Results 1 to 10 of about 2,156 (179)

Determining the antioxidant properties of various beverages using staircase voltammetry [PDF]

open access: yesHeliyon, 2020
Antioxidants are molecules that neutralize reactive oxygen species in the human body, reportedly reducing the risk of cancer and cardiovascular diseases. With multiple dietary products being advertised by their assumed high antioxidant concentration, the
Wouter Olthuis
exaly   +8 more sources

Voltammetry of porous layers: Staircase vs analog voltammetry [PDF]

open access: yesJournal of Electroanalytical Chemistry, 2016
Abstract The use of staircase ramps for cyclic voltammetry rather than true linear analog ramps can lead to significant misinterpretation of the signals recorded for the measurement of diffusional redox species with either reversible or irreversible electrode kinetics measured at electrodes modified with porous layers.
Enno Kätelhön
exaly   +3 more sources

Staircase Voltammetry using Rotating Disk Electrode

open access: yesTo Chemistry Journal, 2018
A theory of staircase voltammetry on the rotating disk electrode is developed. The simulation is based on the method of variable diffusion layer thickness. Critical parameters that define the form of responses are calculated.
Milivoj Lovrić   +1 more
doaj   +4 more sources

CONSIDERAÇÕES TÉCNICAS QUANTO AO USO DA VOLTAMETRIA DE VARREDURA ESCALONADA EM PROCESSOS ADSORTIVOS

open access: yesQuímica Nova, 2015
Cyclic voltammetry has become one of the most useful tools in modern electrochemistry, but the use of digital potentiostats should be treated with caution by users. Staircase Voltammetry utilizes some parameters to build up the potential ramp.
Khallil Hassan Ahmad Ali Fernandes   +4 more
doaj   +2 more sources

Fundamentals and Implication of Point of Zero Charge (PZC) Determination for Activated Carbons in Aqueous Electrolytes [PDF]

open access: yesAdvanced Science
The point of zero charge (PZC) is a crucial parameter for investigating the charge storage mechanisms in energy storage systems at the molecular level. This paper presents findings from three different electrochemical techniques, compared for the first ...
Sylwia Slesinska   +5 more
doaj   +2 more sources

Influence of Potentiostat Hardware on Electrochemical Measurements [PDF]

open access: yesSensors
We describe two operating modes for the same potentiostat, where the redox processes of hydroquinone in a hydrochloric acid medium are contrasted for cyclic voltammetry (CV) as functions of a digital/staircase scan and an analogue/linear scan.
Abhilash Krishnamurthy   +1 more
doaj   +2 more sources

Determining phase-transition temperatures of molten salt mixtures through microsecond-scale staircase voltammetry

open access: yesElectrochemistry Communications
Determining the phase-transition temperature is crucial in the design of molten salt reactors, as operational temperatures need to be established considering the safety margins related to the thermodynamic stability of the molten salt system.
Hwakyeung Jeong   +4 more
doaj   +2 more sources

New complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrode

open access: yesJournal of Electrochemical Science and Engineering, 2021
Cyclic staircase voltammograms of a simple, reversible oxidation on the rotating disk electrode is analysed by the digital simulation. It is demonstrated that the peak currents and potentials depend on the single dimensionless variable that considers ...
Milivoj Lovrić
doaj   +1 more source

Optimal corrosion resistance of cobalt-based dual-phase entropic alloys via compositional modulation of aluminum

open access: yesJournal of Materials Research and Technology, 2023
A new category of Al-doped cobalt-based dual phase entropic alloys with high corrosion resistance properties was designed in the present work. CALPHAD (CALculation of PHAse Diagram) aided prediction was performed to facilitate the alloy design.
Wei Wang   +7 more
doaj   +1 more source

Coupling of Cyclic Voltammetry and Electrochemical Impedance Spectroscopy for Probing the Thermodynamics of Facilitated Ion Transfer Reactions Exhibiting Chemical Kinetic Hindrances [PDF]

open access: yes, 2007
Mathematical models under conditions of cyclic staircase voltammetry and electrochemical impedance spectroscopy (EIS), which consider the kinetic effects due to the complexation reaction by the facilitated transfer of metal ions at polarized interfaces,
Arunachalam   +23 more
core   +3 more sources

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