with tunable aryloxy‐imine ligands exhibit controllable supramolecular self‐assembly into hierarchical fibrous structures. Coordination‐driven stacking, not π–π interactions, enables gelation, dynamic assembly/disassembly, and enhanced nanomechanical properties.
Merlin R. Stühler+10 more
wiley +1 more source
Specific and nonspecific non-covalent molecular association of biomolecules is characteristic for electrospray-ionization mass spectrometry analysis of biomolecules.
Paulina Grocholska+3 more
doaj +1 more source
Structural study of analogues of Titan s haze by trapped ion mobility coupled with a Fourier transform ion cyclotron mass spectrometer [PDF]
The aerosols present in the atmosphere of the Saturn s moon Titan are of particular planetary science interest and several spacecraft missions already allowed to gather spectroscopic data. Titan haze s analogs, so-called tholins, were produced on earth to push forward the comprehension of their formation and properties.
arxiv +1 more source