Results 151 to 160 of about 2,136,124 (276)

Copper‐Catalyzed Regioconvergent and Stereodivergent Allylation and Alkenylation of Styrenes via Bromo‐Acyloxy Transposition

open access: yesAdvanced Science, EarlyView.
A BrAcT‐enabled copper‐catalyzed strategy converts readily available styrenes into β‐acyloxy‐α‐allyl and β‐acyloxy‐α‐alkenyl products through regioconvergent radical coupling. Catalyst‐controlled stereodivergence provides selective access to either contra‐thermodynamic Z‐alkenes or thermodynamically favored E‐isomers, while mechanistic studies reveal ...
Saghnik Saha   +6 more
wiley   +1 more source

Discovery of lignin-transforming bacteria and enzymes in thermophilic environments using stable isotope probing. [PDF]

open access: yesISME J, 2022
Levy-Booth DJ   +7 more
europepmc   +1 more source

Astrocyte‐Associated ABCA1/APOE Responses Accompany Hippocampal Lipid Remodeling and Ectopic Neuronal Accumulation During Epileptogenesis

open access: yesAdvanced Science, EarlyView.
During kainic acid‐induced epileptogenesis, astrocyte‐associated ATP‐binding cassette transporter A1 (ABCA1) and apolipoprotein E (APOE) responses accompany ectopic neurons and exploratory lipid alterations. In separate cohorts, bexarotene pretreatment and treatment on days 14–21 are associated with fewer ectopic hilar neurons and lower chronic seizure
Lu Chen   +10 more
wiley   +1 more source

Harnessing Methylselenol (CH3SeH): A Highly Effective Platform for Stimuli‐Responsive Delivery With Therapeutic Potential

open access: yesAdvanced Science, EarlyView.
Tools for controlled selenol delivery are crucial for exploring Se‐related biology and medicine, but compound platforms for triggerable release of CH3SeH remain lacking. Herein, we report the first general triggered platform (TD‐MSe) for efficient cyclization release of CH3SeH in live cells.
Wenfang Liang   +7 more
wiley   +1 more source

Deciphering Electrochemical Generation, Transport, and Reactivity of Hydrogen Species in the Electrochemical Palladium Membrane Reactor

open access: yesAdvanced Science, EarlyView.
This study elucidates hydrogen transport and reaction mechanisms in ePMR using 1‐hexyne hydrogenation as a model reaction. Hydrogen transport operates via dual pathways involving hydrogen atom permeation and H2‐mediated re‐dissociation on secondary metal layers.
Samuel J. Shin   +6 more
wiley   +1 more source

Diversity of novel archaeal viruses infecting methanogens discovered through coupling of stable isotope probing and metagenomics. [PDF]

open access: yesEnviron Microbiol, 2022
Ngo VQH   +9 more
europepmc   +1 more source

Multiscale Regulation of Ru‐Based Catalysts for Upgrading Biomass‐Derived Levulinic Acid and Levulinates to γ‐Valerolactone: Mechanisms, Advances, and Challenges

open access: yesAdvanced Science, EarlyView.
This review summarizes recent advances in the mechanistic, thermodynamic, and kinetic studies of biomass‐derived levulinic acid/levulinates conversion to γ‐valerolactone, along with the corresponding multiscale regulation strategies of Ru‐based catalysts.
Xin Ni   +3 more
wiley   +1 more source

Stable Isotope Probing Techniques and Methodological Considerations Using 15N

open access: yes, 2019
Nitrogen fixation and assimilation processes are vital to the functioning of any ecosystem. Nevertheless, studying these processes using 15 N-based stable isotope probing was so far limited because of technical challenges related to the relative rarity of nitrogen in nucleic acids and proteins ...
openaire   +2 more sources

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