Results 11 to 20 of about 9,526 (252)
Spin-Crossover Complexes [PDF]
Inorganics, 2018 Spin-crossover (SCO) is a spin-state switching phenomenon between a high-spin (HS) and low-spin (LS) electronic configurations in a transition metal center.
Kazuyuki Takahashi
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Mosaicity of Spin-Crossover Crystals [PDF]
Crystals, 2018 Real crystals are composed of a mosaic of domains whose misalignment is evaluated by their level of “mosaicity” using X-ray diffraction. In thermo-induced spin-crossover compounds, the crystal may be seen as a mixture of metal centres, some ...
Sabine Lakhloufi +7 more
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Hybrid spin-crossover nanostructures [PDF]
Beilstein Journal of Nanotechnology, 2014 This review reports on the recent progress in the synthesis, modelling and application of hybrid spin-crossover materials, including core–shell nanoparticles and multilayer thin films or nanopatterns.
Carlos M. Quintero +7 more
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Molecules, 2020 Three new iron(II) 1D coordination polymers with cooperative spin crossover behavior showing thermal hysteresis loops were synthesized using N2O2 Schiff base-like equatorial ligands and 4,4′-dipyridylethyne as a bridging, rigid axial linker. One of
Katja Dankhoff +2 more
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Modeling Spin-Crossover Dynamics [PDF]
Annual Review of Physical Chemistry, 2021 In this article, we review nonadiabatic molecular dynamics (NAMD) methods for modeling spin-crossover transitions. First, we discuss different representations of electronic states employed in the grid-based and direct NAMD simulations. The nature of interstate couplings in different representations is highlighted, with the main focus on nonadiabatic ...
Mukherjee, Saikat +2 more
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Metal Substitution Effect on a Three-Dimensional Cyanido-Bridged Fe Spin-Crossover Network
Inorganics, 2017 We report the CoII-substitution effect on a cyanido-bridged three-dimensional FeII spin-crossover network, Fe2[Nb(CN)8](4-pyridinealdoxime)8·2H2O. A series of iron–cobalt octacyanidoniobate, (FexCo1−x)2[Nb(CN)8](4-pyridinealdoxime)8·zH2O, was prepared ...
Kenta Imoto +2 more
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Magnetochemistry, 2020 We studied the spin-state dependence of the electrical conductivity of two nanocrystalline powder samples of the spin crossover complex [Fe(pyrazine){Au(CN)2}2].
Andrei-Cristian Gheorghe +9 more
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Spin state switching in iron coordination compounds
Beilstein Journal of Organic Chemistry, 2013 The article deals with coordination compounds of iron(II) that may exhibit thermally induced spin transition, known as spin crossover, depending on the nature of the coordinating ligand sphere. Spin transition in such compounds also occurs under pressure
Philipp Gütlich +2 more
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Spin‐Crossover Complexes [PDF]
European Journal of Inorganic Chemistry, 2013 AbstractEurJIC is proud to present a bumper issue on Spin‐Crossover Complexes. Our Guest Editors, Keith Murray, Hiroki Oshio and José Antonio Real, have worked hard to put together a fantastic issue. With a valuable personal account of the field by Philipp Gütlich and inspiring papers by leading experts, you will not be disappointed.
Keith S. Murray +2 more
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Magnetochemistry, 2020 The effects of mechanochemical synthesis and postsynthetic grinding on the spin crossover material [Fe(atrz)3](BF4)2 was examined in detail using a combination of X-ray diffraction, magnetometry, EXAFS and TEM.
Jed H. Askew +4 more
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