Molecular Oxygen as a Probe Molecule in EPR Spin Labeling Studies of Membrane Structure and Dynamics
Molecular oxygen (O2) is the perfect probe molecule for membrane studies carried out using the saturation recovery EPR technique. O2 is a small, paramagnetic, hydrophobic enough molecule that easily partitions into a membrane’s different phases and ...
Witold K. Subczynski +3 more
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chiLife: An open-source Python package for in silico spin labeling and integrative protein modeling.
Here we introduce chiLife, a Python package for site-directed spin label (SDSL) modeling for electron paramagnetic resonance (EPR) spectroscopy, in particular double electron-electron resonance (DEER).
Maxx H Tessmer, Stefan Stoll
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Structural Impact of Selected Retinoids on Model Photoreceptor Membranes
Photoreceptor membranes have a unique lipid composition. They contain a high level of polyunsaturated fatty acids including the most unsaturated fatty acid in nature, docosahexaenoic acid (22:6), and are enriched in phosphatidylethanolamines.
Szymon Radzin +8 more
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Thermostimulated crystal structure transformation of the polymineral clay submicron particles
Changes in the structure of phyllosilicate microparticles of submicron fractions of polymineral clay with an average size of 290 nm, as well as changes in the positions of impurity ions of transition metals in the crystal lattice, were studied by X-ray ...
A. G. Chetverikova +4 more
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Spin Labeling of Surface Cysteines Using a Bromoacrylaldehyde Spin Label [PDF]
AbstractStructural investigations of proteins and their biological complexes are now frequently complemented by distance constraints between spin labeled cysteines generated using double electron–electron resonance (DEER) spectroscopy, via site directed spin labeling (SDSL).
Graham Heaven +3 more
openaire +3 more sources
Evidence for an Ordering Transition near 120 K in an Intrinsically Disordered Protein, Casein
Intrinsically disordered proteins (IDPs) are proteins that possess large unstructured regions. Their importance is increasingly recognized in biology but their characterization remains a challenging task.
Natalya A. Maslennikova +2 more
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EPR Study of Spin Labeled Brush Polymers in Organic Solvents [PDF]
Spin-labeled polylactide brush polymers were synthesized via ring-opening metathesis polymerization (ROMP), and nitroxide radicals were incorporated at three different locations of brush polymers: the end and the middle of the backbone, and the end of ...
Burts, Alan O. +7 more
core +2 more sources
Electron Spin Relaxation of Photoexcited Porphyrin in Water—Glycerol Glass
Recently, the photoexcited triplet state of porphyrin was proposed as a promising spin-label for pulsed dipolar electron paramagnetic resonance (EPR).
Natalya Sannikova +5 more
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Conformational Dynamics of metallo-β-lactamase CcrA during Catalysis Investigated by Using DEER Spectroscopy [PDF]
Previous crystallographic and mutagenesis studies have implicated the role of a position-conserved hairpin loop in the metallo-β-lactamases in substrate binding and catalysis.
Aitha, Mahesh +8 more
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THE DYNAMICS OF HEMERYTHRIN AND HEMERYTHRIN DERIVATIVES
The non-heme diiron protein hemerythrin (Hr) has been considered as a possible alternative for semi-artificial oxygen carriers (“blood substitutes”).
Francisco CARRASCOZA +2 more
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