A trinuclear manganese complex supported by the 7‐Dipy scaffold undergoes controlled multielectron oxidation from Mn(II)3 to high‐valent Mn(IV)3 states. Spectroscopic signatures, including 16‐line and geff ≈ 5 EPR features, reveal stepwise redox accumulation. The oxidized Mn3 cluster mediates efficient oxygen‐atom transfer to strong CH bonds, enabling
Yu‐Hsuan Chen, Peter Ping‐Yu Chen
wiley +1 more source
Spin Crossover Composite Film as Recyclable Catalyst for Acetalization Reaction. [PDF]
Lai Y +4 more
europepmc +1 more source
ABSTRACT Purpose/Objectives To compare the effectiveness of MR simulation and 3D‐printed models in training undergraduate students in wisdom tooth removal, and to assess students’ perceptions of the MR simulator. Methods Students trained first on either the MR simulator or 3D‐printed plastic models and then repeated the training using the other method ...
Ruza Bjelovucic +5 more
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Thermally and Light-Induced Spin-Crossover in Iron(III) Complexes with Benzophenone-Based Saltrien Ligands: Hysteresis, Two-Step Transitions, and the LIESST Effect. [PDF]
Pogány L +5 more
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Controlling Collective Quasiparticle Dynamics Beyond Decoherence in Topological Interfaces
Gold nanoparticles placed above a deformed honeycomb plasmonic crystal couple to a chiral topological interface mode. The pseudospin‐split bands ψ+/ ψ− encode spin‐momentum locking, so emitters radiate directionally along the domain wall and share a common phase.
Fatemeh Davoodi
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Elucidating the Transition Kernel and Anharmonic Coupling in the Spin-crossover Process of a [Fe<sup>III</sup>(qsal)<sub>2</sub>] CH<sub>3</sub>OSO<sub>3</sub> Complex. [PDF]
Mitra S +8 more
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Bi3+‐doped Cs2SnCl6 nanocrystals are engineered to deliver highly temperature‐responsive self‐trapped exciton emission, achieving record thermal sensitivity at elevated temperatures. A temperature‐induced dual‐STE excited state landscape enables reversible thermochromism, while a dual‐parameter calibration combining fluorescence lifetime and CIE‐y ...
Sujun Ji +16 more
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Tracking Structural and Electron Spin Density Changes in a Cooperative Mn<sup>3+</sup> Spin Crossover Complex at Atomic Scale via Low Temperature Solid-State NMR. [PDF]
Papawassiliou W +8 more
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Optical limiting in a nanomaterial‐polymer saturable absorber is harnessed as a functional intracavity degree of freedom, where pump‐controlled photothermal loss continuously reshapes the gain spectrum of rare‐earth ions, enabling non‐mechanical spectral engineering in an ultrafast fiber laser.
Maolin Dai +4 more
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Combination of density functional theory and calorimetry reveals the microscopic nature of spin state switching in 1D Fe(ii) spin crossover complexes. [PDF]
Wolny JA +7 more
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