Results 21 to 30 of about 4,812,323 (280)

ZIF-8 Assisted Polyacrylamide Functionalized Silica Core-Shell Stationary Phase for Hydrophilic Interaction Liquid Chromatography

open access: yesSeparations, 2023
A novel ZIF-8 assisted polyacrylamide functionalized silica polar stationary phase was prepared by a facile method of adding ZIF-8 nanoparticles and silica into polyacrylamide (PAM) aqueous solution, and then stirring the mixture until the solution was ...
Tong Zhang   +5 more
doaj   +1 more source

Application of Solvatic Model for Prediction of Retention at Gradient Elution in Reversed-Phase Liquid Chromatography

open access: yesActa Chimica Slovenica, 2019
There are several different approaches for LC method development; beside traditional, different software programs for method development and optimization are available.
Tina Snoj Ekmečič, Irena Kralj Cigic
doaj   +1 more source

The application of the extended thermodynamic approach to describe the effect of counterions, both of chaotropic agents and ionic strength modifiers, on the retention behavior of protonated basic analytes in chaotropic chromatography [PDF]

open access: yesArhiv za farmaciju
In this study, the extended thermodynamic approach was used to quantitatively explain the effect of counterions, both of chaotropic agents and ionic strength modifiers, in variable (vI) and constant ionic strength (cI) systems on the retention behavior ...
Gkountanas Kostas   +4 more
doaj   +1 more source

Separation Of Methionine Enantiomers By Using Teicoplanin And Cyclofructan Columns

open access: yesNova Biotechnologica et Chimica, 2015
Methionine is a naturally occurring amino acid. Its enantiomeric separation by using high performance liquid chromatography on various types of chiral stationary phases was studied.
Hroboňová Katarína   +5 more
doaj   +1 more source

Peptide retention time prediction for immobilized artificial membrane phosphatidylcholine stationary phase: method development and preliminary observations

open access: yesADMET and DMPK, 2018
Development of the first peptide retention prediction model for immobilized artificial membrane phosphatidylcholine (IAM.PC) stationary phase is reported. 2D LC-MS/MS analysis of a whole cell lysate of S. cerevisiae yielded a retention dataset of ~29,500
Daniel Gussakovsky   +3 more
doaj   +1 more source

Fabrication of naphthol-based phenolic polymer coated-silica for mixed-mode chromatography

open access: yesJournal of Chromatography Open, 2022
This paper introduces a novel phenolic resin-coated silica stationary phase grafted from the surface of amino-functionalized porous silica microspheres through copolymerization of 1,5-dihydroxynaphthalene and 1,3,5-trioxane in the dispersed state ...
Yongxing Hu   +2 more
doaj   +1 more source

Isothermal retention indices on poly(3,3,3-trifluoropropylmethylsiloxane) stationary phases

open access: yesJournal of Chromatography A, 2007
Isothermal retention indices (I) of 56 solutes of varied chemical nature and polarity were determined by a well-proven accurate method on poly(3,3,3-trifluoropropylmethylsiloxanes) with trifluoropropyl group percentages between 0 and 50% within the 353-413 K temperature range.
Lebrón-Aguilar, Rosa   +3 more
openaire   +2 more sources

The thermodynamic study of morpholinium 2-((4-(2-methoxyphenyl)-5-(pyridinyl)-4H-1,2,4-triazol-3-yl)thio)acetate and its technological impurities in hydrophilic chromatography

open access: yesЖурнал органічної та фармацевтичної хімії, 2020
Aim. To study the dependence of the retention of morpholinium 2-((4-(2-methoxyphenyl)-5-(pyridinyl)-4H-1,2,4-triazol-3-yl)thio)acetate and its technological impurities on temperature, as well as determine the thermodynamic characteristics of the transfer
B. O. Varynskyi
doaj   +1 more source

Determination of thermodynamic parameters of morpholinium 2-(5-(pyridinyl)-1,2,4-triazole-3-ylthio)acetate and its impurities in conditions of reverse phase chromatography

open access: yesAktualʹnì Pitannâ Farmacevtičnoï ì Medičnoï Nauki ta Praktiki, 2020
The study of thermodynamic retention parameters helps to optimize the separation process in chromatography, and it is also possible to detrmine the nature of the interaction of analyts with the stationary phase.
B. O. Varynskyi
doaj   +1 more source

Development and Validation of Retention Models in Supercritical Fluid Chromatography for Impregnation Process Design

open access: yesApplied Sciences, 2021
The retention factor is the key quantity for the thermodynamic analysis of the retention mechanism in chromatographic experiments. In this work, we measure retention factors for moderately polar solutes on four silica-based porous matrices as stationary ...
Miaotian Sun   +6 more
doaj   +1 more source

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