Results 41 to 50 of about 5,917 (220)

Two-photon photopolymerization directly initiated by spiropyran photochromic molecules

open access: yesLight: Advanced Manufacturing, 2023
Here, we report the ability of spiropyrans to initiate two-photon polymerization (TPP) for the first time in the literature. The comparison and synergies between the spiropyran photochromic molecule of interest, namely 6-nitro-BIPS, and well-known ...
Dandan Ge   +7 more
doaj   +1 more source

Preparation and analysis of photochromic behavior of carboxymethyl chitin derivatives containing spiropyran moieties

open access: yesDesigned Monomers and Polymers, 2020
1ʹ-(2-Acryloxyethyl)-3,3ʹ-dimethyl-6-nitrospiro[2 H-1-benzopyran-2,2ʹ-indoline] (SPA) was synthesized and grafted onto a water-soluble carboxymethyl chitin (CMCH) macromolecule to prepare a photochromic copolymer (CMCH-g-SPA). The structure of CMCH-g-SPA
Bin-Bin Sun   +3 more
doaj   +1 more source

Synthesis and characterisation of spiropyran-polymer brushes in micro-capillaries: towards an integrated optical sensor for continuous flow analysis [PDF]

open access: yes, 2011
Fused silica-capillaries were successfully functionalised with spiropyran-polymer brushes using spiropyran functionalised norbornyl derivative as monomer. The polymerisation was achieved by surface-initiated ring- opening metathesis polymerisation.
Benito-Lopez, Fernando   +3 more
core   +1 more source

Spiropyran-based dynamic materials

open access: yesChem. Soc. Rev., 2014
In the past few years, spiropyran has emerged as the molecule-of-choice for the construction of novel dynamic materials. This unique molecular switch undergoes structural isomerisation in response to a variety of orthogonal stimuli, e.g. light, temperature, metal ions, redox potential, and mechanical stress.
openaire   +3 more sources

Double-stranded RNA induction asa potential dynamic biomarkerfor DNA-demethylating agents

open access: yesMolecular Therapy: Nucleic Acids, 2022
Hypomethylating agents (HMAs), such as azacitidine and decitabine, induce cancer cell death by demethylating DNAs to promote the expression of tumor-suppressor genes. HMAs also reactivate the transcription of endogenous double-stranded RNAs (dsRNAs) that
Minjeong Kang   +14 more
doaj   +1 more source

Eliminating Fatigue in Surface-Bound Spiropyrans [PDF]

open access: yesThe Journal of Physical Chemistry C, 2019
This paper describes an experimental approach to eliminating the loss of reversibility that surface-bound spiropyrans exhibit when switched with light. Although such fatigue can be controlled in other contexts, on surfaces, the photochromic compounds are held in close proximity to each other and relatively few molecules modulate the properties of a ...
Sumit Kumar   +7 more
openaire   +3 more sources

Light‐Controlled Reversible Coassembly of Hybrid Functional Nanostructures

open access: yesAdvanced Functional Materials, EarlyView.
Light‐responsive hybrid nanostructures are formed by coassembling azobenzene‐ and PAH‐functionalized nanoparticles through reversible an tunable π interactions. The system enables tunable coupling between distinct components such as gold and magnetite or carbon nanotubes, producing switchable optical and magnetic properties under light and magnetic ...
Michal Sawczyk   +5 more
wiley   +1 more source

Photo-detection of solvent polarities using non-invasive coatings in capillaries [PDF]

open access: yes, 2011
Fused silica-capillaries were functionalised with spiropyran-polymer brushes using a spiropyran functionalised norbornyl derivative as the monomer (SP-M).
Benito-Lopez, Fernando   +3 more
core   +1 more source

Photoswitching Conduction in Framework Materials

open access: yesAdvanced Functional Materials, EarlyView.
This mini‐review summarizes recent advances in state‐of‐the‐art proton and electron conduction in framework materials that can be remotely and reversibly switched on and off by light. It discusses the various photoswitching conduction mechanisms and the strategies employed to enhance photoswitched conductivity.
Helmy Pacheco Hernandez   +4 more
wiley   +1 more source

Spiropyran Photoisomerization Dynamics in Multiresponsive Hydrogels

open access: yesJournal of the American Chemical Society, 2021
Light-responsive, spiropyran-functionalized hydrogels have been used to create reversibly photoactuated structures for applications ranging from microfluidics to nonlinear optics. Tailoring a spiropyran-functionalized hydrogel system for a particular application requires an understanding of how co-monomer composition affects the switching dynamics of ...
Amos Meeks   +4 more
openaire   +2 more sources

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